Bituminous composition with reduced gelation tendency
View Patent ↗The present invention concerns a bituminous composition which comprises a bituminous component (I), a block copolymer (II), comprising at least two terminal blocks of a poly(monovinylaromatic hydrocarbon) and at least one block of a poly(conjugated diene), and optionally a filler (III), wherein (II) is a partially hydrogenated block polymer, comprising butadiene as the conjugated diene, wherein the poly(conjugated diene) block upon partial hydrogenation comprises less than 3 mol % 1,2-dine recurring units (A) and less than 20 mol % preferably less than 3 mol % ethylene recurring units (D), calculated on the total content mol/mol of conjugated diene recurring units.
1. A bituminous composition comprising:
(I) a bituminous component, and
(II) a block copolymer comprising at least two terminal blocks of a poly(monovinylaromatic hydrocarbon) and at least one block of a poly(conjugated diene),
wherein (II) is a partially, selectively hydrogenated block polymer comprising butadiene as the conjugated diene, selectively hydrogenated by a process in which the ratio of hydrogenation of the 1,2 butadiene recurring units to the 1,4 butadiene recurring units is greater than 5 wherein the poly(conjugated diene) block has an initial content of 1,2-diene recurring units (A) in the range of 5–95 mol %, and, upon partial hydrogenation, the partially hydrogenated block polymer comprises less-tan 3 mol percent 1,2-diene recurring units (A) and less than 20 mol percent ethylene recurring units (D), calculated on the total content mol/mol of initial conjugated diene recurring nails.
2. The composition of claim 1 additionally comprising (III) a filler.
3. The composition of claim 1 wherein the poly(monovinylaromatic hydrocarbon) is polystyrene.
4. The composition of claim 1 wherein the component I is a straight run or distilled bitumen.
5. The composition of claim 4 wherein the straight rum or distilled bitumen has a penetration in the range of 50 to 250 dmm at 25° C.
6. The composition of claim 5 wherein the straight run or distilled bitumen has a penetration in the range of 150 to 250 dmm at 25° C.
7. The composition of claim 1 wherein the poly(conjugated diene) block, upon partial hydrogenation, comprises less-than 3 mol percent 1,2-diene recurring units (A) and less than 3 mol percent ethylene recurring units (D), calculated on the total content mol/mol of conjugated diene recurring units.
8. The composition of claim 7 , wherein the poly(conjugated diene) block has an initial content of 1,2-diene recurring units (A) in the range of 6–70 mol percent, calculated on the total content mol/mol of conjugated diene recurring units.
9. The composition of claim 1 , wherein the poly(conjugated diane) block is at least 80 mole percent butadiene.
10. The composition of claim 9 wherein the poly(conjugated diane) block is additionally comprising conjugated dienes of from 5 to 8 carbon atoms per monomer.
11. The composition of claim 10 wherein the conjugated dienes of from 5 to 8 carbon atoms per monomer are selected from the group consisting of 2-methyl-1,3-butadiene; 2,3-dimethyl-1,3butadiene; 1,3-pentadiene; 1,2-hexadiene; and mixtures thereof.
12. The composition of claim 1 wherein the poly(monovinylaromatic hydrocarbon) blocks are polymerized monomers selected from the group consisting of styrene, o-methyl styrene, p-methyl styrene, p-tert-butylstyrene, 2,4-dimethylstyrene, a-methylstyrene, vinyl naphthalene, vinyl toluene, vinyl xylene, and mixtures thereof.
13. The composition of claim 1 wherein the content of monovinylaromatic hydrocarbons of the final block copolymer ranges from 10 to 70% wt.
14. The composition of claim 1 wherein the polymer blocks of monovinylaromatic hydrocarbons (“A”) have an apparent molecular weight in the range from 2,000 to 100,000.
15. The composition of claim 1 wherein the polymer blocks of conjugated dienes (“B”) have an apparent molecular weight in the range of from 25,000 to 1,000,000.
16. The composition of claim 1 wherein the amount of component (II) is in the range of 1–20 percent by weight on the basis of the composition.
17. A process for preparing or repairing a roof comprising using a composition of claim 1 in a roofing application.
18. The process of claim 17 wherein the composition of claim 10 is a component of a roofing felt.
19. A bituminous composition comprising:
(I) a bituminous component, and
(II) a block copolymer comprising at least two terminal blocks of a poly(monovinylaromatic hydrocarbon) and at least one block of a poly(conjugated diene),
wherein (II) is a partially, selectively hydrogenated block polymer comprising butadiene as the conjugated diane, selectively hydrogenated by a process in which the ratio of hydrogenation of the 1,2 butadiene recurring units to the 1,4 butadiene recurring units is greater than 5 wherein the poly(conjugated diene) block has an initial content of 1,2-diene recurring units (A) in the range of 4–50 mol %, and, upon partial hydrogenation, to partially hydrogenated block polymer comprises less-than 3 mol percent 1,2-diane recurring units (A) and less than 3 mol percent ethylene recurring units (D), calculated on the total content mol/mol of initial conjugated diene recurring units.