Oxide phosphor and radiation detector using it, and X-ray CT device
View Patent ↗An oxide phosphor includes an oxide consisting of at least Gd, Ce, Al, Ga, and O, and has the crystal structure of a garnet structure, the atomic ratio (Gd+Ce)/(Al+Ga+Gd+Ce) of which is more than 0.375 and 0.44 or less, and the atomic ratio Ce/(Ce+Gd) of which is 0.0005 or more and 0.02 or less. This oxide phosphor reduces composition misalignment occurring during sintering, being a drawback of a phosphor having (Gd 1-x Ce x ) 3 Al 5-y Ga y O 12 composition, and has a property of extremely small afterglow and high luminescence efficiency. By using this oxide phosphor as a scintillator of a radiation detector having a light detector, the radiation detector with low afterglow and high output can be obtained. Further, by applying this radiation detector to an X-ray CT apparatus, a tomogram with high resolution and high quality can be obtained.
1. An oxide phosphor having the oxide consisting of at least Gd, Ce, Al, Ga, and O, wherein a crystal structure of said oxide is a garnet structure, the atomic ratio (Gd+Ce)/(Al+Ga+Gd+Ce) is more than 0.375 and 0.44 or less, and the atomic ratio Ce/(Ce+Gd) is no less than 0.0005 and no more than 0.02.
2. An oxide phosphor according to claim 1 , wherein the atomic ratio Ga/(Al+Ga) is more than 0 and less than 1.0.
3. An oxide phosphor according to claim 1 , further including an impurity phase of a perovskite structure.
4. An oxide phosphor according to claim 3 , wherein the intensity of a main diffraction line of the perovskite structure in an X-ray diffraction measurement is 50% or less with respect to the intensity of the main diffraction line of the garnet structure.
5. An oxide phosphor according to claim 1 , wherein oxide powder is synthesized by at least one of the following methods: an oxide-mixing method, a coprecipitation method, and a mechanically grinding method using material powder.
6. An oxide phosphor according to claim 5 , wherein the diameters of crystal grain of the oxide-synthesized powder are 1 μm or less.
7. An oxide phosphor according to claim 5 , wherein said oxide-synthesized powder is sintered by at least one of the following methods: a hot-press method, an HIP method, a pressureless sintering method, and simultaneous use of a pressureless sintering method and an HIP method.
8. An oxide phosphor according to claim 7 , wherein the relative density of the sintered body of the oxide-synthesized powder is 99.0% or more.
9. A scintillator including a sintered body of the oxide phosphor according to claim 1 .
10. A radiation detector in an X-ray detector including a ceramics scintillator and a light detector for detecting light emission of said scintillator, wherein the scintillator according to claim 9 is employed as said ceramics scintillator.
11. An X-ray CT apparatus comprising:
an X-ray source;
an X-ray detector located opposite to said X-ray source;
a rotating disk holding said X-ray source and said X-ray detector, which is driven to rotate around an object to be examined; and
an image reconstruction means for image-reconstructing a tomogram of said object on the basis of intensity of X-rays detected by said X-ray detector,
wherein a radiation detector according to claim 10 is employed as said X-ray detector.
12. An oxide phosphor having the oxide consisting essentially of Gd, Ce, Al, Ga, and O, wherein a crystal structure of said oxide is a garnet structure, the atomic ratio (Gd+Ce)/(Al+Ga+Gd+Ce) is more than 0.375 and 0.44 or less, and the atomic ratio Ce/(Ce+Gd) is no less than 0.0005 and no more than 0.02.
13. An oxide phosphor according to claim 12 , wherein the atomic ratio Ga/(Al+Ga) is more than 0 and less than 1.0.
14. An oxide phosphor according to claim 12 , further including an impurity phase of a perovskite structure.
15. An oxide phosphor according to claim 14 , wherein the intensity of a main diffraction line of the perovskite structure in an X-ray diffraction measurement is 50% or less with respect to the intensity of the main diffraction line of the garnet structure.
16. An oxide phosphor according to claim 12 , wherein oxide powder is synthesized by at least one of the following methods: an oxide-mixing method, a coprecipitation method, and a mechanically grinding method using material powder.
17. An oxide phosphor according to claim 16 , wherein the diameters of crystal grain of the oxide-synthesized powder are 1 μm or less.
18. An oxide phosphor according to claim 16 , wherein said oxide-synthesized powder is sintered by at least one of the following methods: a hot-press method, an HIP method, a pressureless sintering method, and simultaneous use of a pressureless sintering method and an HIP method.
19. An oxide phosphor according to claim 18 , wherein the relative density of the sintered body of the oxide-synthesized powder is 99.0% or more.
20. A scintillator including a sintered body of the oxide phosphor according to claim 12 .
21. A radiation detector in an X-ray detector including a ceramics scintillator and a light detector for detecting light emission of said scintillator, wherein the scintillator according to claim 20 is employed as said ceramics scintillator.
22. An X-ray CT apparatus comprising:
an X-ray source;
an X-ray detector located opposite to said X-ray source;
a rotating disk holding said X-ray source and said X-ray detector, which is driven to rotate around an object to be examined; and
an image reconstruction means for image-reconstructing a tomogram of said object on the basis of intensity of X-rays detected by said X-ray detector,
wherein a radiation detector according to claim 21 is employed as said X-ray detector.
23. An oxide phosphor according to claim 12 , wherein the oxide consists of Gd, Ce, Al, Ga and O.
24. A scintillator including a sintered body of the oxide phosphor according to claim 23 .
25. A radiation detector in an X-ray detector including a ceramics scintillator and a light detector for detecting light emission of said scintillator, wherein the scintillator according to claim 24 is employed as said ceramics scintillator.
26. An X-ray CT apparatus comprising:
an X-ray source;
an X-ray detector located opposite to said X-ray source;
a rotating disk holding said X-ray source and said X-ray detector, which is driven to rotate around an object to be examined; and
an image reconstruction means for image-reconstructing a tomogram of said object on the basis of intensity of X-rays detected by said X-ray detector,
wherein a radiation detector according to claim 25 is employed as said X-ray detector.