Negative-working thermal lithographic printing plate precursor comprising a smooth aluminum support
View Patent ↗A negative-working lithographic printing plate precursor is disclosed which comprises a grained and anodized aluminum support having a hydrophilic surface and a heat-sensitive coating provided on the hydrophilic surface, the coating comprising hydrophobic thermoplastic polymer particles which are capable of forming a hydrophobic phase in the coating by heat-induced coalescence of the polymer particles. The support is characterized by a surface roughness, expressed as arithmetical mean center-line roughness Ra, which is less than 0.45 μm. The smooth surface enables to prepare a lithographic printing plate from the mentioned precursor, which is characterized by a high run length during printing.
1. A negative-working lithographic priming plate precursor comprising
a grained and anodized aluminum support having a hydrophilic surface;
a heat-sensitive coating provided on the hydrophilic surface, said coating consisting essentially of hydrophobic thermoplastic polymer particles which are capable of forming a hydrophobic phase in said coating by heat-induced coalescence of said polymer particles and an anionic infrared light absorbing cyanine dye; and optionally one or more of binders, surfactants, colorants, development inhibitors or accelerators, and light-to-heat converting compounds;
wherein the hydrophilic surfacc has a surface roughness, expressed as arithmetical mean center-line rougbness Ra, which is less than 0.45 μm, and the aluminum support comprises more than 2.5 g/m 2 of aluminum oxide at the hydrophilic surface.
2. A plate precursor according to claim 1 wherein the hydrophilic surface has a surface roughness, expressed as arithmetical mean center-line roughness Ra, which is less than 0.4 μm.
3. A plate precursor according to claim 1 wherein the hydrophilic surface has a surface roughness, expressed as arithmetical mean center-line roughness Ra, which is less than 0.3 μm.
4. A plate precursor according to claim 1 wherein the aluminum support comprises more than 3.5 g/m 2 of aluminum oxide at the hydrophilic surface.
5. A plate precursor according to claim 1 wherein the hydrophobic thermoplastic polymer is a homopolymer or a copolymer of (meth)acrylonitrile and/or styrene.
6. A plate precursor according to claim 1 wherein the hydrophobic thermoplastic polymer comprises sulfonamide and/or phthalimide pendant groups.
7. A plate precursor according to claim 1 wherein the heat-sensitive coating further comprises a hydrophilic polymeric binder comprising carboxylic pendant groups.
8. A plate precursor according to claim 1 wherein the heat-sensitive coating further comprises a visible light absorbing dye or pigment.
9. A plate precursor according to claim 1 wherein the hydrophilic surface is hydrophilized by treatment with (i) an organic acid and/or a salt thereof or with (ii) a polymer selected from the group consisting of polyvinylphosphonic acid, polyvinylmethylphosphonic acid, phosphoric acid esters of polyvinyl alcohol, polyvinylsulfonic acid, polyvinylbenzenesulfonic acid, sulfuric acid esters of polyvinyl alcohol, and the product of the reaction of polyvinylalcohol with a sulfonated aliphatic aldehyde.
10. A method of making a lithographic printing plate comprising the steps of
image-wise exposing a plate precursor according to claim 1 to heat or to infrared light, thereby inducing coalescence of the hydrophobic thermoplastic polymer particles at exposed areas;
developing the exposed plate precursor by supplying to the coating a liquid comprising a hydrophilic phase, thereby removing the coating from the support at non-exposed areas, said liquid being selected from the group consisting of water, an aqueous liquid, gum, fountain and single-fluid ink.
11. A method according to claim 10 wherein the steps of exposing and developing are performed while the plate precursor is mounted on a cylinder of a lithographic printing press.
12. A method according to claim 10 further comprising the step of subjecting the developed plate precursor to a baking treatment at a temperature above 60° C.
13. A method of lithographic printing comprising the steps of
making a lithographic printing plate according to the method of claim 12 ;
printing at least 300,000 copies with the lithographic printing plate thus obtained.
14. A method of lithographic printing comprising the steps of
making a lithographic printing plate according to the method of claim 10 ;
printing at least 60,000 copies with the lithographic printing plate thus obtained.
15. A method of lithographic printing comprising the steps of
making a lithographic printing plate according to the method of claim 10 ;
printing at least 100,000 copies with the lithographic printing plate thus obtained.