Image forming method using photothermographic material
View Patent ↗An image forming method using a photothermographic material including, on at least one surface of a support, at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for silver ions, and a binder, in which (1) the photothermographic material is exposed and thermally developed during transportation at a transportation speed of 23 mm/sec or faster, (2) the non-photosensitive organic silver salt contains 30 mol % to 85 mol % of silver behenate and an amount of the time until a leading end of the photothermographic material reaches a thermal development station after a power source for ae thermal developing apparatus is turned on is 15 minutes or less, or (3) a coating amount of silver inf the photothermographic material is 1.9 g/m 2 or less and a thermal development time is 12 sec or less.
1. An image forming method comprising:
providing a sheet of a photothermographic material comprising, on at least one surface of a support, at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for silver ions and a binder, wherein the non-photosensitive organic silver salt containing 30 mol % to 85 mol % of silver behenate, and imagewise exposing and thermally developing continuously said sheet of the photothermographic material during transportation at a transportation speed of 23 mm/sec or faster using a thermal developing apparatus having an image exposing station and a developing station, wherein the imagewise exposing is started from a leading end of the sheet of the photothermographic material followed by thermal development which is started before completing the imagewise exposing up to a posterior end of the sheet of the photothermographic material;
wherein a hue angle (hab) of the image according to JIS Z 8729 at an optical density D of 1.2 is within the following range:
185°<hab<260°.
2. An image forming method according to claim 1 , wherein the reducing agent is contained in amount of 0.1 mol % to 30 mol % per one mol of the non-photosensitive organic silver salt.
3. An image forming method according to claim 2 , wherein the reducing agent is a bisphenolic reducing agent.
4. An image forming method according to claim 3 , wherein the reducing agent is represented by the following general formula (R):
wherein R 11 and R 11 ′ each independently represent an alkyl group having 1 to 20 carbon atoms; R 12 and R 12′ each independently represent a hydrogen atom or a substituent capable of substituting for a hydrogen atom on a benzene ring; L represents a —S— group or a —CHR 13 — group, R 13 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; and X and X 1 each independently represents a hydrogen atom or a group capable of substituting for a hydrogen atom on a benzene ring.
5. An image forming method according to claim 4 , wherein R 11 and R 4 ′ in the above general formula (R) each independently represent a secondary or tertiary alkyl group having 3 to 15 carbon atoms.
6. An image forming method according to claim 1 , wherein a coating amount of silver in the photothermographic material is 1.9 g/m 2 or less.
7. An image forming method according to claim 1 , wherein the photothermographic material contains a development accelerator.