Steel wire for heat-resistant spring, heat-resistant spring and method for producing heat-resistant spring
View Patent ↗A high-strength steel wire for heat-resistant springs has both excellent high-temperature tensile strength and excellent high-temperature sag resistance at a temperature as high as 350 to 500° C., particularly at 400° C. or so (these properties are needed for spring materials). The steel wire contains (a) 0.01 to 0.08 wt % C, 0.18 to 0.25 wt % N, 0.5 to 4.0 wt % Mn, 16 to 20 wt % Cr, and 8.0 to 10.5 wt % Ni, (b) at least one constituent selected from the group consisting of 0.1 to 3.0 wt % Mo, 0.1 to 2.0 wt % Nb, 0.1 to 2.0 wt % Ti and 0.3 to 2.0 wt % Si, and (c) mainly Fe and unavoidable impurities both of which constitute the remainder. The steel wire has (a) a tensile strength of at least 1,300 N/mm 2 and less than 2,000 N/mm 2 before being treated with low-temperature annealing, and (b) a maximum crystal-grain diameter of less than 12 μm in the γ phase (austenite) in a transverse cross section of the wire.
1. A steel wire for heat-resistant springs, the steel wire containing:
(a) 0.01 to 0.08 wt % C, 0.18 to 0.25 wt % N, 0.5 to 4.0 wt % Mn, 16 to 20 wt % Cr, 8.0 to 10.5 wt % Ni, and 0.2 to 2.0 wt % Co;
(b) at least one constituent selected from the group consisting of 0.1 to 3.0 wt % Mo, 0.1 to 2.0 wt % Nb, 0.1 to 2.0 wt % Ti and 0.3 to 2.0 wt % Si; and
(c) mainly Fe and unavoidable impurities both of which constitute the remainder;
the steel wire having:
(d) a tensile strength of at least 1,300 N/mm 2 and less than 2,000 N/mm 2 before being treated by low-temperature annealing;
(e) a maximum crystal-grain diameter of less than 12 μm in the γ phase (austenite) in a transverse cross section of the wire; and
(f) a surface roughness, expressed as Rz, of 1 to 20 μm, the surface roughness being defined as a roughness in the direction of wire drawing.
2. A steel wire as defined by claim 1 , wherein the shape of the transverse cross section of the steel wire is selected from the group consisting of a square, rectangle, trapezoid, ellipse, and oval.
3. A method for producing a heat-resistant spring, the method comprising the steps of:
(a) forming a spring by using a steel wire containing:
(a1) 0.01 to 0.08 wt % C, 0.18 to 0.25 wt % N, 0.5 to 4.0 wt % Mn, 16 to 20 wt % Cr, 8.0 to 10.5 wt % Ni, and 0.2 to 2.0 wt % Co;
(a2) at least one constituent selected from the group consisting of 0.1 to 3.0 wt % Mo, 0.1 to 2.0 wt % Nb, 0.1 to 2.0 wt % Ti and 0.3 to 2.0 wt % Si; and
(a3) mainly Fe and unavoidable impurities both of which constitute the remainder;
the steel wire having:
(a4) a tensile strength of at least 1,300 N/mm 2 and less than 2,000 N/mm 2 before being treated by low-temperature annealing; and
(a5) a maximum crystal-grain diameter of less than 12 μm in the γ phase (austenite) in a transverse cross section of the wire; and
(a6) a surface roughness, expressed as Rz, of 1 to 20 μm. the surface roughness being defined as a roughness in the direction of wire drawing; and
(b) treating the spring with low-temperature annealing at a temperature of 450 to 600° C., wherein
the step of forming the spring includes performing solution treatment at a temperature of 950 to 1.200° C., a temperature-maintaining period of which is 0.3 to 5 min/mm, the temperature-maintaining period being expressed by a ratio of maintaining period (mm) and wire diameter (mm), and controlling wire drawing reduction of area to be within 50 to 70%.
4. A method as defined by claim 3 , wherein the low-temperature annealing is performed at a temperature of 500 to 550° C. so as to increase the tensile strength of the steel wire by at least 15%.
5. A method for producing a heat-resistant spring, the method comprising the steps of:
forming a spring by using a steel wire containing
(a) 0.01 to 0.08 wt % C, 0.18 to 0.25 wt % N, 0.5 to 4.0 wt % Mn, 16 to 20 wt % Cr, 8.0 to 10.5 wt % Ni, and 0.2 to 2.0 wt % Co,
(b) at least one constituent selected from the group consisting of 0.1 to 3.0 wt % Mo, 0.1 to 2.0 wt % Nb, 0.1 to 2.0 wt % Ti and 0.3 to 2.0 wt % Si, and
(c) mainly Fe and unavoidable impurities both of which constitute the remainder;
the steel wire having
(d) a tensile strength of at least 1,300 N/mm 2 and less than 2,000 N/mm 2 before being treated by low-temperature annealing,
(e) a maximum crystal-grain diameter of less than 12 μm in the γ phase (austenite) in a transverse cross section of the wire, and
(f) a surface roughness, expressed as Rz, of 1 to 20 μm, the surface roughness being defined as a roughness in the direction of wire drawing; and
treating the spring with low-temperature annealing at a temperature of 450 to 600°C.
6. A steel wire for heat-resistant springs, the steel wire containing:
(a1) 0.01 to 0.08 wt % C, 0.18 to 0.25 wt % N, 0.5 to 4.0 wt % Mn, 16 to 20 wt % Cr, 8.0 to 10.5 wt % Ni, and 0.2 to 2.0 wt % Co;
(a2) at least one constituent selected from the group consisting of 0.1 to 3.0 wt % Mo, 0.1 to 2.0 wt % Nb, 0.1 to 2.0 wt % Ti and 0.3 to 2.0 wt % Si; and
(a3) mainly Fe and unavoidable impurities both of which constitute the remainder;
the steel wire having:
(a4) a tensile strength of at least 1,300 N/mm 2 and less than 2,000 N/mm 2 before being treated by low-temperature annealing;
(a5) a maximum crystal-grain diameter of less than 12 μm in the γ phase (austenite) in a transverse cross section of the wire; and
(a6) a surface roughness, expressed as Rz, of 1 to 20 μm, the surface roughness being defined as a roughness in the direction of wire drawing, wherein
solution treatment is performed at a temperature of 950 to 1,200 0C, a temperature-maintaining period of which is 0.3 to 5 min/mm, the temperature-maintaining period being expressed by a ratio of maintaining period (min) and wire diameter (mm), and
wire drawing reduction of area is controlled to be within 50 to 70%.