Conductive plastic molding material, the use thereof and moulded bodies produced therefrom
View Patent ↗The present invention relates to a plastics molding composition based on polyarylene sulfide and/or on liquid-crystalline plastic, where the molding composition comprises carbon black and graphite and/or metal powder, the carbon black has a specific surface area of from 500 to 1500 m 2 /g, and a dibutyl phthalate value of from 100 to 700 ml/100 g, and the graphite has a specific surface area of from 1 to 35 m 2 /g. The molding compositions of the invention have good conductivities, and better flowabilities and mechanical properties.
1. A bipolar plate, end plate, or part of an end plate of a fuel cell, comprising a liquid-crystalline plastic and a conductive molding composition based on liquid-crystalline plastic, wherein the conductive molding composition comprises, as conductive constituents,
A) carbon black and graphite, or
B) carbon black and metal powder, or
C) carbon black and graphite and metal powder,
the carbon black has a specific surface area of from 500 to 1500 m 2 /g, and a dibutyl phthalate value of from 470 to 700 ml/l 100 g, and the graphite has a specific surface area of from 1 to 35 m 2 /g and a median particle size of from 50 to 450 βm.
2. A process for producing a bipolar plate, endplate, or part of an endplate for fuel cells from a liquid-crystalline plastic molding composition wherein the plastic molding composition comprises, as conductive constituents,
A) carbon black and graphite, or
B) carbon black and metal powder, or
C) carbon black and graphite and metal powder,
the carbon black has a specific surface area of from 500 to 1500 m 2 /g, and a dibutyl phthalate value of from 470 to 700 ml/100 g, and the graphite has a specific surface area of from 1 to 35 m 2 /g and a median particle size of from 50 to 450 βm, which comprises production via compression molding.
3. The process as claimed in claim 2 , wherein the plastics molding composition has been pre-ground and has particle sizes of from 1500 to 50 βm.
4. The process as claimed in claim 2 , wherein the plastics molding composition has been pre-ground and has particle sizes of from 1,000 to 100 μm.
5. The process as claimed in claim 2 , wherein the plastics molding composition has been pre-ground and has particle sizes of from 800 to 150 μm.
6. The molding as claimed in claim 5 , wherein the molding is a bipolar plate, an end plate or a part of an end plate of a fuel cell.
7. A process for producing a bipolar plate, endplate, or part of an endplate for fuel cells from a liquid-crystalline plastic molding composition wherein the plastic molding composition comprises, as conductive constituents,
A) carbon black and graphite, or
B) carbon black and metal powder, or
C) carbon black and graphite and metal powder,
the carbon black has a specific surface area of from 500 to 1500 m 2 /g, and a dibutyl phthalate value of from 470 to 700 ml/100 g, and the graphite has a specific surface area of from 1 to 35 m 2 /g and a median particle size of from 50 to 450 βm, which comprises production in a single step of a process, by bringing together the compounding step and the preparation step to give a single-stage process.
8. The process as claimed in claim 7 , wherein the method of production is injection-molding compounding with injection-compression molding unit.
9. The process as claimed in claim 7 , wherein the method of production is melt-application compression molding.