Semi-continuous photochemical method and device therefor
View Patent ↗In the photochemical synthetic process in semi-continuous mode according to the invention, a reactor comprising two zones is used, the radiating portion of the lamp(s) being totally immersed in a first zone which is completely filled with reaction medium and spills off via an overflow into a second zone whose volume is sufficient to contain the volume of reaction medium originating from the first zone and corresponding substantially to the volume of the reagent(s) gradually introduced.
1. A semi-continuous photochemical synthesis process comprising:
introducing a first reagent selected from a mercaptan or hydrogen sulphide into a first reaction zone of a photochemical reactor which comprises two zones, in a quantity sufficient to totally immerse a radiating portion of a lamp therein; thereafter
activating said lamp; and thereafter
gradually introducing a second alkene reagent into said first reaction zone, forming a reaction medium comprising said first reagent and said second alkene reagent; said second alkene reagent introduced in sufficient quantity to cause said reaction medium in said first reaction zone to overflow said first reaction zone and spill off, via an overflow, into a second zone of said photochemical reactor whose volume is sufficient to contain said overflow of said reaction medium corresponding substantially to the volume of said second alkene reagent introduced.
2. Process according to claim 1 , in which said lamp comprises one or more lamps delivering UV radiation of wavelengths between 200 and 400 nm.
3. Process according to claim 1 , wherein said photochemical reactor is maintained at a pressure ranging from 0.1 to 50 bar relative.
4. Process according to claim 3 , wherein said photochemical reactor is maintained at a pressure of between 2 and 10 bar relative.
5. Process according to claim 1 , wherein said photochemical reactor is maintained at a temperature of between −20 and 120° C.
6. Process according to claim 1 , wherein said photochemical reactor is maintained at a temperature of between 10 and 90° C.
7. Process according to claim 1 , in which the mercaptan is methyl mercaptan and the second alkene reagent is ethylene.
8. Process according to claim 1 , in which the ratio of the volume of the first zone to the volume of the second zone is between 0.4 and 0.7.
9. Process according to claim 1 , further comprising gradually introducing a photoinitiator into said first reaction zone.