Blend of organophosphorus flame retardant, lactone stabilizer, and phosphate compatibilizer
A flame retardant blend, suitable for incorporation into a polyurethane foam, comprises: an oligomeric organophosphourus flame retardant, preferably an organophosphate, having a phosphorus content of no less than about 10%; a benzofuran-2-one stabilizer; and a monomeric phosphate ester containing alkyl and/or haloalkyl groups to act as a solubilizing addtive for the oligomeric organophosphorus flame retardant and benzofuran-2-one stabilizer.
1. A flame retardant composition which comprises: from about 60% to about 98%, by weight of the flame retardant composition, of an oligomeric organophosphorus flame retardant which is a phosphate ester containing at least three phosphate ester units therein; from about 0.05% to about 1.0%, by weight of the flame retardant composition, of a benzofuran-2-one stabilizer; and from about 1% to about 40%, by weight of the flame retardant composition, of a monomeric phosphate ester compatibilizer.
2. A composition as claimed in claim 1 wherein the monomeric phosphate ester compatibilizer is tributoxyethyl phosphate.
3. A flame retardant composition which comprises: from about 80% to about 98%, by weight of an oligomeric organophosphorus flame retardant which is a phosphate ester containing at least three phosphate ester units therein; from about 0.05% to about 1.0%, by weight of a benzofuran-2-one stabilizer; and from about 1% to about 40%, by weight of a monomeric phosphate ester compatibilizer.
4. A composition as claimed in claim 3 wherein the phosphate ester is of the formula
wherein n is, on a number average basis, of from about 2 to about 20, R is ethyl, and R′ is ethylene.
5. A composition as claimed in claim 3 wherein the benzofuran-2-one stabilizer has the formula
wherein either two of R 1 , R 7 , R 8 , R 9 and R 10 are each independently of the other C 1 –C 4 alkyl or C 1 –C 4 alkoxy, the others being hydrogen, or R 7 to R 10 are hydrogen, or at most two of these radicals are each independently of the other methyl or methoxy, and R 1 is —O—CHR 3 —CHR 5 —O—CO—R 6 , R 2 and R 4 are each independently of the other hydrogen or C 1 –C 6 alkyl, R 3 is hydrogen or C 1 –C 4 alkyl, R 5 is hydrogen, phenyl or C 1 –C 6 alkyl, and R 6 is C 1 –C 4 alkyl.
6. A composition as claimed in claim 5 wherein the benzofuran-2-one stabilizer is (5,7-di-t-butyl-3(3,4 dimethyiphenyl)-3H-benzofuran-2-one.
7. A composition as claimed in claim 3 wherein the monomeric phosphate ester compatibilizer is of the formula O═P—(OR) 3 , where R is independently selected from alkyl, alkoxyalkyl, or haloalkyl containing up to about 8 carbon atoms in the alkyl, alkoxyalkyl and/or haloalkyl groups.
8. A composition as claimed in claim 3 wherein the organophosphorus flame retardant is a monomeric phosphate ester having the formula O═P(OR) 3 , where R is selected from alkyl and haloalkyl groups having from 1 to about 8 carbon atoms in such groups.
9. A composition as claimed in claim 3 wherein the monomeric phosphate ester compatibilizer is tributoxyethyl phosphate.
10. A flame retarded polyurethane foam that comprises the composition of any of claims 1 to 8 .