Fuel cell system
View Patent ↗A process for producing electricity in a fuel cell which comprises: a) pre-reforming a higher carbon (C2+) hydro-carbon fuel in a pre-reformer under conditions effective to achieve substantially complete conversion of higher carbon (C2+) hydro-carbons to produce a pre-reformed fuel stream; b) subjecting the pre-reformed fuel stream to methanation under conditions effective to produce a fuel stream having an increased concentration of methane relative to the pre-reformed fuel stream; and c) supplying the fuel stream and an oxidant to a high temperature fuel cell in which methane is reformed and electricity is produced by reacting the fuel stream at an anode of the fuel cell and reacting the oxidant at a cathode of the fuel cell.
1. A process for producing electricity in a fuel cell which comprises:
a) pre-reforming a higher carbon (C 2+ ) hydrocarbon fuel in a pre-reformer at a temperature of at least 300° C. under conditions effective to achieve substantially complete conversion of higher carbon (C 2+ ) hydrocarbons to produce a pre-reformed fuel stream containing methane, hydrogen and oxides of carbon;
b) subsequently subjecting the pre-reformed fuel stream obtained in a) to methanation at a temperature in the range of 250° C. to 450° C. and which is less than the pre-reforming temperature under conditions effective to produce a fuel stream having an increased concentration of methane relative to the pre-reformed fuel stream; and
c) supplying the fuel stream and an oxidant to a high temperature fuel cell in which methane is reformed and electricity is produced by reacting the fuel stream at an anode of the fuel cell and reacting the oxidant at a cathode of the fuel cell,
wherein the methane content of the fuel stream resulting from methanation is at least 40% by volume (measured on a dry basis).
2. A process according to claim 1 , wherein the higher carbon hydrocarbon fuel is pre-reformed by partial oxidation.
3. A process according to claim 2 , wherein partial oxidation takes place at a temperature of at least 400° C.
4. A process according to claim 1 , wherein the higher carbon hydrocarbon fuel is pre-reformed using an autothermal reformer.
5. A process according to claim 4 , wherein the autothermal reformer is operated at a temperature of at least 400° C.
6. A process according to claim 1 , wherein the fuel pre-reforming and methanation are carried out in a single reactor having a first healing zone for fuel pre-reforming and a second zone for methanation.
7. A process according to claim 1 , wherein the fuel pre-reforming and methanation are carried out in two separate reactors provided in series.
8. A process according to claim 1 , wherein pre-reforming results in 97.5% or greater conversion of C 2+ hydrocarbons.
9. A process according to claim 1 , wherein there is no more than about 0.5 vol % (measured on a dry basis) C 2+ hydrocarbons present in the fuel stream to the fuel cell.
10. A process according to claim 1 , wherein the fuel cell is operated at a temperature of at least 650° C.
11. A process according to claim 1 , wherein waste heat from the fuel cell is recycled to the pre-reformer and/or methanator.