IP Library Granted Patent US 6,878,436
Granted Patent B2
US 6,878,436 · App. 10/431,820 · Granted Apr 12, 2005

Light emitting diode signs and translucent plastic sheets used therein

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Quick Facts
Patent No.
US 6,878,436
App. No.
10/431,820
Granted
Apr 12, 2005
Kind
B2
Abstract

Disclosed is a polished translucent co-extruded sheet having utility as a light diffusing protective cover or sign face for light emitting diode (LED) light sources and other purposes. The sheet is comprised of (a) a particle layer containing particles having a mean particle size of about 4 to 100 microns and having a particle size distribution of between 1-110 microns, at a loading of 1 to 60% melt blended with a thermoplastic matrix, wherein the particle and matrix have refractive indices that differ by greater than 0.001 units of each other when measured in conformance with ASTM D 542; and (b) at least one substrate layer comprised of thermoplastic compositions, wherein the substrates have a refractive index within 0.2 units of the refractive index of the particle layer matrix when measured in conformance with ASTM D 542.

Claims (31)

1. A light diffusing sign comprised of

(a) a light emitting diode (LED) light source; and

(b) a polished translucent co-extruded sheet comprised of

(i) a particle layer containing particles having a mean particle size of about 4 to 100 microns and having a particle size distribution of between 1-110 microns, at a loading of 1 to 60% melt blended with a thermoplastic matrix, wherein the particle and matrix have refractive indices that differ by greater than 0.001 units of each other when measured in conformance with ASTM D 542; and

(ii) at least one substrate layer comprised of a thermoplastic composition, wherein each substrate layer has a refractive index within 0.2 units of the refractive index of the particle layer matrix when measured in conformance with ASTM D 542.

2. A light diffusing sign comprised of

(a) a light emitting diode (LED) light source; and

(b) a polished translucent co-extruded sheet comprised of

(i) a particle layer, containing particles having a mean particle size of about 4 to 100 microns and having a particle size distribution of between 1-110 microns, at a loading of 1 to 60% melt blended with a thermoplastic matrix, wherein the particles and matrix have refractive indices that differ by greater than 0.001 units of each other when measured in conformance with ASTM D 542;

(ii) at least one substrate layer comprised of a thermoplastic composition on the particle layer side facing away from the LED light source, wherein each substrate has a refractive index within 0.2 units of the refractive index of the particle layer matrix when measured in conformance with ASTM D 542.

(iii) optionally, at least one substrate layer on the particle side facing the LED light source, each substrate layer comprised of a thermoplastic composition, wherein each substrate has a refractive index within 0.2 units of the refractive index of the particle layer matrix when measured in conformance with ASTM D 542.

3. A light diffusing sign comprised of

(a) a light emitting diode (LED) light source; and

(b) a polished translucent co-extruded sheet, 0.002 to 1.0 inches thick, comprised of

(i) a particle layer, 0.001 to 0.1 inches thick, containing particles having a mean particle size of about 15 to 70 microns and having a particle size distribution of between 1-110 microns, and a refraction index from 1.46 to 1.59, at a loading of 10 to 50% melt blended with a thermoplastic matrix, wherein the particles and matrix have refractive indices that differ by greater than 0.002 units of each other when measured in conformance with ASTM D 542;

(ii) at least one substrate layer comprised of a thermoplastic composition on the particle layer side facing away from the LED light source, wherein each substrate layer has a refractive index within 0.2 units of the refractive index of the particle layer matrix when measured in conformance with ASTM D 542; and

(iii) optionally, at least one substrate layer on the particle layer side facing the LED light source, each substrate layer comprised of a thermoplastic composition, wherein each substrate layer has a refractive index within 0.2 units of the refractive index of the particle layer matrix when measured in conformance with ASTM D 542.

4. The sign of claim 1 , wherein the sheet is colored.

5. The sign of claim 1 wherein the sheet is non-colored.

6. The sign of claim 1 , wherein the composition of the particles of the particle layer is 0-99.99% styrene, 0-99.99% alkyl methacrylate or alkyl acrylate, or a mixture of both, and 0.01-5% crosslinking agent and the particles have an index of refraction ranging from 1.46 to 1.59.

7. The sign of claim 6 , wherein, the matrix of the particle layer is 90-98% MMA and 2-10% EA.

8. The sign of claim 7 wherein the optional layers are each comprised of 90-98% MMA and 2-10% EA.

9. A translucent co-extruded sheet, comprised of:

(a) an interior particle layer containing particles having a mean particle size of about 4 to 100 microns, and having a particle size distribution of between 1-110 microns, at a loading of 1 to 60%, melt blended with a thermoplastic matrix, wherein the particles and matrix have refractive indices that differ by greater than 0.001 units when measured in conformance with ASTM D 542; and

(b) at least two outer substrate layers comprised of thermoplastic compositions, wherein each substrate layer has a refractive index within 0.2 units of the refractive index of the particle layer matrix when measured in conformance with ASTM D 542.

10. The sheet of claim 9 , wherein the sheet is colored.

11. The sheet of claim 9 wherein the sheet is 0.002 to 1.0 inches thick.

12. The sheet of claim 9 , wherein the composition of the particles of the particle layer is 0-99.99% styrene, 0-99.99% alkyl methacrylate or alkyl acrylate, or a mixture of both, and 0.01-5% crosslinking agent and the particles have an index of refraction ranging from 1.46 to 1.59.

13. The sheet of claim 12 , wherein, the matrix of the particle layer is 90-98% MMA and 2-10% EA.

14. The sheet of claim 9 wherein the outer layers are each comprised of 90-98% MMA and 2-10% EA.

15. The sheet of claim 9 which is tri-layered.

Assignments (6)
SECURITY INTEREST Recorded Jan 29, 2025
From: TRINSEO EUROPE GMBH
To: ALTER DOMUS (US) LLC
Reel/Frame 070048/0159 →
SECURITY INTEREST Recorded Jan 29, 2025
From: TRINSEO EUROPE GMBH
To: ALTER DOMUS (US) LLC
Reel/Frame 070048/0204 →
NUNC PRO TUNC ASSIGNMENT Recorded Jul 6, 2021
From: ARKEMA FRANCE
To: TRINSEO EUROPE GMBH
Reel/Frame 057368/0486 →
CHANGE OF NAME Recorded Jun 29, 2006
From: ARKEMA
To: ARKEMA FRANCE
Reel/Frame 017846/0717 →
CHANGE OF NAME Recorded Mar 9, 2005
From: ATOFINA
To: ARKEMA
Reel/Frame 015749/0855 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 28, 2003
From: REILLY, JACK J.; KEATING, PAUL J.; DIRKX, RYAN R.
To: ATOFINA
Reel/Frame 013683/0265 →