Data storage media containing transparent polycarbonate blends
View Patent ↗The invention relates to transparent blends of polymers suitable for use in optical articles; the polymers contain residues of BCC and its derivatives, and have properties particularly suited for use in high density optical data storage media. The polymers further contain residues of other polymers, such as α-methyl polystyrene and polystyrene derivatives; bisphenols, such as bisphenol A; cycloaliphatic polyester resins, such as PCCD and its derivatives or some combination of each.
1. A miscible polymer blend comprising polymer A and polymer C, wherein (A) is a polycarbonate comprising structural units corresponding to structure (I),
where R 1 and R 2 independently comprise a C 1 -C 6 alkyl; X comprises CH; m is an integer from 4 to 7; n is an integer fron 1 to 4; p is an integer from 1 to 4, with the proviso that at least one of R 1 or R 2 is in the 3 or 3′ position, and
(C) is a polymer comprising structural units corresponding to structure (III)
where R 4 , R 5 and R 6 independently comprise a C 1 -C 6 alkyl.
2. The miscible polymer blend as defined in claim 1 , wherein (A) is selected to be carbonate structural units of structure (I), the carbonate structural units of structure (I) further selected from the coup consisting of residues of 1,1-bis(4-hydroXy-3-methylphenyl)cyclohexane (BCC); 1,1-bis(4-hydroxy-3-methylphenyl)cyclopentane; 1,1-bis(4-hydroxy-3-methylphenyl)cycloheptane and mixtures thereof.
3. The miscible polymer blend as defined in claim 1 , wherein the first polymer (A) comprises from 1 to 99 weight %, and the second polymer (C) comprises from 1 to 99 weight % of the blend.
4. The miscible polymer blend as defined in claim 1 , wherein the polymer blend is transparent.
5. An article comprising the miscible polymer blend of claim 1 .
6. The article of claim 5 , wherein the article is an optical article.
7. The article of claim 5 , wherein the article is an optical data storage medium.
8. The article of claim 5 , wherein the optical data storage medium comprises a data layer and a transparent overlayer adjacent to the data layer, wherein the transparent overlayer has a thickness of equal to or less than 0.6 mm.
9. The article of claim 5 , wherein the optical data storage medium comprises a data layer and a transparent overlayer adjacent to the data layer, wherein the data layer has a thickness of equal to or less than 1.1 mm and the transparent overlayer has a thickness equal to or less than 100 microns.
10. The miscible polymer blend as defined in claim 1 , wherein the additive used in optical applications is from 0.0001 to 10% by weight of the blend.
11. A miscible polymer blend comprising polymer A and polymer C, wherein (A) is a polycarbonate comprising structural units corresponding to structure (I),
where R 1 and R 2 independently comprise a C 1 -C 6 alkyl; X comprises CH 2 ; m is an integer from 4 to 7; n is an ininger from 1 to 4; p is an integer from 1 to 4, with the proviso chat at least one of R 1 or R 2 is in the 3 or 3′ position, and
(C) is a polymer comprising structural units corresponding to structure (IV)