Hose construction containing fluoroelastomer composition and fluoroplastic barrier
View Patent ↗The present invention relates to a hose comprising: a thermoplastic fluoropolymer barrier layer; and a rubber layer adjacent to the barrier layer, the rubber layer comprising 100 parts by weight of an elastomer comprising FKM fluoroelastomer; from about 1 to about 15 parts by weight, per 100 parts by weight of elastomer, of at least one acid acceptor selected from the group consisting of magnesium oxide, calcium hydroxide, litharge, dibasic lead phosphite, calcium oxide, and zinc oxide; from about 1 to about 6 parts by weight, per 100 parts by weight of elastomer, of at least one diamine curative; and from about 1 to about 10 parts by weight, per 100 parts by weight of elastomer, of at least one of a hydrotalcite or tricalcium aluminate hexahydrate; wherein the weight ratio of the at least one acid acceptor to the at least one hydrotalcite ranges from about 1 to about 5.
1. A hose comprising:
a thermoplastic fluoropolymer barrier layer comprising a thermoplastic quadpolymer derived from (i) tetrafluoroethylene, (ii) vinylidene fluoride, (iii) at least one ethylenically unsaturated monomer of the formula CF 2 ═CFR f where R f is a perfluoroalkyl or a perfluoroalkoxy of 1 to 8 carbon atoms, and (iv) a perfluorovinyl ether of the formula CF 2 ═CF—(OCF 2 CF(R f )) a OR′ f , where R f is as described in (iii), R′ f is a perfluoroaliphatic, a perfluoroalkyl or a perfluoroalkoxy, of 1 to 8 carbon atoms, and a has a value of 0 to 3; and
a rubber layer adjacent to said barrier layer, said rubber layer comprising 100 parts by weight of an elastomer comprising FKM which is a tetrafluoroethylene/hexafluoropropylene/vinylidene fluoride terpolymer composition;
from about 5 to about 15 parts by weight, per 100 parts by weight of elastomer, of at least one acid acceptor selected from the group consisting of magnesium oxide, calcium hydroxide, litharge, dibasic lead phosphite, calcium oxide, and zinc oxide;
from about 1 to about 6 parts by weight, per 100 parts by weight of elastomer, of at least one diamine curative; and
from about 1 to about 10 parts by weight, per 100 parts by weight of elastomer, of at least one of a hydrotalcite or tricalcium aluminate hexahydrate;
wherein the weight ratio of said at least one acid acceptor to said at least one of a hydrotalcite or tricalcium aluminate hexahydrate ranges from about 1:1 to about 5:1; and
from about 0.5 to about 6 parts by weight, per 100 parts by weight of elastomer, of at least one fatty amine selected from the group consisting of cocoalkylamines, 1-dodecylamine, 1-hexadecylamine, 1-octadecylamine, oleylamine, soyaalkylamines, tallowalkylamines, hydrogenated tallowalkylamines, dicocoalkylamines, di-n-docecylamine, di-n-hexadecylamine, di-n-octadecylamine, di(tallowalkyl)amines, di(hydrogenated tallowalkyl)amines, cocoalkyldimethylamines, dimethyl-n-octylamine, dimethyl-n-decylamine, dimethyl-n-dodecylamine, dimethyl-n-tetradecylamine, dimethyl-n-hexadecylamine, dimethyl-n-octadecylamine, dimethyloleylamines, di-n-decylmethylamine, dicocoalkylmethylamines, dihydrogenated tallowalkylmethylamines, tri-n-octylamine, tri-n-dodecylamine, and tri-n-hexadecylamine.
2. The hose of claim 1 , wherein said at least one fatty amine is di(hydrogenated tallowalkyl)amines of formula R 2 NH wherein R is C 16 H 33 to C 18 H 37 .
3. The hose of claim 1 , wherein said rubber layer comprises from about 1 to about 3 phr of said at least one fatty amine.
4. The hose of claim 1 , wherein said at least one acid acceptor is magnesium oxide.
5. The hose of claim 1 , wherein said rubber layer comprises from about 5 to about 15 phr of said at least one acid acceptor.
6. The hose of claim 1 , wherein said rubber layer further comprises from about 0 to about 10 phr of a dibutyl sebacate plasticizer.
7. The hose of claim 1 , wherein said rubber layer further comprises from 0 to about 30 phr of carbon black.
8. The hose of claim 1 , wherein said rubber layer comprises from 2 to about 8 phr of at least one of a hydrotalcite and tricalcium aluminate hexahydrate.
9. The hose of claim 1 , wherein said at least one hydrotalcite includes hydrotalcites having the formula Mg (1-x) Al x (OH) 2 (CO 3 ) x/2 .n H 2 O; 0.25<x<0.33.
10. The hose of claim 1 , wherein said rubber layer comprises from 1 to about 4 phr of said at least one diamine curative.
11. The hose of claim 1 , wherein the thermoplastic quadpolymer is derived from tetrafluoroethylene, hexafluoropropylene, vinylidene fluoride, and a perfluorovinyl ether of one of the following formulas:
CF 2 ═CFOCF 2 CF 2 CF 3
12. The hose of claim 1 , wherein the thermoplastic quadpolymer is derived from (i) 40 to 80 weight percent tetrafluoroethylene, (ii) 10 to 30 weight percent vinylidene fluoride, (iii) 5 to 40 weight percent of a comonomer of the formula CF 2 ═CFR f , and (iv) 0.1 to 15 weight percent of the perfluorovinyl ether of the formula CF 2 ═CF—(OCF 2 CF(R f )) a OR′ f .
13. The hose of claim 1 , wherein said FKM fluoroelastomer comprises about 0 to 70 parts by weight tetrafluoroethylene, about 20 to 50 parts by weight hexafluoropropylene and about 20 to 80 parts by weight vinylidene fluoride, based on 100 parts by weight of FKM.
14. The hose of claim 1 , wherein said barrier layer is the innermost layer of the hose.
15. The hose of claim 1 , wherein said rubber layer is the innermost layer of the hose.
16. The hose of claim 1 , wherein said at least one diamine curative is selected from N,N′-dicinnamylidene-1,6-hexanediamine and 4,4′-methylenebis(cyclohexylamine)carbamate.
17. The hose of claim 16 , wherein the at least one fatty amine is di(hydrogenated tallowalkyl)amines of formula R 2 NH wherein R is C 16 H 33 to C 18 H 37 .