Method for the hydrolytic precipitation of iron
View Patent ↗The invention relates to a method for the hydrolytic precipitation of iron as jarosite from a sulphate-containing solution in connection with zinc recovery from zinc calcine. The recovey contains neutral leach, ferrite leach, zinc electrolysis and iron precipitation stages. The ferrite included in the calcine is leached with return acid of the electrolysis after which the iron present in ferrous form is neutralized and routed to an iron precipitation stage, where the iron is oxidised to the trivalent form using an oxygen-containing gas. Also present in the precipitation stage arc Na, K or NH 4 ions and jarosite nuclei.
1. A method for hydrolytic precipitation of iron as jarosite from a sulphate-containing solution in connection with zinc recovery from zinc calcine, which recovery contains neutral leach, ferrite leach, zinc electrolysis and iron precipitation stages, comprising: leaching the ferrite included in the calcine with return acid of the zinc electrolysis; after which reducing the ferric iron generated in the leach to ferrous form and neutralizing the ferrous iron; and in the iron precipitation stage, oxidizing the neutralized ferrous iron into trivalent form using oxygen-containing gas, with sodium, potassium or ammonium ions and jarosite nuclei being present in the iron precipitation stage and the temperature of the iron precipitation stage being at most that of the boiling point of the solution.
2. A method according to claim 1 , wherein the ferric iron is reduced using zinc concentrate.
3. A method according to claim 1 , wherein the ferric iron is reduced using sulphur dioxide.
4. A method according to claim 1 , wherein the reduction of the ferric iron is carried out using zinc concentrate, which is added to the ferrite leach stage.
5. A method according to claim 1 , wherein the ferrous iron contained in the solution from the ferric iron reducing stage is neutralised with zinc calcine.
6. A method according to claim 1 , wherein the ferrous iron contained in the solution from the ferric iron reducing stage is neutralised by routing the solution to the latter stage of a two-stage neutral leach of zinc calcine.
7. A method according to claim 1 , wherein the ferrous iron contained in the solution from the ferric iron reducing stage is neutralised at least to a pH level of 4 in order to precipitate gallium, indium and germanium.
8. A method for the hydrolytic precipitation of iron as jarosite from a sulphate-containing solution in connection with zinc recovery, comprising: leaching zinc calcine in a two-stage neutral leach; electrolysing the zinc sulphate solution formed and leaching the remaining undissolved ferrite with return acid of die electrolysis in a ferrite leach stage; reducing to divaleni form the ferrie iron dissolved in the ferrite leach; after which routing the precipitate formed to a zinc roaster and the solution to the second stage of the neutral leach; where the solution in the second stage of the neutral leach is neutralised using the residue from the first neutral leach stage; routing a residue from the second neutralisation stage to the ferrite leach and routing the neutralised solution to the iron precipitation stage; where the iron in the iron precipitation stage is precipitated as jarosite with oxygen in the presence of alkali or ammoniuni ions and jarosite nuclei.
9. A method according to claim 8 , wherein the ferric iron is reduced using zinc concentrate.
10. A method according to claim 8 , wherein the ferric iron is reduced using sulphur dioxide.