IP Library Granted Patent US 6,852,853
Granted Patent B2
US 6,852,853 · App. 10/421,149 · Granted Feb 8, 2005

Methods for preparation of biopolymer thickened fire retardant compositions

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Quick Facts
Patent No.
US 6,852,853
App. No.
10/421,149
Granted
Feb 8, 2005
Kind
B2
Abstract

Fire retardant compositions and methods of making and using the same are provided. The fire retardant compositions are comprised of at least one fire retardant component, including at least one ammonium polyphosphate and at least one biopolymer having a weight average particle diameter of less than about 100 microns. In a specific embodiment, the fire retardant composition is comprised of a xanthan biopolymer.

Claims (39)

1. A method of preparing a fire retardant composition, adapted for aerial application to wildland fires, the method comprising the steps of:

(a) forming an intermediate concentrate composition comprising:

(i) a fire retardant comprised at least one ammonium polyphosphate; and

(ii) at least one biopolymer having a weight average particle diameter less than about 100 microns; and

(c) diluting said intermediate concentrate with water to form said fire retardant composition wherein said at least one biopolymer is not guar gum.

2. The method of claim 1 wherein said step of forming an intermediate concentrate composition comprises forming an intermediate concentrate composition comprising:

(i) a fire retardant comprised of at least one ammonium polyphosphate;

(ii) at least one biopolymer having a weight average particle diameter less than about 100 microns; and

(iii) at least one additive selected from the group consisting of coloring agents, suspending agents, surfactants, stabilizers, corrosion inhibitors and any combination thereof.

3. The method of claim 2 wherein said step of forming an intermediate concentrate composition comprises forming an intermediate concentrate composition comprising:

(i) a fire retardant comprised at least one ammonium polyphosphate;

(ii) at least one biopolymer having a weight average particle diameter less than about 100 microns; and

(iii) a coloring agent selected from the group consisting of fugitive coloring agents, non-fugitive coloring agents, opacifying pigments and any combination thereof.

4. The method of claim 2 wherein said step of forming an intermediate concentrate composition comprises forming an intermediate concentrate composition comprising:

(i) a fire retardant comprised at least one ammonium polyphosphate;

(ii) at least one biopolymer having a weight average particle diameter less than about 100 microns; and

(iii) at least one suspending agent selected from the group consisting of Attapulgus, Sepiolite, Fuller's earth, Montmorillonite and Kaolin clays.

5. The method of claim 1 wherein said step of forming an intermediate concentrate composition comprises forming an intermediate concentrate composition comprising from about 0.01% by weight to about 5.0% by weight said biopolymer.

6. The method of claim 1 wherein said step of forming an intermediate concentrate composition comprises forming an intermediate concentrate composition comprising about 3.0% by weight said biopolymer.

7. The method of claim 1 wherein said step of forming an intermediate concentrate composition comprises forming an intermediate concentrate composition comprising about 1.0% by weight said biopolymer.

8. The method of claim 1 wherein said step of forming an intermediate concentrate composition comprises forming an intermediate concentrate composition comprising about 0.5% by weight said biopolymer.

9. The method of claim 1 wherein said step of forming an intermediate concentrate composition comprises forming an intermediate concentrate composition comprising:

(i) a fire retardant comprised at least one ammonium polyphosphate; and

(ii) at least one biopolymer having a weight average particle diameter less than about 100 microns, wherein each of said at least one biopolymer is selected from the group consisting of xanthan, welan and rhamsan biopolymers.

10. The method of claim 1 wherein said step of forming an intermediate concentrate composition comprises forming an intermediate concentrate composition comprising:

(i) a fire retardant comprised at least one ammonium polyphosphate; and

(ii) at least one xanthan biopolymer having a weight average particle diameter less than about 100 microns.

11. The method of claim 1 wherein said step of diluting said intermediate concentrate with water to form said fire retardant composition comprises diluting said intermediate concentrate with water such that said fire retardant composition comprises from about 0.00224% by weight to about 1.12% by weight said biopolymer after said dilution step.

12. The method of claim 1 wherein said step of diluting said intermediate concentrate with water to form said fire retardant composition comprises diluting said intermediate concentrate with water such that said fire retardant composition comprises at least about 0.112% by weight said biopolymer after said dilution step.

13. The method of claim 1 wherein said step of diluting said intermediate concentrate with water to form said fire retardant composition comprises diluting said intermediate concentrate with water such that said fire retardant composition comprises about 0.112% by weight said biopolymer after said dilution step.

14. The method of claim 1 wherein said step of diluting said intermediate concentrate with water to form said fire retardant composition comprises diluting said intermediate concentrate with water such that said fire retardant composition comprises at least about 0.672% by weight said biopolymer after said dilution step.

15. The method of claim 1 wherein said step of diluting said intermediate concentrate with water to form said fire retardant composition comprises diluting said intermediate concentrate with water such that said fire retardant composition comprises at least about 0.224% by weight said biopolymer after said dilution step.

16. The method of claim 1 wherein said step of forming an intermediate concentrate composition comprises forming an intermediate concentrate composition comprising at least about 0.5% by weight said biopolymer.

17. A method of preparing a fire retardant composition, adapted for aerial application to wildland fires, the method comprising the steps of:

(a) forming an intermediate concentrate composition comprising:

(i) a fire retardant comprised at least one ammonium polyphosphate; and

(ii) a xanthan biopolymer having a weight average particle diameter of less than about 100 microns;

wherein said intermediate concentrate composition comprises from about 0.01% by weight to about 5.0% by weight said xanthan biopolymer; and

(b) diluting said intermediate concentrate with water to form said fire retardant composition.

Assignments (11)
RELEASE OF SECURITY INTEREST IN PATENTS (FIRST LIEN) Recorded Nov 10, 2021
From: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT
To: PERIMETER SOLUTIONS LP (F/K/A ICL PERFORMANCE PRODUCTS LP)
Reel/Frame 058843/0399 →
RELEASE OF SECURITY INTEREST IN PATENTS (SECOND LIEN) Recorded Nov 10, 2021
From: GOLDMAN SACHS BANK USA, AS ADMINISTRATIVE AGENT
To: PERIMETER SOLUTIONS LP (F/K/A ICL PERFORMANCE PRODUCTS LP)
Reel/Frame 058842/0769 →
PATENT SECURITY AGREEMENT Recorded Nov 9, 2021
From: PERIMETER SOLUTIONS LP
To: MORGAN STANLEY SENIOR FUNDING, INC., AS ADMINISTRATIVE AGENT
Reel/Frame 058083/0729 →
NOTES PATENT SECURITY AGREEMENT Recorded Nov 9, 2021
From: PERIMETER SOLUTIONS LP
To: U.S. BANK NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 058083/0822 →
SECOND LIEN PATENT SECURITY AGREEMENT Recorded Jun 20, 2018
From: PERIMETER SOLUTIONS LP (F/K/A ICL PERFORMANCE PRODUCTS LP)
To: GOLDMAN SACHS BANK USA, AS ADMINISTRATIVE AGENT
Reel/Frame 046397/0409 →
FIRST LIEN PATENT SECURITY AGREEMENT Recorded Jun 20, 2018
From: PERIMETER SOLUTIONS LP (F/K/A ICL PERFORMANCE PRODUCTS LP)
To: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT
Reel/Frame 046397/0418 →
RELEASE OF SECURITY INTEREST Recorded May 18, 2018
From: CITICORP USA, INC.
To: ICL PERFORMANCE PRODUCTS LP (SUCCESSOR-IN-INTEREST TO ASTARIS LLC)
Reel/Frame 045841/0127 →
CHANGE OF NAME Recorded Apr 25, 2018
From: ICL PERFORMANCE PRODUCTS LP
To: PERIMETER SOLUTIONS LP
Reel/Frame 046298/0785 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 14, 2006
From: ASTARIS LLC
To: ICL PERFORMANCE PRODUCTS LP
Reel/Frame 018385/0220 →
SECURITY INTEREST Recorded Mar 9, 2005
From: ASTARIS LLC, LIMITED LIABILITY COMPANY DELAWARE; ASTARIS PRODUCTION LLC, A DELAWARE LIMITED LIABILITY COMPANY; ASTARIS INTERNATIONAL LLC A DELAWARE LIMITED LIABILITY COMPANY
To: CITICORP USA, INC.,
Reel/Frame 015861/0384 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 5, 2004
From: VANDERSALL, HOWARD L.; KEGELER, GARY H.
To: ASTARIS, LLC
Reel/Frame 014633/0283 →