Process for preparing polymer polyols
View Patent ↗The invention relates to a process for the batch or semi-batch preparation of a polymer polyol, which process involves (1) preparing a seed by polymerizing in a base polyol at least one ethylenically unsaturated monomer in the presence of a polymerization initiator and macromer, and in the presence of from 0.5 to 50% wt of polymer polyol heel, based on amount of polymer present in the heel compared with total amount of polymer formed, (2) adding additional ethylenically unsaturated monomer to the seed obtained in step (1) and optionally additional polyol, and (3) polymerizing the mixture obtained in step (2).
1. A process for the batch or semi-batch preparation of a polymer polyol, which process comprises:
(1) preparing a seed by polymerizing in a base polyol at least one ethylenically unsaturated monomer in the presence of a polymerization initiator and macromer, and in the presence of from 0.5 to 50% wt of polymer polyol heel, based on amount of polymer present in the heel compared with total amount of polymer formed;
(2) adding additional ethylenically unsaturated monomer to the seed obtained in step (1) and optionally additional polyol; and,
(3) polymerizing the mixture obtained in step (2) wherein the polymer polyol is formed in a batch or semi-batch process.
2. The process of claim 1 , in which the amount of polymer derived from step (1) as present in the final product, is of from 3% wt to 30% wt.
3. The process of claim 1 , in which the polyol has a nominal molecular weight in the range of from 1500 to 15,000 and an average nominal functionality of at least 2.0.
4. The process of claim 3 , in which the polyol has a primary hydroxyl content of at least 70%.
5. The process of claim 1 , in which the polyol has a nominal molecular weight in the range of from 2500 to 14,000 and an average nominal functionality in the range of from 2.5 to 6.0.
6. The process of claim 1 , in which the polyol has a primary hydroxyl content in the range of from 75 to 95%.
7. The process of claim 1 , in which the ethylenically unsaturated monomers are styrene and acrylonitrile in a molar ratio of from 30:70 to 100:0.
8. The process of claim 7 , in which the molar ratio is in the range of from 33:67 to 67:33.
9. The process of claim 1 in which process the macromer is obtained by reacting a polyol with a cyclic dicarboxylic acid anhydride not containing any polymerizable double bond, to obtain an adduct and subsequently reacting the adduct thus obtained with an epoxide compound containing a polymerizable double bond.
10. The process of claim 9 , in which the macromer has a nominal molecular weight in the range of from 5000 to 50,000.
11. The process of claim 9 in which the polyol for preparing the macromer has a hydroxyl functionality of at least 3.
12. The process of claim 9 , in which the cyclic dicarboxylic acid anhydride is phthalic anhydride.
13. The process of claim 11 , in which the epoxide compound is glycidyl methacrylate or glycidyl acrylate.
14. The process of claim 13 , in which the polymerization initiator is present in an amount of from 0.01 wt % to 5 wt % based on total weight of monomer.