Preparation and use of iminodisuccinic acid ammonium metal salts
View Patent ↗The invention relates to a process for the preparation of iminodisuccinic acid ammonium metal salts, characterized in that, in a first stage, maleic anhydride (MA), alkali metal hydroxide and water are mixed in the molar ratio of 2:0–3:5–30 and then ammonia is metered in in the ratio MA: ammonia 2:1.5–8, in order to obtain iminodisuccinic acid ammonium salts which, in a second stage, are reacted with metal oxides, metal hydroxides (and) or other metal salts or their mixtures to give iminodisuccinic acid ammonium metal salts of the formula 8, IDA(NH 4 ) x (Na) y (K) z (Me) m .(NH 3 ) n Formula 8 in which IDA represents iminodisuccinic acid moiety, x=0.1–3.9 y=0–3 z=0–3 m=0.1–2 n=0–6 and Me represents metals of the IInd, IIIrd and IVth main groups and of the Ist to VIIIth subgroups as well as metals of the lanthanide series, of the Periodic Table, which can occur in the oxidation states 1, 2, 3 or 4, the compounds themselves and their intermediates and the use.
1. Process for the preparation of iminodisuccinic acid ammonium metal salts, comprising:
in a first stage, mixing maleic anhydride (MA), alkali metal hydroxide and water in a molar ratio of 2:0–3:5–30 and then metering ammonia into the resulting reaction mixture in a molar ratio of MA:ammonia 2:1.5–8, in order to obtain iminodisuccinic acid ammonium salts of the formula 6
IDA(NH 4 ) x (Na) y (K) z (H) m Formula 6
wherein IDA represents iminodisuccinic acid moiety, with x=0.1–4, y=0–3, z=0–3 and m=0–2,
in a second stage, reacting the iminodisuccinic acid ammonium salts with metal oxides, metal hydroxides or metal salts or their mixtures to give iminodisuccinic acid ammonium metal salts of the formula 8,
IDA(NH 4 ) x (Na) y (K) z (Me) m . (NH 3 ) n Formula 8
in which
IDA is the iminodisuccinic acid moiety
x=0.1–3.9
y=0–3
z=0–3
m=0.1–2
n=0–6
and
Me represents metals of the IInd, IIIrd and IVth main groups and of the Ist to VIIIth subgroups as well as metals of the lanthanide series of the Periodic Table, which can occur in the oxidation states 1, 2, 3 or 4.
2. Process according to claim 1 wherein, ammonia is metered into the reaction mixture which is in the form of suspensions or solutions comprising maleic acid or maleic acid salt(s) in the MA:ammonia molar ratio of 2:1.5–8.
3. Iminodisuccinic acid ammonium metal salts of the formula 8
IDA(NH 4 ) x (Na) y (K) z (Me) m (NH 3 ) n Formula 8
wherein
IDA is the iminodisuccinic acid moiety
x=0.1–3.9
y=0–3
z=0–3
m=0.1–2
n=0–6,
and
Me represents metals of the IInd, IIIrd and IVth main groups and of the Ist to VIIIth subgroups as well as metals of the lanthanide series of the Periodic Table, which can occur in the oxidation states 1, 2, 3 or 4, with the exception of the S,S isomers of the Mg and Ca iminodisuccinic acid ammonium metal salts.
4. Iminodisuccinic acid ammonium metal salts of the formula (8) according to claim 3 , wherein Me represents Mg, Ca, Sr, Ba, Ti, Zr, Cr, Mo, W, Mn, Fe, Co, Ni, Cu, Ag, Zn, Cd, Al, Sn, Pb, La or Ce, with the exception of the S,S isomers of the Ca and Mg iminodisuccinic acid ammonium metal salts.