Dimethyl terephthalate composition and process for producing the same

1. A dimethyl terephthalate composition comprising, as a principal composition, dimethyl terephthalate, and further containing 0.001 to 200 ppm of methyl 4-(1,3-dioxolan-2-yl)benzoate and 0 to 1 ppm of dimethyl hydroxyterephthalate.

2. A method for producing a dimethyl terephthalate composition comprising, as a principal component, dimethyl terephthalate, and further containing 0.001 to 200 ppm of methyl 4-(1,3-dioxolan-2-yl)benzoate and 0 to 1 ppm of dimethyl hydroxyterephthalate, comprising: subjecting a polyalkylene terephthalate to a depolymerization reaction with ethylene glycol; subsequently subjecting the resulting mixture to a transesterification reaction with methanol, to produce crude dimethyl terephthalate and an alkylene glycol; applying a cooling treatment to the reaction mixture; carrying out operations to separate the reaction mixture into a cake of crude dimethyl terephthalate and a mixture solution by using a centrifugal separator; and then distillation-refining the cake to provide a dimethyl terephthalate composition, characterized in that the reflux ratio during the distillation-refining step is controlled to 0.1 to 2.

3. The method for producing the dimethyl terephthalate composition according to claim 2 , wherein the polyalkylene terephthalate comprises at least one member selected from the group consisting of polyethylene terephthalate, polytrimethylene terephthalate and polybutylene terephthahate.

4. A method for producing a dimethyl terephthalate composition comprising, as a principal component, dimethyl terephthalate and further containing 0.001 to 200 ppm of methyl 4-(1,3-dioxolan-2-yl)benzoate and 0 to 1 ppm of dimethyl hydroxyterephthalate, comprising: subjecting a polyalkylene terephthalate to a depolymerization reaction with ethylene glycol; subsequently subjecting the resulting mixture to a transesterification reaction with methanol, to produce crude dimethyl terephthalate and an alkylene glycol; applying a cooling treatment to the reaction mixture; separating the reaction mixture into a cake of crude dimethyl terephthalate and a mixture solution by using a centrifugal separator; and then distillation-refining the cake to provide a dimethyl terephthalate composition, characterized in that methanol is added in an amount of 1 to 5 times the mass of the cake obtained by centrifugal separating operation to the cake under conditions of 30 to 60° C.; then the resulting mixture is again subjected to a separation operations to separate a cake of dimethyl terephthalate from a mixture solution by using a centrifugal separator; and then the resultant cake is subjected to a distillation refining procedure.

5. The method for producing the dimethyl terephthalate composition according to claim 4 , wherein the polyalkylene terephthalate comprises at least one selected from the group consisting of polyethylene terephthalate, polytrimethylene terephthalate and polybutylene terephthalate.

6. A method for producing terephthalic acid, employing as a starting material, a dimethyl terephthalate composition consisting, as a principal component, dimethyl terephthalate and further containing 0.001 to 200 ppm of methyl 4-(1,3-dioxolan-2-yl)benzoate and 0 to 1 ppm of dimethyl hydroxyterephthalate.

7. A method for producing bis(β-hydroxyethyl)terephthalate, employing as a starting material, a dimethyl terephthalate composition comprising, as a principal component, dimethyl terephthalate and further containing 0.001 to 200 ppm of methyl 4-(1,3-dioxolan-2-yl)benzoate and 0 to 1 ppm of dimethyl hydroxyterephthalate.

8. A method for producing a polyalkylene terephthalate, employing, as a starting material, a dimethyl terephthalate composition consisting, as a principal component, dimethyl terephthalate and further containing 0.001 to 200 ppm of methyl 4-(1,3-dioxolan-2-yl)benzoate and 0 to 1 ppm of dimethyl hydroxyterephthalate.