Use of branched polyacids in dental compounds
View Patent ↗The invention relates to dental compounds that contain at least one polyacid or at least one polyacid and at least one salt of at least one polyacid. The polyacids used have at least one branch point in the polymer structure and are water-soluble and not cross-linked and their repeat units consist to at least 80 mole % of acrylic acid segments.
1. A dental material including:
A. 1 to 60% by weight of polyacids, in which the polyacids used have at least one branching point in the polymer structure, are water-soluble and noncrosslinked and, with regard to the repeat units, comprise at least 80 mol % acrylic acid segments, the term “branching point” being understood as meaning a position in the polymer backbone from which, covalently bonded, at least two polymer residues start out, these comprising at least three repeat units;
B. 35 to 80% by weight of fillers;
C. 0 to 20% by weight of additives and auxiliaries;
D. 5 to 40% by weight of water.
2. The dental material of claim 1 , wherein polyacids, together with at least one salt of at least one polyacid, being used as component (A), in which the polyacids used have at least one branching point in the polymer structure, are water-soluble and noncrosslinked and, with regard to the repeat units, comprise at least 80 mol % acrylic acid segments.
3. A dental material including:
A. 1 to 60% by weight of polyacids, in which the polyacids used have at least one branching point in the polymer structure, are water-soluble and noncrosslinked and, with regard to the repeat units, comprise at least 80 mol % acrylic acid segments, the term “branching point” being understood as meaning a position in the polymer backbone from which, covalently bonded, at least two polymer residues start out, these comprising at least three repeat units;
C. 0 to 20% by weight of additives and auxiliaries;
D. 10 to 40% by weight of water;
E. 30 to 80% by weight of zinc oxide.
4. The dental material as claimed in claim 3 , wherein polyacids, together with at least one salt of at least one polyacid, being used as component (A), in which the polyacids used have at least one branching point in the polymer structure, are water-soluble and noncrosslinked and, with regard to the repeat units, comprise at least 80 mol % acrylic acid segments.
5. A dental material including:
A. 1 to 76% by weight of polyacids, in which the polyacids used have at least one branching point in the polymer structure, are water-soluble and noncrosslinked and, with regard to the repeat units, comprise at least 80 mol % acrylic acid segments, the term “branching point” being understood as meaning a position in the polymer backbone from which, covalently bonded, at least two polymer residues start out, these comprising at least three repeat units;
D. 5 to 40% by weight of water;
F. 8.9 to 70% by weight of one or more radically polymerizable monomers;
G. 10 to 90% by weight of fillers;
H. 0.1 to 5% by weight of initiators and optionally activators;
I. 0 to 30% by weight of additives, optionally pigments, thixotropic auxiliaries, plasticizers.
6. The dental material as claimed in claim 5 , wherein polyacids, together with at least one salt of at least one polyacid, being used as component (A), in which the polyacids used have at least one branching point in the polymer structure, are water-soluble and noncrosslinked and, with regard to the repeat units, comprise at least 80 mol % acrylic acid segments.
7. A container including the dental material as claimed in claim 1 .
8. A container including the dental material as claimed in claim 3 .
9. A container including the dental material as claimed in claim 5 .
10. A material comprising:
at least one polyacid or at least one polyacid together with at least one salt of at least one polyacid, the polyacids employed having at least one branching point in the polymer structure, being water-soluble and noncrosslinked and, with regard to the repeat units, comprising at least 80 mol % acrylic acid segments, the term “branching point” being understood as meaning a position in the polymer backbone from which, covalently bonded, at least two polymer residues start out, these comprising at least three repeat units; and
one or more radically polymerizable monomers,
wherein the material is a curable dental material.
11. The material as claimed in claim 10 , wherein the polyacids comprise star polymers or comb polymers.
12. The material of claim 10 , wherein the polyacids are copolymers in which the proportion of the comonomers amounts to 0.1 to 20 mol %.
13. A container including the material as claimed in claim 10 .
14. The material of claim 11 , wherein the polyacids are copolymers in which the proportion of the comonomers amounts to 0.1 to 20 mol %.
15. A material comprising:
at least one polyacid or at least one polyacid together with at least one salt of at least one polyacid, the polyacids employed having at least one branching point in the polymer structure, being water-soluble and noncrosslinked and, with regard to die repeat units, comprising at least 80 mol % acrylic acid segments, the term “branching point” being understood as meaning a position in the polymer backbone from which, covalently bonded, at least two polymer residues start out, these comprising at least three repeat units; and
one or more reactive fillers,
wherein the material is a curable dental material in which the one or more reactive fillers can react with the at least one polyacid or at least one polyacid together with at least one salt of at least one polyacid.
16. The material as claimed in claim 15 , wherein the polyacids comprise star polymers or comb polymers.
17. The material of claim 15 , wherein the polyacids are copolymers in which the proportion of the comonomers amounts to 0.1 to 20 mol %.
18. A container including the material as claimed in claim 15 .
19. The material of claim 16 , wherein the polyacids are copolymers in which the proportion of the comonomers amounts to 0.1 to 20 mol %.