Method and device for the continuous polycondensation of polyester material in the solid phase
View Patent ↗The invention relates to a method and device for the continuous polycondensation of polyester material in the solid phase, in particular in the form of partially crystalline granulate. The aim of the invention is to achieve a high product throughput on recrystallising and recondensation of polyester material with a low initial IV. Said aim is achieved, whereby on recrystallisation, a low residence time of 1-10 minutes is achieved, by means of a rapid heating of a thin product layer, followed by an SSP treatment.
1. A process for the continuous polycondensation of polyester material in a solid phase comprising the steps of
passing a flow of hot gas through a fluidized bed of polyester granulate to heat the polyester granulate at a rate of from 50° C./minute to 100° C./minute to a temperature in a range of from 200° C. to 235° C.;
passing the heated polyester granulate from the fluidized bed through a post-crystallizer in heat exchange relation with a flow of heated gas to maintain the temperature of the polyester granulate in a range of from 200° C. to 250° C.; and
thereafter passing the polyester granulate from the post-crystallizer into a cooler in heat exchange relation with a flow of cooling gas to reduce the temperature to under 60° C. after solid state polymerisation.
2. A process as set forth in claim 1 wherein the flow of hot gas is passed through the fluidized bed to heat the polyester granulate at a rate of 50° C./minute.
3. A process as set forth in claim 1 wherein the flow of hot gas is passed through the fluidized bed to heat the polyester granulate at a rate of 100° C./minute.
4. A process as set forth in claim 1 wherein the fluidized bed of polyester granulate has a thickness of from 2 to 15 centimeters.
5. A procedure for the continuous polycondensation of polyester material in a solid phase, said procedure comprising the steps of
forming a layer of one of an amorphous or partially crystallized polyester granulate with a thickness of from 2 to 15 cm;
passing a hot process gas through said layer to heat the polyester granulate during a retention time of from 1 to 10 minutes at a heating rate of from 50° C./minute to 100° C./minute to a temperature of from 200° C. to 235° C.;
thereafter subjecting the heated polyester granulate to post-crystallizing at a temperature between 200° C. and 250° C.;
subsequently subjecting the post-crystallized polyester granulate to post-condensation at a temperature of between 200° C. and 250° C.; and
cooling the post-condensed polyester granulate to a temperature of under 60° C.
6. The procedure according to claim 5 further characterized in that said layer measures 3-8 cm.
7. The procedure according to claim 5 further characterized in that said retention time is from 2 to 8 minutes.
8. The procedure according to claim 7 further characterized in that said process gas is a high quantity of gas with a flow rate of 1.5 to 4 m/s.
9. The procedure according to claim 8 further characterized in that said process gas traverses the polyester granulate in one of a cross current, counter current and parallel current.
10. The procedure according to claim 9 further characterized in that the post-condensed polyester granulate is passed in heat exchange relation with the process gas prior to the process gas passing through said layer to cool the polyester granulate while heating the process gas.
11. The procedure according to claim 5 characterized in that nitrogen is used as the process gas.