Polyester tackifier and adhesive composition
View Patent ↗The invention relates to a novel polyester tackifier, adhesive compositions comprising the tackifier and methods of preparation. More specifically, the polyester tackifier is obtainable by polymerising a mixture comprising a diacid or derivative thereof, a diol, and at least 6 molar % of an organic monofunctional compound, wherein the mixture is essentially free from compounds comprising more than two carboxylic acid groups or alcohol groups.
1. An aqueous or a hot melt pressure sensitive adhesive composition comprising a polymer and a non-branched polyester tackifier, wherein the polyester tackifier is obtained by polymerizing a mixture comprising a diacid or derivative thereof, a diol, and between 6 molar % and 40 molar % of an organic monofunctional compound, the mixture being essentially free from compounds comprising more than two carboxylic acid groups or two alcohol groups.
2. A pressure sensitive adhesive composition according to claim 1 , wherein the mixture comprises from 15 up to 45 molar % of a diacid, from 30 up to 55 molar % of the diol.
3. A pressure sensitive adhesive composition according to claim 1 , wherein the mixture comprises from 10 molar % up to 40 molar % of the organic monofunctional compound.
4. A pressure sensitive adhesive composition according to claim 1 , wherein the mixture comprises from 15 molar % up to 35 molar % of an organic monofunctional compound.
5. A pressure sensitive adhesive composition according to claim 1 , wherein the organic monofunctional compound is a monocarboxylic acid or monohydric alcohol.
6. A pressure sensitive adhesive composition according to claim 5 , wherein the organic monofunctional compound is a monocarboxylic acid.
7. A pressure sensitive adhesive composition according to claim 6 , wherein the monocarboxylic acid is a rosin derived from natural sources.
8. A pressure sensitive adhesive composition according to claim 1 , wherein the diacid is an aromatic diacid.
9. A pressure sensitive adhesive composition according claim 1 , wherein the diol is an alkylene glycol or a polyalkylene glycol or a mixture thereof.
10. A method of bonding an adhesive and substrate by contacting the pressure sensitive adhesive composition of claim 1 with a substrate and pressing it to the substrate.
11. A pressure sensitive adhesive composition according to claim 1 , wherein the mixture comprises less than 1 molar % based on total monomers of compounds comprising more than two carboxylic acid groups or two alcohol groups.
12. A pressure sensitive adhesive composition according to claim 1 , wherein the derivative of the diacid is capable of forming an ester moiety in the polyester.
13. A pressure sensitive adhesive composition according to claim 8 , wherein the aromatic diacid has dicarboxylic acid moieties in the para or ortho position.
14. A pressure sensitive adhesive composition according to claim 13 , wherein the aromatic diacid is terephthalic or phthalic acid.
15. The pressure sensitive adhesive according to claim 1 wherein the tackifier has a number average molecular weight between 400 and 6000.
16. The pressure sensitive adhesive according to claim 1 wherein the tackifier has a polydispersity from 1.1 to 2.0.
17. A method of making a non-branched polyester tackifier comprising polymerizing a mixture of diacid or derivative thereof, a diol and between 6 molar % and 40 molar % of an organic monofunctional compound in an inert gas atmosphere at a temperature between 150° C. to 350° C., wherein the mixture is essentially free from compounds comprising more than two carboxylic acid groups or two alcohol groups.
18. The pressure sensitive adhesive composition of claim 1 wherein the polyester tackifier is non-aqueous and is present is an amount between 30 and 60 molar %, based on the total composition.
19. The pressure sensitive adhesive composition of claim 1 wherein the polymer is a thermoplastic.