Active topical skin protectants containing amines, polyalkenimines and /or derivatives

1. A topical skin protectant formulation comprising:

one or more of the following formulations:

formulation 1

a) about 10 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 7 wt % water and

d) about 48 wt % perfluoropolyether; and

e) about 32 wt % poly(tetrafluoroethylene);

formulation 2

a) about 7 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 3 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 10 wt % water and

d) about 48 wt % perfluoropolyether; and

e) about 32 wt % poly(tetrafluoroethylene);

formulation 3

a) about 20 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 3 wt % water and

d) about 60 wt % perfluoropolyether; and

e) about 15 wt % poly(tetrafluoroethylene);

formulation 4

a. about 25 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b. about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c. about 7 wt % water and

d. about 45 wt % perfluoropolyether; and

e. about 21 wt % poly(tetrafluoroethylene);

formulation 5

a) about 25 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 5 wt % water and

d) about 43 wt % perfluoropolyether; and

e) about 25 wt % poly(tetrafluoroethylene);

formulation 6

a) about 25 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 3 wt % water and

d) about 40 wt % perfluoropolyether; and

e) about 30 wt % poly(tetrafluoroethylene);

formulation 7

a) about 25 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 8 wt % water and

d) about 35 wt % perfluoropolyether; and

e) about 30 wt % poly(tetrafluoroethylene);

formulation 8

a) about 10 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 10 wt % water, and

c) about 55 wt % perfluoropolyether; and

d) about 25 wt % poly(tetrafluoroethylene);

formulation 9

a) about 20 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 40 wt % perfluoropolyether; and

c) about 40 wt % poly(tetrafluoroethylene);

formulation 10

a. about 26 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b. about 3 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c. about 38 wt % perfluoropolyether; and

d. about 33 wt % poly(tetrafluoroethylene);

formulation 11

a) about 26 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 38 wt % perfluoropolyether; and

d) about 33 wt % poly(tetrafluoroethylene);

formulation 12

a) about 15 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 44 wt % perfluoropolyether; and

d) about 36 wt % poly(tetrafluoroethylene), and

e) about 5 wt % water;

formulation 13

a) about 19 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 44 wt % perfluoropolyether; and

d) about 36 wt % poly(tetrafluoroethylene);

formulation 14

a) about 24 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 35 wt % perfluoropolyether; and

d) about 30 wt % poly(tetrafluoroethylene), and

e) about 9 wt % water;

formulation 15

a) about 10 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 8 wt % water, and

d) about 40 wt % perfluoropolyether; and

e) about 40 wt % poly(tetrafluoroethylene);

formulation 16

a) about 10 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 13 wt % water, and

d) about 40 wt % perfluoropolyether; and

e) about 35 wt % poly(tetrafluoroethylene);

formulation 17:

a. about 10 wt % of polyaziridine of average molecular weight of 25,000, and

b. about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c. about 14 wt % water, and

d. about 40 wt % perfluoropolyether; and

e. about 35 wt % poly(tetrafluoroethylene);

formulation 18

a) about 15 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 5 wt % water, and

d) about 44 wt % perfluoropolyether; and

e) about 35 wt % poly(tetrafluoroethylene);

formulation 19

a) about 26 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 38 wt % perfluoropolyether; and

d) about 33 wt % poly(tetrafluoroethylene);

formulation 20

a) about 26 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 3 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 38 wt % perfluoropolyether; and

d) about 33 wt % poly(tetrafluoroethylene);

formulation 21

a) about 21 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 5 wt % 1, 3-pentanediamine, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 22

a) about 10 wt % of polyaziridine of average molecular weight of 1300, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 8 wt % water and

d) about 40 wt % perfluoropolyether; and

e) about 40 wt % poly(tetrafluoroethylene);

formulation 23

a) about 10 wt % polyaziridine of average molecular weight of 1300, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 5 wt % water and

d) about 40 wt % perfluoropolyether; and

e) about 43 wt % poly(tetrafluoroethylene);

formulation 24

a) about 10 wt % polyaziridine of average molecular weight of 1300, and

b) about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 6 wt % water and

d) about 40 wt % perfluoropolyether; and

e) about 43 wt % poly(tetrafluoroethylene);

formulation 25

a) about 15 wt % polyaziridine of average molecular weight of 1300, and

b) about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 5 wt % water and

d) about 36 wt % perfluoropolyether; and

e) about 43 wt % poly(tetrafluoroethylene);

formulation 26

a) about 26 wt % polyaziridine of average molecular weight of 1300, and

b) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 38 wt % perfluoropolyether; and

d) about 33 wt % poly(tetrafluoroethylene);

formulation 27:

a) about 26 wt % polyaziridine of average molecular weight of 1300, and

b) about 3 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 38 wt % perfluoropolyether; and

d) about 33 wt % poly(tetrafluoroethylene);

formulation 28

a) about 10 wt % hydroxyethylated polyaziridine with average molecular weight of 110,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 40 wt % perfluoropolyether; and

d) about 45 wt % poly(tetrafluoroethylene), and

e) about 3 wt % water;

formulation 29

a) about 10 wt % hydroxyethylated polyaziridine with average molecular weight of 110,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 8 wt % water and

d) about 40 wt % perfluoropolyether; and

e) about 40 wt % poly(tetrafluoroethylene);

formulation 30

a) about 10 wt % hydroxyethylated polyaziridine with average molecular weight of 110,000, and

b) about 1 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 9 wt % water and

d) about 40 wt % perfluoropolyether; and

e) about 40 wt % poly(tetrafluoroethylene);

formulation 31

a) about 15 wt % hydroxyethylated polyaziridine with average molecular weight of 110,000, and

b) about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 5 wt % water and

d) about 35 wt % perfluoropolyether; and

e) about 44 wt % poly(tetrafluoroethylene);

formulation 32

a) about 15 wt % hydroxyethylated polyaziridine with average molecular weight of 110,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 5 wt % water and

d) about 34 wt % perfluoropolyether; and

e) about 44 wt % poly(tetrafluoroethylene);

formulation 33

a) about 26 wt % hydroxyethylated polyaziridine with average molecular weight of 110,000, and

b) about 3 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 38 wt % perfluoropolyether; and

d) about 33 wt % poly(tetrafluoroethylene);

formulation 34

a. about 26 wt % hydroxyethylated polyaziridine with average molecular weight of 110,000, and

b. about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c. about 38 wt % perfluoropolyether; and

d. about 33 wt % poly(tetrafluoroethylene);

formulation 35

a) about 26 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

b) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 38 wt % perfluoropolyether; and

d) about 33 wt % poly(tetrafluoroethylene);

formulation 36

a) about 26 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

b) about 3 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 38 wt % perfluoropolyether; and

d) about 33 wt % poly(tetrafluoroethylene);

formulation 37

a) about 21 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

b) about 5 wt % 1, 3-pentanediamine, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 38

a) about 17 wt % of a 15:80:5 wt % mixture of formamide polyaziridine, water, and sodium formate, and

b) about 2 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 4 wt % water and

d) about 31 wt % perfluoropolyether; and

e) about 46 wt % poly(tetrafluoroethylene);

formulation 39

a) about 23 wt % of a 15:80:5 wt % mixture of formamide polyaziridine, water, and sodium formate, and

b) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 35 wt % perfluoropolyether; and

d) about 40 wt % poly(tetrafluoroethylene);

formulation 40

a) about 20 wt % of a 15:80:5 wt % mixture of formamide polyaziridine, water, and sodium formate, and

b) about 1 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 5 wt % water and

d) about 38 wt % perfluoropolyether; and

e) about 35 wt % poly(tetrafluoroethylene);

formulation 41

a) about 25 wt % of a 15:80:5 wt % mixture of formamide polyaziridine, water, and sodium formate, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 38 wt % perfluoropolyether; and

d) about 35 wt % poly(tetrafluoroethylene);

formulation 42

a) about 13 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

b) about 13 wt % of polyaziridine of average molecular weight of 25,000, and

c) about 1.5 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

d) about 1.5 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

e) about 38 wt % perfluoropolyether; and

f) about 33 wt % poly(tetrafluoroethylene);

formulation 43

a) about 5 wt % 1,3-pentanediamine, and

b) about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 49 wt % perfluoropolyether; and

d) about 45 wt % poly(tetrafluoroethylene);

formulation 44:

a) about 5 wt % 1,3-pentanediamine, and

b) about 1 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 49 wt % perfluoropolyether; and

d) about 45 wt % poly(tetrafluoroethylene);

formulation 45

a) about 13 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 13 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 46

a) about 13 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 13 wt % polyaziridine of average molecular weight of 1300, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 47

a) about 13 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 13 wt % hydroxyethylated polyaziridine with average molecular weight of 110,000, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 48

a) about 13 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 13 wt % of polyaziridine of average molecular weight of 25,000, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 49

a) about 13 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 13 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 50

a) about 14 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 13 wt % polyaziridine of average molecular weight of 1300, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 51

a) about 13 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 13 wt % hydroxyethylated polyaziridine with average molecular weight of 110,000, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 52

a) about 13 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

b) about 13 wt % hydroxyethylated polyaziridine with average molecular weight of 110,000, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 53

a) about 13 wt % hydroxyethylated polyaziridine with average molecular weight of 110,000, and

b) about 13 wt % polyaziridine of average molecular weight of 1300, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 54

a) about 11 wt % polyaziridine of average molecular weight of 1300, and

b) about 12 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n (CH 2 ) m —H, and

d) about 34 wt % perfluoropolyether; and

e) about 40 wt % poly(tetrafluoroethylene);

formulation 55

a) about 13 wt % of a 15:80:5 wt % mixture of formamide polyaziridine, water, and sodium formate, and

b) about 13 wt % polyaziridine of average molecular weight of 1300, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 56

a) about 13 wt % of a 15:80:5 wt % mixture of formamide polyaziridine, water, and sodium formate, and

b) about 13 wt % of polyaziridine of average molecular weight of 25,000, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 38 wt % perfluoropolyether; and

e) about 33 wt % poly(tetrafluoroethylene);

formulation 57

a) about 11 wt % of a 15:80:5 wt % mixture of formamide polyaziridine, water, and sodium formate, and

b) about 12 wt % hydroxyethylated polyaziridine with average molecular weight of 110,000, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 34 wt % perfluoropolyether; and

e) about 41 wt % poly(tetrafluoroethylene);

formulation 58

a) about 12 wt % of a 15:80:5 wt % mixture of formamide polyaziridine, water, and sodium formate, and

b) about 12 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 35 wt % perfluoropolyether; and

e) about 38 wt % poly(tetrafluoroethylene);

formulation 59

a) about 12 wt % of a 15:80:5 wt % mixture of formamide polyaziridine, water, and sodium formate, and

b) about 12 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

c) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

d) about 36 wt % perfluoropolyether; and

e) about 37 wt % poly(tetrafluoroethylene);

formulation 60

a) about 23 wt % of a 50.4 weight % aqueous solution of homopolymer of 2-propene-1-amine hydrochloride, and

b) about 3 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 34 wt % perfluoropolyether; and

d) about 41 wt % poly(tetrafluoroethylene);

formulation 61

a) about 26 wt % of a 50.4 weight % aqueous solution of homopolymer of 2-propene-1-amine hydrochloride, and

b) about 3 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 38 wt % perfluoropolyether; and

d) about 33 wt % poly(tetrafluoroethylene);

formulation 62

a) about 19 wt % of a 10.3 weight % aqueous solution of homopolymer of 2-propene-1-amine, and

b) about 1 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 28 wt % perfluoropolyether; and

d) about 52 wt % poly(tetrafluoroethylene);

formulation 63

a) about 18 wt % of a 10.3 weight % aqueous solution of homopolymer of 2-propene-1-amine, and

b) about 2 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 25 wt % perfluoropolyether; and

d) about 55 wt % poly(tetrafluoroethylene);

formulation 64

a) about 12 wt % of a 10.3 weight % aqueous solution of homopolymer of 2-propene-1-amine, and

b) about 12 wt % of a 50.4 weight % aqueous solution of homopolymer of 2-propene-1-amine hydrochloride, and

c) about 3 wt % Fluorolink 7005, and

d) about 34 wt % perfluoropolyether; and

e) about 40 wt % poly(tetrafluoroethylene);

formulation 65

a) about 2 wt % DEAM (diethanolamine), and

b) about 1 wt % Surfactant, and

c) about 1 wt % water, and

d) about 49 wt % perfluoropolyether; and

e) about 46 wt % poly(tetrafluoroethylene);

formulation 66

a) about 2 wt % DEAM, and

b) about 1 wt % Surfactant, and

c) about 1 wt % water, and

d) about 48 wt % perfluoropolyether; and

e) about 48 wt % poly(tetrafluoroethylene);

formulation 67

a) about 2 wt % DEAM, and

b) about 1 wt % Surfactant, and

c) about 1 wt % water, and

d) about 49 wt % perfluoropolyether; and

e) about 47 wt % poly(tetrafluoroethylene);

formulation 68

a) about 13 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 13 wt % polyaziridine of average molecular weight of 1300, and

c) about 1.5 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

d) about 1.5 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

e) about 38 wt % perfluoropolyether; and

f) about 33 wt % poly(tetrafluoroethylene);

formulation 69

a) about 13 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 13 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

c) about 1.5 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

d) about 1.5 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

e) about 38 wt % perfluoropolyether; and

f) about 33 wt % poly(tetrafluoroethylene);

formulation 70

a) about 13 wt % polyaziridine of average molecular weight of 1300, and

b) about 2 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 44 wt % perfluoropolyether; and

d) about 42 wt % poly(tetrafluoroethylene);

formulation 71

a) about 6 wt % polyaziridine of average molecular weight of 1300, and

b) about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 47 wt % perfluoropolyether; and

d) about 46 wt % poly(tetrafluoroethylene);

formulation 72

a) about 13 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 2 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 44 wt % perfluoropolyether; and

d) about 42 wt % poly(tetrafluoroethylene);

formulation 73

a) about 6 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 47 wt % perfluoropolyether; and

d) about 46 wt % poly(tetrafluoroethylene);

formulation 74

a) about 14 wt % polyaziridine of average molecular weight of 1300, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 43 wt % perfluoropolyether; and

d) about 41 wt % poly(tetrafluoroethylene);

formulation 75

a) about 7 wt % polyaziridine of average molecular weight of 1300, and

b) about 1 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 47 wt % perfluoropolyether; and

d) about 45 wt % poly(tetrafluoroethylene);

formulation 76

a) about 13 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 44 wt % perfluoropolyether; and

d) about 42 wt % poly(tetrafluoroethylene);

formulation 77

a) about 7 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 47 wt % perfluoropolyether; and

d) about 46 wt % poly(tetrafluoroethylene);

formulation 78

a) about 13 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

b) about 2 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m ,—(OCH 2 CH 2 ) n —(CH 2 ) m —H with molecular weight range 1500-1700, and

c) about 44 wt % perfluoropolyether; and

d) about 41 wt % poly(tetrafluoroethylene);

formulation 79

a) about 7 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

b) about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 47 wt % perfluoropolyether; and

d) about 46 wt % poly(tetrafluoroethylene);

formulation 80

a) about 7 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

b) about 7 wt % of polyaziridine of average molecular weight of 25,000, and

c) about 1 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

d) about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

e) about 44 wt % perfluoropolyether; and

f) about 42 wt % poly(tetrafluoroethylene);

formulation 81

a) about 3 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

b) about 3 wt % of polyaziridine of average molecular weight of 25,000, and

c) about 0.5 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

d) about 0.5 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

e) about 49 wt % perfluoropolyether; and

f) about 47 wt % poly(tetrafluoroethylene);

formulation 82

a) about 13 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 1.5 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 45 wt % perfluoropolyether; and

d) about 41 wt % poly(tetrafluoroethylene);

formulation 83

a) about 6 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 1 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m (OCH 2 CH 2 ) n —(CH 2 ) m —H, and

c) about 48 wt % perfluoropolyether; and

d) about 45 wt % poly(tetrafluoroethylene)

formulation 84

a) about 15 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 51 wt % perfluoropolyether; and

d) about 33 wt % poly(tetrafluoroethylene);

formulation 85

a) about 14 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 48 wt % perfluoropolyether; and

d) about 36 wt % poly(tetrafluoroethylene);

formulation 86

a) about 17 wt % of polyaziridine of average molecular weight of 25,000, and

b) about 1 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 50 wt % perfluoropolyether; and

d) about 41 wt % poly(tetrafluoroethylene);

formulation 87

a) about 7 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 1 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 49 wt % perfluoropolyether; and

d) about 43 wt % poly(tetrafluoroethylene);

formulation 88

a) about 13 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 13 wt % of polyaziridine of average molecular weight of 25,000, and

c) about 1.5 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH with molecular weight of 600-700)], and

d) about 1.5 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

e) about 38 wt % perfluoropolyether; and

about 33 wt % poly(tetrafluoroethylene);

formulation 89

a) about 13 wt % polyaziridine of average molecular weight of 1300, and

b) about 13 wt % of ethylenediamine-aziridine copolymer of average molecular weight of 800, and

c) about 1.5 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

d) about 1.5 wt % of Cl(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

e) about 38 wt % perfluoropolyether; and

f) about 33 wt % poly(tetrafluoroethylene);

formulation 90

a) about 13 wt % polyaziridine of average molecular weight of 1300, and

b) about 13 wt % of polyaziridine of average molecular weight of 25,000, and

c) about 1.5 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

d) about 1.5 wt % of Cl—(C 3 F 6 O) n —CF 2 —CONH(CH 2 ) m —(OCH 2 CH 2 ) n —(CH 2 ) m —H, and

e) about 38 wt % perfluoropolyether; and

d) about 33 wt % poly(tetrafluoroethylene);

formulation 91

a) about 10 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 2 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 —COOH], and

c) about 7 wt % water, and

d) about 38 wt % perfluoropolyether; and

e) about 43 wt % poly(tetrafluoroethylene); and

formulation 92

a) about 15 wt % of a 50:50 mixture of water and aziridine homopolymer of average molecular weight of 750,000, and

b) about 3 wt % of Poly(hexafluoropropylene oxide) monocarboxylic acid, chloro terminated [Cl—(C 3 F 6 O) n —CF 2 ——COOH], and

c) about 6 wt % water, and

d) about 27 wt % perfluoropolyether; and

e) about 49 wt % poly(tetrafluoroethylene).

2. The topical skin protectant formulation of claim 1 , further comprising one or more additives.

3. The topical skin protectant formulation of claim 2 , wherein said additives comprise one or more of water, surfactants, including:

a. propene, 1,1,2,3,3,3-hexafluoro-, telomers with chlorotrifluoroethene, oxidized, reduced ,ethyl ester, hydrolyzed,

b. perfluoropolyether derivative is PFPE-CONH—(CH 2 ) 3 —OCH 2 CH 3 ) 18 —CH 3 ,

c. perfluoropolyether surfactant,

d. stabilizers,

e. camouflage paints, and

f. sunscreens.

4. The topical skin protectant formulation of claim 1 , having a viscosity is 20 cSt to 500 cSt.

5. The topical skin protectant formulation of claim 1 , having a surface area of 6 m 2 /g.

6. The topical skin protectant formulation of claim 1 , wherein said active moiety is in said base cream as a solid or aqueous suspension.