Granted Patent B2

US 6,858,188 · App. 10/434,805 · Granted Feb 22, 2005

Abstract

Claims (24)

1. Apparatus for olefin polymerization comprising:

an olefin containing feedstock distribution assembly including a feedstock inlet and a plurality of feedstock outlets, said distribution assembly being adapted and arranged to receive feedstock via said feedstock inlet, divide said feedstock into a plurality of separate streams and deliver each of said streams to a respective one of said outlets;

a plurality of reactors, each of said reactors comprising (1) structure defining a reaction zone, said structure being adapted and arranged to facilitate the conduct of an exothermic olefin polymerization reaction on an olefin polyymerization reaction mixture in said zone, said structure comprising inlet and outlet connections arranged in fluid communication with said zone, and (2) a recirculation system including a pump arranged and adapted to circulate said reaction mixture in said zone,

each said feedstock outlet being connected in fluid communication with the inlet connection of a respective reactor,

each said recirculation system being adapted and arranged to circulate reaction mixture in its respected zone independently of the introduction of feedstock into said zone via a respective inlet connection; and

a crude polyolefin product collection assembly including a plurality of crude polyolefin product inlets and a crude polyolefin product outlet, each said crude polyolefin product inlet being connected in fluid communication with the outlet connection of a respective reactor,

whereby said reactors are arranged and connected for operation in parallel.

2. Apparatus for olefin polymerization as set forth in claim 1 , comprising two of said reactors.

3. Apparatus for olefin polymerization as set forth in claim 1 , comprising at least three of said reactors.

4. Apparatus for olefin polymerization as set forth in claim 1 , comprising a respective catalyst composition inlet in fluid communication with each reaction zone, each said catalyst composition inlet being adapted and arranged to introduce catalyst composition into said recirculating olefin polymerization reaction mixture in said zone, and a respective catalyst modifier inlet in fluid communication with each said reaction zone, each said catalyst modifier inlet being adapted and arranged to introduce catalyst modifier into said recirculating olefin polymerization reaction mixture at a rate which is independent of the rate of introduction of the catalyst composition.

5. Apparatus for olefin polymerization as set forth in claim 4 , wherein each said catalyst modifier inlet is spaced from its corresponding catalyst composition inlet.

6. Apparatus for olefin polymerization as set forth in claim 1 or claim 4 , and a crude polyolefin product catalyst removal and wash system including a plurality of settler vessels, associated piping and an inlet for a catalyst killing agent, said crude polyolefin product catalyst removal and wash system being adapted and arranged to receive crude polyolefin product from said crude polyolefin product outlet and remove residual catalyst therefrom.

7. Apparatus for olefin polymerization as set forth in claim 6 , wherein said crude polyolefin product catalyst removal and wash system comprises:

an upstream settler vessel defining an internal settlement chamber adapted and arranged for receiving a mixture of a crude polyolefin product and an aqueous wash media and allowing said product and said media to separate therein under the influence of gravity;

a crude, catalyst containing olefin polymerization product inlet line connected to said crude polyolefin product outlet and arranged in fluid communication with the chamber of said upstream settler vessel;

a catalyst killing agent inlet conduit in fluid communication with the chamber of said upstream settler vessel;

a first make-up water inlet passageway in fluid communication with the chamber of said upstream settler vessel;

a downstream settler system including at least one downstream settler vessel defining an internal settlement chamber adapted and arranged for receiving a mixture of a partially washed crude polyolefin product and an aqueous wash media and allowing said product and said media to separate therein under the influence of gravity;

an overhead, partially washed polyolefin product line intercommunicating the chamber of said upstream settler vessel with said downstream settler system;

a washed crude olefin polymerization product outlet line in fluid communication with said downstream settler system;

a second make-up water inlet passageway in fluid communication with said downstream settler system;

a first drain line interconnecting the chamber of said upstream settler vessel with an inlet connection to a waste water receiving system; and

a second drain line interconnecting said downstream settler system with said inlet connection.

8. Apparatus for olefin polymerization as set forth in claim 1 , wherein each said reactor comprises a shell and tube heat exchanger configured and arranged so that said reaction zone is on the tube side thereof.

Assignments (31)