Method for producing acrylate adhesive materials
View Patent ↗A process for preparing pressure sensitive adhesives based on acrylate hotmelt, in which a monomer mixture including at least the following monomers (a) 70 to 100% by weight of compounds from the group of (meth)acrylic acid and the derivatives thereof corresponding to the following general formula is free-radically polymerized in solution wherein I. the polymerization is initiated using at least one dissociating photoinitiator and by irradiation with ultraviolet light, the photoinitiator being added to the monomer mixture before the beginning of the polymerization and/or to the reaction mixture in the course of the polymerization, II. the polyacrylate is freed from the solvent, III. the polyacrylate is processed further in the melt.
1. A process for preparing pressure sensitive adhesives based on acrylate hotmelt, in which a monomer mixture including at least the following monomers
(a) 70 to 100% by weight of compounds selected from the group consisting of (meth)acrylic acid and the derivatives thereof corresponding to the following formula
with R 1 =H or CH 3 and R 2 =an alkyl chain having 2 to 20 carbon atoms and also including
(b) 0 to 30% by weight of olefinically unsaturated monomers containing functional groups
and also including
(c) optionally, further components
is free-radically polymerized in solution in a reactor to give a polyacrylate,
wherein
I. the polymerization is initiated using at least one dissociating photoinitiator and by irradiation with ultraviolet light, the photoinitiator being added to the monomer mixture before the beginning of the polymerization and/or to the reaction mixture in the course of the polymerization,
II. the polyacrylate is freed from the solvent,
III. the polyacrylate is processed further in the melt.
2. The process of claim 1 , wherein the at least one photolnitialor is or are used in an amount of from 0.1 to 2% by weight, based on the weight of the monomer mixture.
3. The process of claim 1 , wherein the irradiation with ultraviolet light is carried out in the form of two or more irradiation cycles and/or pulsed irradiation is carried out.
4. The process of claim 1 , wherein the free-radical polymerization is conducted at least up to a conversion of 98% of the monomers.
5. The process of claim 1 , wherein the removal of the solvent is carried out after the polymerization in a twin-screw extruder.
6. The process of claim 1 , wherein crosslinkers are added to the monomer mixture, to the reaction mixture or to the polyacrylate.
7. The process of claim 1 , wherein resins and/or additives are added to the monomer mixture, to the reaction mixture or to the polyacrylate.
8. The process of claim 1 , further comprising the step of applying the pressure sensitive adhesive from the melt to a backing material.
9. An adhesive tape provided with a layer of a self-adhesive prepared by the process of claim 1 on one or both sides.
10. The process of claim 2 , wherein said at least one photoinitiator is used in an amount of between 0.25 and 1% by weight, based on the weight of the monomer mixture.
11. The process of claim 6 , wherein said crosslinkers are selected from the group consisting of difunctional or polyfunctional acrylates, difunctional or polyfunctional methacrylates, difunctional or polyfunctional isocyanates, difunctional or polyfunctional epoxides, or mixtures thereof.
12. The process of claim 7 , wherein said resins and/or adhesives are selected from the group consisting of ageing inhibitors, light stabilizers, ozone protectants, fatty acids, plasticizers, nucleating agents, blowing agents, accelerators and fillers.