Platy precipitated calcium carbonate synthesis method
View Patent ↗A process for the preparation of platy PCC comprising the steps of providing a suspension of calcium hydroxide, carbonating the suspension of calcium hydroxide, adding a condensed phosphate to the suspension prior to the completion of carbonation to precipitate platy calcium carbonate. A paper that is filled is also provided and a paper that is coated and a polymer that is filled are envisioned that use the platy PCC according to the present invention.
1. A process for the preparation of platy PCC comprising the steps of:
providing a suspension of calcium hydroxide;
starting carbonation of the suspension of calcium hydroxide; and
adding a condensed phosphate in an amount of at least about 1.25 percent dry condensed phosphate additive on dry PCC to the suspension prior to the completion of the carbonation to precipitate platy calcium carbonete; wherein the step of adding a condensed phosphate to the suspension is initiated during carbonation.
2. The process for the preparation of platy PCC according to claim 1 , wherein the step of providing a suspension of calcium hydroxide is comprised of hydrating lime to form the calcium hydroxide suspension having a concentration of about 0.09 grams to about 0.14 grams calcium hydroxide per milliliter of suspension.
3. The process for the preparation of platy PCC according to claim 1 , wherein the initial temperature of the suspension of calcium hydroxide prior to carbonation is in a range from about 8 degrees Celsius to about 18 degrees Celsius.
4. The process for the preparation of platy PCC according to claim 1 , wherein citric acid is added in an amount up to about 0.30 percent dry citric acid on dry PCC by weight.
5. The process forte preparation of platy PCC according to claim 1 , wherein the step of carbonating the suspension is performed until the pH of the resultant solution reaches about 7.0 to about 8.0.
6. The process for the preparation of platy PCC according to claim 1 , wherein the step of adding a condensed phosphate to the suspension is performed without discontinuing the step of carbonating the suspension.
7. The process for the preparation of platy PCC according to claim 1 , wherein the step of adding a condensed phosphate is performed by discontinuing the carbonating step, adding the condensed phosphate as an aqueous solution, mixing the suspension, and resuming carbonating the suspension to precipitate platy PCC.
8. The process for the preparation of platy PCC according to claim 1 , wherein the condensed phosphate is added to the suspension during carbonation when the specific conductivity decreases at a rate of about 0.02 milliSiemens to about 0.04 milliSiemens per centimeter per second.
9. The process for the preparation of platy PCC according to claim 1 , wherein the condensed phosphate added to the suspension is selected from the group consisting of sodium hexametaphosphate, sodium trimetaphosphate, and sodium tripolyphosphate.
10. The process for the preparation of platy PCC according to claim 1 , wherein the condensed phosphate is added in an amount of at least about 3 percent by weight of dry condensed phosphate on dry PCC yield.