Method for production of non-oriented electrical steel strip
The present invention relates to a method for producing a non-oriented electrical steel with improved magnetic properties and improved resistance to ridging, brittleness, nozzle clogging and magnetic aging.. The chromium bearing steel is produced from a steel melt which is cast as a thin slab or conventional slab, cooled, hot rolled and/or cold rolled into a finished strip. The finished strip is further subjected to at least one annealing treatment wherein the magnetic properties are developed, making the steel sheet of the present invention suitable for use in electrical machinery such as motors or transformers.
1 . A method for producing a non-oriented electrical steel having a volume resistivity of at least 20 μΩ-cm and a peak austenite volume fraction, γ 1150° C. , of at least 5 wt % comprising the steps of:
(a) preparing a non-oriented electrical steel melt having a composition in weight % comprising:
up to about 6.5% silicon,
up to about 5% chromium,
up to about 0.05% carbon,
up to about 3% aluminum,
up to about 3% manganese, and
the balance being substantially iron and residuals;
(b) casting a steel slab having a thickness of from about 20 mm to about 375 mm;
(c) providing said steel slab at a temperature - - -
(c) heating said steel slab to a temperature less than T max and greater than T min as defined by;
T min , °C.=759−4430(% C)−194(% Mn)+445(% P)+181(% Si)+378(% Al)−29.0(% Cr)−48.8(% N)−68.1(% Cu)−235(% Ni+116(% Mo)
T max , ° C.=1633+3970(% C)+236(% Mn)−685(% P)−207(% Si)−455(% Al)+9.64(% Cr)−706(% N)+55.8(% Cu)+247(% Ni)−156(% Mo)
(d) hot rolling said slab to a hot rolled strip having a thickness of from about 0.35 mm to about 1.5 mm wherein said hot rolling provides a nominal strain of at least 700 using the equation: (need to say “with at least one reduction with the steel having at least X % austentite?)
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2 . The method of claim 1 wherein the non-oriented electrical steel melt comprises:
about 1% to about 3.5% silicon,
about 0.1% to about 3% chromium,
up to about 0.01% carbon,
up to about 1% aluminum,
about 0.1% to about 1% manganese,
up to about 0.01% of a metal selected from the group consisting of
sulfur, selenium and mixtures thereof,
up to about 0.01% nitrogen, and
the balance being substantially iron and residuals.
3 . The method of claim 1 wherein the non-oriented electrical steel melt comprises:
about 1.5% to about 3% silicon,
about 0.15% to about 2% chromium,
up to about 0.005% carbon,
up to about 0.5% aluminum,
about 0.1% to about 0.35% manganese,
up to about 0.005% sulfur;
up to about 0.007% selenium;
up to about 0.002% nitrogen, and
the balance being substantially iron and residuals.
4 . The method of claim 1 wherein the non-oriented electrical steel melt further comprises up to about 0.15% antimony, up to about 0.005% niobium, up to about 0.25% phosphorus, up to about 0.15% tin, up to about 0.01% sulfur and/or selenium, and up to about 0.01% vanadium.
5 . The method of claim 1 wherein the slab is:
(a) heated to a temperature of ? to ?;
(b) hot rolled to a strip having a thickness of about 1 to about 10 mm;
(c) cooled to a temperature below ?
(d) pickled;
(e) cold rolled to a thickness of ?; and
(f) finish annealed at a temperature below T min .
6 . The method of claim 1 wherein the hot rolled strip is cold rolled
7 . The method of claim 6 wherein the hot rolled strip is annealed at temperature of ? prior to cold rolling.
8 . The method of claim 1 wherein γ 1150° C. is at least 10%.
9 . The method of claim 1 wherein γ 1150° C. is at least 20%.
10 . The method of claim 1 further comprising decarburizing annealing of the strip prior to finish annealing.
11 . The method of claim 1 further comprising the steps after said hot rolling of:
a) providing said hot rolled steel with a temper rolling; and
b) providing said temper rolled steel with a quality anneal.
12 . The method of claim 1 further comprising the steps after hot rolling of:
a)providing said hot rolled steel with a pickling operation;
b)providing said pickled steel with one or more cold rollings with an anneal if more than 1 cold rollings; and
c) quality annealing said cold rolled steel.
13 . The method of claim 1 further comprising the steps after said hot rolling of:
a) annealing said hot rolled steel;
b) pickling said annealed steel;
c) cold rolling said annealed steel in one or more stages with an anneal if more than 1 cold rollings; and
d) quality annealing said cold rolled steel.
14 . The method of claim 2 wherein the volume resistivity is at least 20% and the peak austenite volume fraction is at least 10%.