Transparent glass having blue edge color
View Patent ↗A method is provided for making clear glass having an azure edge coloration and low amber surface coloration in a non-vacuum float glass system. The method includes processing batch materials in a non-vacuum float glass system to provide a final glass product including: SiO 2 65-75 wt. %; Na 2 O 10-20 wt. %; CaO 5-15 wt. %; MgO 0-5 wt. %; Al 2 O 3 0-5 wt. %; K 2 O 0-5 wt. %; a colorant portion having total iron (Fe 2 O 3 ) of 0-0.02 wt. %, CoO of 0-5 ppm, Nd 2 O 3 of 0-0.1 wt. %, and CuO of 0-0.03 wt. %. The glass has a redox ratio in the range of 0.2 to 0.6, and can have a retained sulfur content of less than or equal to 0.2 wt. %, such as less than or equal to 0.11 wt. %.
1. A method of making clear glass having an azure edge coloration and low amber surface coloration in a non-vacuum float glass system, comprising:
providing a non-vacuum float glass system having a melter and a molten metal bath; and
melting batch materials to provide a final glass product comprising:
SiO 2
65-75 wt. %;
Na 2 O
10-20 wt. %;
CaO
5-15 wt .%;
MgO
0-5 wt. %;
Al 2 O 3
0-5 wt. %;
K 2 O
0-5 wt. %;
and
a colorant portion comprising:
total iron (Fe 2 O 3 )
0-0.02
wt. %;
CoO
0-5
ppm;
Nd 2 O 3
0-0.1
wt. %; and
CuO
0-0.03
wt. %,
wherein the glass has a redox ratio in the range of 0.3 to 0.6,
wherein the glass has a retained sulfur content of less than or equal to 0.11 wt. % SO 3 , and
wherein the batch materials comprise sodium sulfate and sodium nitrate, with the sodium sulfate present in an amount to provide a final glass product having less than or equal to 0.11 wt. % SO 3 .
2. The method of claim 1 , wherein the melter is an a air-fuel furnace having oxygen lances.
3. The method of claim 1 , wherein the melter is an oxyfuel furnace.
4. The method of claim 1 , wherein the batch materials further include a non-sulfur containing oxidizing agent.
5. The method of claim 4 , wherein the oxidizing agent comprises at least one of sodium nitrate and cerium oxide.
6. The method of claim 1 , wherein the redox ratio is in the range of 0.4 to 0.6.
7. The method of claim 1 , wherein the retained sulfer is less than or equal to 0.1 wt. % SO 3 .
8. The method of claim 1 , wherein the retained sulfer is less than or equal to 0.08 wt. % SO 3 .
9. The method of claim 1 , wherein the retained sulfer is less than or equal to 0.05 wt. % SO 3 .
10. The method of claim 1 , wherein the total iron is in the range of 0.005 to 0.02 wt. %.
11. The method of claim 1 , wherein the molten metal bath is essentially free of iron.
12. The method of claim 1 , wherein the molten metal in the molten metal bath comprises less than or equal to 0.05 wt. % Fe.
13. The method of claim 1 , wherein the molten metal in the molten metal bath comprises less than or equal to 0.01 wt. % Fe.
14. The method of claim 1 , wherein the glass has a dominant wavelength in the range of 485 nm to 505 nm at a 5.5 mm equivalent thickness for glass sheets having a thickness in the range of 2 mm to 25 mm when viewed on edge.
15. A method of making clear glass in a non-vacuum float glass system, comprising:
providing a non-vacuum float class system having a melter and a molten metal bath; and
melting batch materials to provide a final glass product comprising:
SiO 2
65-75 wt. %;
Na 2 O
10-20 wt. %;
CaO
5-15 wt. %;
MgO
0-5 wt. %;
Al 2 O 3
0-5 wt. %;
K 2 O
0-5 wt. %;
and
a colorant portion comprising:
total iron (Fe 2 O 3 )
0-0.02 wt. %;
CoO
0-5 ppm;
Nd 2 O 3
0-0.1 wt. %; and
CuO
0-0.03 wt. %,
wherein the glass has a redox ratio in the range of 0.3 to 0.6 and
wherein the batch materials are essentially free of sulfur-containing materials.
16. The method of claim 15 , wherein the redox ratio is in the range of 0.4 to 0.6.
17. The method of claim 15 , wherein the total iron is in the range of 0.005 to 0.02 wt. %.
18. The method of claim 15 , wherein the molten metal bath is essentially free of iron.
19. The method of claim 15 , wherein the molten metal in the molten metal bath comprises less than or equal to 0.05 wt. % Fe.
20. A method of making clear glass having an azure edge coloration and low amber surface coloration in a non-vacuum float glass system, comprising:
providing a non-vacuum float glass system having a melter and a molten metal bath; and
melting the batch materials to provide a final glass product comprising:
SiO 2
65-75 wt. %;
Na 2 O
10-20 wt. %;
CaO
5-15 wt .%;
MgO
0-5 wt. %;
Al 2 O 3
0-5 wt. %;
K 2 O
0-5 wt. %;
CeO 2
greater than 0-0.2 wt. %;
and
a colorant portion comprising:
total iron (Fe 2 O 3 )
0 wt. % to 0.02 wt. %;
CoO
0-5 ppm;
Nd 2 O 3
0-0.1 wt. %;
CuO
0-0.03 wt. %,
wherein the glass has a redox ratio in the range of 0.3 to 0.6,
wherein the glass has a retained sulfur content of less than or equal to 0.2 wt. % SO 3 ,
wherein the batch materials comprise sodium sulfate and sodium nitrate, with the sodium sulfate present in an amount to provide a final glass product having less than or equal to 0.2 wt. % SO 3 .
21. The method of claim 20 , wherein the redox ratio is in the range of 0.4 to 0.6.
22. The method of claim 20 , wherein the retained sulfur content is less than or equal to 0.15.
23. The method of claim 20 , wherein the retained sulfur is less than or equal to 0.1 wt. % SO 3 .
24. The method of claim 20 , wherein the total iron is in the range of 0.005 to 0.02 wt. %.
25. The method of claim 20 , wherein the molten metal bath is essentially free of iron.
26. The method of claim 20 , wherein the glass has dominant wavelength in the range of 485 nm to 505 nm at a 5.5 mm equivalent thickness for glass sheets having a thickness in the range of 2 mm to 25 mm when viewed on edge.
27. A method of making clear glass in a non-vacuum float glass system, comprising:
providing a non-vacuum float glass system having a melter and a molten metal bath;
melting the batch materials to provide a final glass product comprising:
SiO 2
65-75 wt. %;
Na 2 O
10-20 wt. %;
CaO
5-15 wt. %;
MgO
0-5 wt. %;
Al 2 O 3
0-5 wt. %;
K 2 O
0-5 wt. %;
CeO 2
greater than 0-0.2 wt. %;
and
a colorant portion comprising:
total iron (Fe 2 O 3 )
0.007 wt. % to 0.02 wt. %;
CoO
0-5 ppm;
Nd 2 O 3
0-0.1 wt. %;
CuO
0-0.03 wt. %,
wherein the glass has a redox ratio in the range of 0.3 to 0.6, and
wherein the batch materials are essentially free of sulfur-containing materials.
28. A method of making clear glass having an azure edge coloration and low amber surface coloration in a non-vacuum float glass system, comprising:
providing a non-vacuum float glass system having a melter and a molten metal bath;
melting batch materials to provide a final glass product comprising:
SiO 2
65-75 wt. %;
Na 2 O
10-20 wt. %;
CaO
5-15 wt .%;
MgO
0-5 wt. %;
Al 2 O 3
0-5 wt. %;
K 2 O
0-5 wt. %;
and
a colorant portion comprising:
total iron (Fe2O3)
0.007 wt. % to 0.02 wt. %;
CoO
0-5 ppm;
Nd2O3
0-0.1 wt. %; and
CuO
0-0.03 wt. %,
wherein the glass has a redox ratio in the range of 0.3 to 0.6, and
wherein the glass has a retained sulfur content of less than or equal to 0.11 wt. % SO 3 ;
further including treating the molten metal in the molten metal bath to remove dissolved iron such that the dissolved iron remaining in the molten metal is less than or equal to 0.05 wt. %.
29. The method of claim 28 , including treating the molten metal such that the dissolved iron is less than or equal to 0.04 wt. %.
30. The method of claim 28 , including treating the molten metal such that the dissolved iron is less than or equal to 0.03 wt. %.
31. The method of claim 28 , including treating the molten metal such that the dissolved iron is less than or equal to 0.02 wt. %.
32. The method of claim 28 , including treating the molten metal such that the dissolved iron is less than or equal to 0.01 wt. %.