Use of fatty alcohols ethoxylates as penetration promoters
View Patent ↗This invention relates to fatty alcohol ethoxylates of the formula in which m represents average values from 8.0 to 13.0 and n represents average values from 6.0 to 17.0, that are highly suitable for use as penetrants for insecticidally active neonicotinyls when employed in amounts such that they are present in the commercial formulations in concentrations from 0.1 to 30% by weight and such that the weight ratio of neonicotinyl to fatty alcohol ethoxylate is from 1:0.1 to 1:2.0.
1. A method of promoting penetration of plants by insecticidally active neonicotinyls comprising applying to a plant a composition comprising
(a) from 0.1 to 30% by weight, based on the composition, of a fatty alcohol ethoxylate of formula (I)
in which
m represents an average value from 8.0 to 13.0, and
n represents an average value from 6.0 to 17.0, and
(b) an insecticidally active neonicotinyl at a weight ratio of neonicotinyl to fatty alcohol ethoxylate of from 1:0.1 to 1:2.0.
2. A method according to claim 1 wherein the insecticidally active neonicotinyl is imidacloprid, nitenpyram, acetamiprid, thiacloprid, thiamethoxam, clothianidin, or dinotefuran.
3. A plant treatment composition comprising
(a) from 0.1 to 30% by weight, based on the composition, of a fatty alcohol ethoxylate of formula (I)
in which
m represents an average value from 8.0 to 13.0, and
n represents an average value from 6.0 to 17.0, and
(b) an insecticidally active neonicotinyl at a weight ratio of neonicotinyl to fatty alcohol ethoxylate of from 1:0.1 to 1:2.0.
4. A plant treatment composition according to claim 3 comprising
(a) from 0.1 to 30% by weight, based on the composition, of a fatty alcohol ethoxylate of formula (I),
(b) from 0.1 to 50% by weight, based on the composition, of an insecticidally active neonicotinyl,
(c) from 1 to 80% by weight, based on the composition, of dimethyl sulfoxide, N-methylpyrrolidone, butyrolactone, or a mixture thereof, and
(d) from 0 to 20% by weight, based on the composition, of one or more additives.
5. A plant treatment composition according to claim 4 wherein, for the fatty alcohol ethoxylate of formula (I),
m represents an average value from 9.0 to 12.0, and
n represents an average value from 7.0 to 9.0.
6. A plant treatment composition according to claim 4 wherein, for the fatty alcohol ethoxylate of formula (I),
m represents an average value of 10.5, and
n represents an average value of 8.4.
7. A plant treatment composition according to claim 4 wherein the insecticidally active neonicotinyl is imidacloprid, nitenpyram, acetamiprid, thiacloprid, thiamethoxam, clothianidin, or dinotefuran.
8. A plant treatment composition according to claim 4 wherein the one or more additives are agrochemically active compounds, crystallization inhibitors, wetting agents, emulsifiers, water, or mixtures thereof.
9. A plant treatment composition according to claim 4 comprising
(a) from 0.5 to 15% by weight, based on the composition, of a fatty alcohol ethoxylate of formula (I),
(b) from 2.5 to 30% by weight, based on the composition, of an insecticidally active neonicotinyl,
(c) from 30 to 80% by weight, based on the composition, of dimethyl sulfoxide, N-methylpyrrolidone, butyrolactone, or a mixture thereof, and
(d) from 0 to 15% by weight, based on the composition, of one or more additives.
10. A ready-to-use plant treatment composition comprising
(a) a fatty alcohol ethoxylate of formula (I)
in which
m represents an average value from 8.0 to 13.0, and
n represents an average value from 6.0 to 17.0, and
(b) from 0.001 to 0.03% by weight, based on the composition, of an insecticidally active neonicotinyl at a weight ratio of neonicotinyl to fatty alcohol ethoxylate of from 1:0.1 to 1:2.0,
(c) from 0 to 50% by weight, based on the composition, of dimethyl sulfoxide, N-methylpyrrolidone, butyrolactone, or a mixture thereof, and
(d) from 0 to 95% by weight, based on the composition, of one or more additives.