Electrode-electrolyte composites having discrete regions
View Patent ↗Various embodiments of the invention are directed towards electrode-electrolyte composites. The electrode-electrolyte composites comprise electrode material and electrolyte material. At least a portion of the electrode material is present as a plurality of discrete regions having conductive contact with the electrolyte material.
1. An electrode-electrolyte composite, comprising:
anode material;
cathode material and
electrolyte material;
wherein at least a portion of the anode or cathode material is present as a plurality of discrete regions having conductive contact with the electrolyte material on a single surface side of the electrolyte material,
wherein the individual discrete regions of anode or cathode material do not make contact with other individual discrete regions of the same material; and
wherein a layer of electrode material is present at least partially as an interfacial layer between the discrete regions of similar material and electrolyte material.
2. The composite of claim 1 , further comprising current collectors in electrical contact with each of the individual discrete regions of a particular material.
3. A fuel cell comprising the composite of claim 1 .
4. The composite of claim 1 wherein the individual discrete regions on average occupy an area of about 10 to about 99% of the single surface side of the electrolyte material.
5. The composite of claim 1 wherein the individual discrete regions on average occupy an area of about 75 to about 90% of the single surface side of the electrolyte material.
6. An electrochemical apparatus, comprising:
a stack of two or more fuel cell components comprised of electrode and electrolyte material;
wherein the electrode material is deposited in at least one or more areas on a single surface side of the electrolyte material as two or more discrete regions of at least one of anode or cathode material each having conductive contact with the electrolyte material and wherein each of the discrete regions within a deposit area make electrical contact with each other; and
wherein a layer of electrode material is present at least partially as an interfacial layer between the discrete regions of similar material and electrolyte material.
7. The apparatus of claim 6 wherein the individual discrete regions on average occupy an area of about 10 to about 99% of the single surface side of the electrolyte material.
8. The apparatus of claim 6 wherein the individual discrete regions on average occupy an area of about 75 to about 90% of the single surface side of the electrolyte material.
9. A method for reducing stress in a fuel cell, comprising depositing electrode material an a single electrolyte material, wherein the electrode material is deposited in at least one or more areas on a single surface side of the electrolyte material as two or more discrete regions of at least one of anode or cathode material each having conductive contact with the electrolyte material and wherein each of the discrete regions within a deposited area of either anode or cathode material make electrical contact with each other; and depositing one or more interfacial layers of material between the discrete regions of electrode material and electrolyte material.
10. The method of claim 9 wherein at least one of the interfacial layers comprises electrode material of similar material to the discrete regions and electrolyte material.
11. The method of claim 9 wherein the interfacial layers comprise at least one layer comprised of electrode material of similar material to the discrete regions and electrolyte material and at least one other layer of differing composition.
12. The method of claim 9 wherein the individual discrete regions of anode or cathode material do not make contact with other individual discrete regions of the same material.
13. The method of claim 9 further comprising current collectors.
14. The method of claim 9 wherein the current collectors make electrical contact with each of the individual discrete regions of a particular material.
15. The method of claim 9 wherein the individual discrete regions on average occupy an area of about 10 to about 99% of the single surface side of the electrolyte material.
16. The method of claim 9 wherein the individual discrete regions on average occupy an area of about 75 to about 90% of the single surface side of the electrolyte material.