Production of carrageenan and carrageenan products
View Patent ↗The methods of the present invention prepare carrageenan products from processed seaweed material having a solids content of less than 25% by weight solids, using shear stress treatment. The carrageenan products comprise at least about 60% by weight of carrageenan and at least about 2% by weight of acid insoluble material. The carrageenan products of the present invention are useful as components in food products, such as, dairy products, meats, and dessert gels as well as non-food products, such as, toothpaste formulations, cosmetics, paints, films and delivery capsules.
1. A method comprising:
subjecting a carrageenan-containing seaweed material having a solids content of less than 25% by weight to a shear stress treatment to provide a carrageenan-containing product;
providing a solution containing-the carrageenan containing product;
forming a barrier material from the solution.
2. The method of claim 1 wherein the solution comprises water.
3. The method of claim 2 in which the amount of color development that occurs during the sheer stress treatment corresponds to less than about 4.0 L* units as measured using a Macbeth ColorEye 3000 colorimeter.
4. The method of claim 1 additionally comprising heating the solution comprising the carrageenan-containing product prior to forming the barrier material and depositing at least a portion of the solution upon a substrate.
5. The method of claim 4 in which the barrier is a capsule, the carrageenan material comprises κ-carrageenan, and the substrate is a cooled rotating drum.
6. The method of claim 1 wherein the barrier material is a film, bead or capsule.
7. A capsule comprising a carrageenan material prepared by subjecting a carrageenan-containing seaweed material having a solids content of less than 25% by weight to a shear stress treatment.
8. The capsule of claim 7 wherein the carrageenan material comprises κ-carrageenan.
9. The capsule of claim 8 in which the amount of color development that occurs during the sheer stress treatment corresponds to less than about 4.0 L* units as measured using a Macbeth ColorEye 3000 colorimeter.
10. The capsule of claim 9 in which the carrageenan is derived from Eucheuma cottonii and has an onset of hydration below about 50° C. as measured with a Brabender viscometer as a 2% by weight solids aqueous solution.
11. The capsule of claim 8 in which the carrageenan is derived from Eucheuma cottonii and has an onset of hydration below about 50° C. as measured with a Brabender viscometer as a 2% by weight solids aqueous solution.
12. The capsule of claim 7 in which the amount of color development that occurs during the sheer stress treatment corresponds to less than about 4.0 L* units as measured using a Macbeth ColorEye 3000 colorimeter.
13. The capsule of claim 12 in which the carrageenan is iota-carrageenan derived from Eucheuma spinosum that has an onset of hydration below about 30° C. as measured with a Brabender viscometer as a 2% by weight solids aqueous solution.
14. The capsule of claim 12 in which carrageenan material comprises at least about 60% by weight carrageenan and at least about 2% by weight of acid insoluble material.
15. A capsule comprising a film, wherein said film comprises a carrageenan material comprising at least about 60% by weight carrageenan and at least about 2% by weight of acid insoluble material and, optionally, at least one plasticizer, filler, binder, colorant, or flavorant.
16. A film composition comprising a carrageenan material comprising at least about 60% by weight carrageenan and at least about 2% by weight of acid insoluble material and, optionally, at least one plasticizer, filler, binder, colorant, or flavorant.
17. A semi-refined carrageenan product comprising at least about 60% by weight carrageenan and at least about 2% acid insoluble material.