Process for inhibiting polymerization of an aromatic vinyl compound
View Patent ↗According to the present invention, there is provided a process for inhibiting the polymerization of an aromatic vinyl compound which is capable of efficiently inhibiting the polymerization of an aromatic vinyl compound not only in an initial stage but also over a long term in the stage of producing, purifying, storing or transporting the aromatic vinyl compound, and which is excellent in handling. The present invention relates to a process for inhibiting the polymerization of an aromatic vinyl compound which requires the step of adding a 2-nitrophenol compound in combination with a sulfonic acid compound to the aromatic vinyl monomer during the stage of producing, purifying, storing or transporting the aromatic vinyl compound.
1. A process for inhibiting polymerization of an aromatic vinyl compound which is characterized by adding (A) 2-nitrophenol compound represented by the general formula (I) together with (B) sulfonic acid compound represented by the general formula (II) to the aromatic vinyl compound during the stage of producing, purifying, storing or transporting the aromatic vinyl compound
wherein A, B, C and D independently represent hydrogen, a nitro group, a carboxyl group, a hydroxyl group, or a straight or branched chain alkyl group having 1–12 carbon atoms,
wherein R represents a hydroxyl group, a straight or branched chain alkyl group having 1–32 carbon atoms, an alkyl phenyl or an alkyl naphthyl group, each having at least one straight or branched chain alkyl group having 1–32 carbon atoms.
2. The process for inhibiting polymerization of an aromatic vinyl compound as claimed in claim 1 , wherein the 2-nitrophenol compound represented by the general formula (I) is at least one member selected from the group consisting of 2,4-dinitrophenol, 2,6-dinitrophenol, 2,4-dinitro-6-methylphenol, 2,6-dinitro-4-methylphenol, 2,4-dinitro-6-sec-butylphenol and 2,6-dinitro-4-sec-butylphenol.
3. The process for inhibiting polymerization of an aromatic vinyl compound as claimed in claim 1 , wherein the sulfonic acid compound represented by the general formula (II) is at least one member selected from the group consisting of sulfuric acid, toluenesulfonic acid, xylenesulfonic acid, cumenesulfonic acid, dodecylbenzenesulfonic acid, pentadecylbenzenesulfonic acid and dinonylnaphthalenesulfonic acid.
4. The process for inhibiting polymerization of an aromatic vinyl compound as claimed in claim 1 , wherein the (A) 2-nitrophenol compound and (B) sulfonic acid compound are added in combination in a proportion of 5:95–95:5 in weight ratio.
5. The process for inhibiting polymerization of an aromatic vinyl compound as claimed in claim 1 , wherein the 2-nitrophenol compound is at least one member selected from the group consisting of 2,4-dinitro-6-sec-butylphenol, 2,6-dinitro-4-sec-butylphenol, 2,4-dinitrophenol, 2,6-dinitrophenol, 2,4-dinitro-6-methylphenol and 2,6-dinitro-4-methylphenol and the sulfonic acid compound is at least one member selected from the group consisting of sulfuric acid, methanesulfonic acid, p-toluenesulfonic acid, xylenesulfonic acid, cumenesulfonic acid, dodecylbenzenesulfonic acid, pentadecylbenzenesulfonic acid and dinonylnaphthalenesulfonic acid.