Doped titanium oxides
View Patent ↗Pyrogenically prepared titanium dioxide doped by means of an aerosol contains an oxide from the group zinc oxide, platinum oxide, magnesium oxide and/or aluminium oxide as the doping component. It is prepared as follows: in the pyrogenic preparation of titanium dioxide, a metal salt solution is atomised to form an aerosol and injected into the production stream. The titanium dioxide may be used as a photocatalyst or as a UV adsorber or in processes for purification of waste water or waste air/gases.
1. A photocatalyst comprising pyrogenically prepared titanium dioxide doped by an aerosol and containing, as a doping component, an oxide selected from the group consisting of zinc oxide, platinum oxide, magnesium oxide, and aluminum oxide, wherein said photocatalyst has either:
a) a BET surface area of 65 m 2 /g to 80 m 2 /g and a doping component concentration of 40ppm to 800 ppm; or
b) a BET surface area of 35 ppm 2 /g to 60 m 2 /g and a doping component concentration of more than 1000 ppm.
2. Process for the preparation of the photocatalyst according to claim 1 , the process comprising:
(a) feeding an aerosol into a flame used for the preparation of pyrogenic titanium dioxide, wherein the titanium dioxide is prepared by flame oxidation or flame hydrolysis, and wherein the aerosol:
(i) comprises a salt solution or suspension containing: a metal salt, a metalloid salt, mixtures of a metal salt and a metalloid salt, a suspension of a metal insoluble in water, a suspension of a metalloid compound, or a mixture of a suspension of a metal insoluble in water and a suspension of a metalloid compound,
(ii) is produced by atomisation using a two-component nozzle, an aerosol generator, or ultrasound atomisation, and
(iii) is mixed homogeneously with a gas mixture, wherein the gas mixture further comprises air, and allowed to react in the flame; and
(b) separating the resulting photocatalys from the gas mixture.
3. An adsorbent for UV radiation comprising a pyrogenically prepared titanium dioxide having a BET surface area of 35 m 2 /g to 60 m 2/ g doped by means of an aerosol containing an oxide selected from the group consisting of zinc oxide, magnesium oxide, platinum oxide and aluminum oxide as the doping component present in an amount greater than 1000 ppm.
4. A glass or plastic article coated with the UV adsorbent of claim 3 .
5. A process for purification of waste water comprising contacting waste water with a pyrogenically prepared titanium dioxide having a BET surface area of 65 m 2 /g to 80 m 2 /g doped by means of an aerosol and containing an oxide selected from the group consisting of zinc oxide, platinum oxide, magnesium oxide, and aluminum oxide as the doping component present in an amount of 40 ppm to 800 ppm.
6. A process for purification of waste air and/or waste gases comprising contacting the waste air and/or waste gases with a pyrogenically prepared titanium dioxide having a BET surface area of 65 m 2 /g to 80 m 2 /g doped by means of an aerosol and containing an oxide selected from the group consisting of zinc oxide, platinum oxide, magnesium oxide, and aluminum oxide as the doping component present in an amount of 40 ppm to 800 ppm.