Methods of processing nickel-titanium alloys
View Patent ↗Embodiments of the present invention provide methods of processing nickel-titanium alloys including from greater than 50 up to 55 atomic percent nickel to provide a desired austenite transformation temperature and/or austenite transformation temperature range. In one embodiment, the method comprises selecting a desired austenite transformation temperature, and thermally processing the nickel-titanium alloy to adjust an amount of nickel in solid solution in a TiNi phase of the alloy such that a stable austenite transformation temperature is reached, wherein the stable austenite transformation temperature is essentially equal to the desired austenite transformation temperature.
1. A method of processing a nickel-titanium alloy comprising from greater than 50 up to 55 atomic percent nickel to provide a desired austenite transformation temperature, the method comprising:
selecting the desired austenite transformation temperature; and
thermally processing the nickel-titanium alloy to adjust an amount of nickel in solid solution in a TiNi phase of the alloy such that a stable austenite transformation temperature is reached during thermally processing the nickel-titanium alloy, wherein the stable austenite transformation temperature is essentially equal to the desired austenite transformation temperature,
wherein the nickel-titanium alloy comprises sufficient nickel to reach a solid solubility limit during thermally processing the nickel-titanium alloy.
2. The method of claim 1 , wherein the desired austenite transformation temperature ranges from −100° C. to 100° C.
3. The method of claim 1 , wherein after thermally processing the nickel-titanium alloy, the stable austenite transformation temperature of the nickel-titanium alloy is independent of overall composition of the nickel-titanium alloy.
4. The method of claim 1 , wherein thermally processing the nickel-titanium alloy includes isothermally aging the nickel-titanium alloy.
5. The method of claim 4 , wherein the nickel-titanium alloy is isothermally aged at a temperature of 500° C. to 800° C.
6. The method of claim 1 , wherein thermally processing the nickel-titanium alloy includes isothermally aging the nickel-titanium alloy for at least 2 hours.
7. The method of claim 1 , wherein thermally processing the nickel-titanium alloy includes isothermally aging the nickel-titanium alloy for at least 24 hours.
8. The method of claim 1 , wherein thermally processing the nickel-titanium alloy includes aging the nickel-titanium alloy at a first aging temperature and subsequently aging the nickel-titanium alloy at a second aging temperature, the first aging temperature being higher than the second aging temperature.
9. The method of claim 8 , wherein the first aging temperature ranges from 600° C. to 800° C. and the second aging temperature ranges from 500° C. to 600° C.
10. The method of claim 8 , wherein the nickel-titanium alloy reaches the stable austenite transformation temperature during aging at the second aging temperature.
11. The method of claim 1 , wherein thermally processing the nickel-titanium alloy includes aging the nickel-titanium alloy at a first aging temperature and subsequently aging the nickel-titanium alloy at a second aging temperature, the first aging temperature being lower than the second aging temperature.
12. The method of claim 11 , wherein the first aging temperature ranges from 500° C. to 600° C. and the second aging temperature ranges from 600° C. to 800° C.
13. The method of claim 11 , wherein the nickel-titanium alloy reaches the stable austenite transformation temperature during aging at the second aging temperature.
14. The method of claim 1 , wherein the nickel-titanium is a binary nickel-titanium alloy.
15. The method of claim 1 , wherein the nickel-titanium alloy further comprises at least one additional alloying element.
16. The method of claim 15 , wherein the at least one additional alloying element is selected from the group consisting of copper, iron, and hafnium.
17. A method of processing a nickel-titanium alloy to provide a desired austenite transformation temperature, the method comprising:
selecting a nickel-titanium alloy comprising from greater than 50 up to 55 atomic percent nickel;
selecting the desired austenite transformation temperature; and
thermally processing the selected nickel-titanium alloy to adjust an amount of nickel in solid solution in a TiNi phase of the alloy such that a stable austenite transformation temperature is reached during thermally processing the selected nickel-titanium alloy, the stable austenite transformation temperature being essentially equal to the desired austenite transformation temperature; and
wherein the selected nickel-titanium alloy comprises sufficient nickel to reach a solid solubility limit during thermally processing the selected nickel-titanium alloy.
18. The method of claim 17 , wherein after thermally processing the nickel-titanium alloy, the stable austenhte transformation temperature of the nickel-titanium alloy is independent of overall composition of the nickel-titanium alloy.
19. A method of processing a nickel-titanium alloy comprising from greater than 50 up to 55 atomic percent nickel to achieve a desired austenite transformation temperature range, the method comprising isothermally aging the nickel-titanium alloy in a furnace at a temperature ranging from 500° C. to 800° C. for at least 2 hours, wherein after aging the nickel-titanium alloy has an austenite transformation temperature range no greater than 15° C.
20. The method of claim 19 , wherein after aging the austenite transformation temperature range is no greater than 10° C.
21. The method of claim 19 , wherein after aging the austenite transformation temperature range is no greater than 6° C.
22. The method of claim 19 , wherein the nickel-titanium alloy is a binary nickel-titanium alloy.
23. The method of claim 19 , wherein the nickel-titanium alloy further comprises at least one additional alloying element.
24. The method of claim 23 , wherein the at least one additional alloying element is selected from the group consisting of copper, iron, and hafnium.
25. A method of processing a nickel-titanium alloy comprising from greater than 50 up to 55 atomic percent nickel to achieve a desired austenite transformation temperature range, the method comprising:
aging the nickel-titanium alloy in a furnace at a first aging temperature to achieve a stable auslenite transformation temperature; and
aging the nickel-titanium alloy at a second aging temperature that is different than the first aging temperature, wherein after aging at the second aging temperature, the nickel-titanium alloy has an austenite transformation temperature range that is essentially equal to the desired transformation temperature range.
26. The method of claim 25 , wherein the second aging temperature is lower than the first aging temperature.
27. The method of claim 25 , wherein the second aging temperature is higher than the first aging temperature.
28. The method of claim 25 , wherein the austenite transformation temperature range achieved after aging the nickel-titanium alloy at the second aging temperature is greater than an austenite transformation temperature range achieved after aging the nickel-titanium alloy at the first aging temperature.