Hydrophilic additives
The invention relates to hydrophilic additives for synthetic fibres containing polyolefin; said additives are represented by general formula (I): A—B—C—B—A wherein A is a radical R—COO, wherein R represents a saturated, cross-linked or non-cross-linked alkyl radical having 7–21 C atoms, B represents a group (C n H 2n O) k , wherein n is a whole number from 2–4 and k can have a value of 1–15, C represents a linear or cross-linked alkylene radical having at least 2 and at the most 6 C atoms and the radical C can be, optionally, interrupted by oxygen atoms.
1. An internal hydrophilicizing additive of a formula:
A—B—C—B—A (I)
wherein A represents a residue of fatty acid R—CO wherein R is a linear alkyl group containing 9 carbon atoms, B represents a group (C n H 2n O) k in which k has a value of 5, n has a valued 2 and C is a —O—CH 2 CH(CH 3 )—O— group.
2. An internal hydrophilicizing additive of a formula:
A—B—C—B—A (I)
wherein A represents a residue of fatty acid R—CO wherein R is a linear alkyl group containing 11 carbon atoms, B represents a group (C n H 2n O) k in which k has a value of 5, n has a valued 2 and C is a —O—CH 2 CH(CH 3 )—O— group.
3. A synthetic fiber composition comprising a mixture of:
(a) a polyolefin; and
(b) an additive of the formula:
A—B—C—B—A (I)
wherein A represents a residue of a fatty acid R—CO in which R is a saturated, branched or unbranched C 7-21 alkyl group, B represents a (C n H 2n O) k group in which n is an integer of from 2 to 4 and k has a value of from 1 to about 15, and C is a linear or branched residue of a diol selected from the group consisting of —O—CH 2 —CH(CH 3 )—O—, —O—CH 2 —CH 2 —CH 2 —O—, —O(CH 2 ) 4 —O—, —O—CH 2 —CH 2 —CH 2 —O—CH 2 —CH 2 —CH 2 —O—, and —O—CH 2 CH(CH 3 )—O—CH 2 —CH(CH 3 )—O—.
4. The composition of claim 3 wherein in formula (I), R is a saturated linear alkyl group containing 9 to 13 carbon atoms.
5. The composition of claim 3 wherein in formula (I), k has a value of 1 to 15.
6. The composition of claim 3 , wherein in formula (I), k has a value of 4 to 10.
7. The composition of claim 3 wherein in formula (I), k has a value of 5.
8. The composition of claim 3 wherein in formula (I), n has a value of 2.
9. The composition of claim 3 wherein in formula (I), R is a linear alkyl group containing 9 carbon atoms, k has a value of 5, n has a value of 2 and C is a —O—CH 2 —CH(CH 3 )—O— group.
10. The composition of claim 3 wherein in formula (I), R is a linear alkyl group containing 11 carbon atoms, k has a value of 5, n has a value of 2 and C is a —O—CH 2 —CH(CH 3 )—O— group.
11. The composition of claim 3 wherein the additive has a cold cloud point below 12° C.
12. The composition of claim 3 wherein the additive is present in the composition in an amount of from about 0.1 to 30% by weight, based on the weight of the composition.
13. A process for hydrophilicizing synthetic polyolefin fibers comprising adding to the fibers an additive of the formula:
A—B—C—B—A (I)
wherein A represents a residue of a fatty acid R—CO in which R is a saturated branched or unbranched C 7-21 alkyl group, B represents a group (C n H 2n O) k in which n is an integer of from 2 to 4 and k has a value of from 1 to about 15, and C is a linear or branched residue of a diol selected from the group consisting of —O—CH 2 —CH(CH 3 )—O—, —O—CH 2 —CH 2 —CH 2 —O—, —O—(CN 2 ) 4 —O—, —O—CH 2 —CH(CH 3 —) —O—CH 2 —CH(CH 3 )—O—, and —O—CH 2 CH 2 CH 2 —O—CH 2 CH 2 CH 2 —O—.
14. The process of claim 13 wherein in formula (i), R is a saturated linear alkyl group containing 9 to 13 carbon atoms.
15. The process of claim 13 wherein in formula (I), k has a value of 1 to 15.
16. The process of claim 13 wherein in formula (I), k has a value of 4–10.
17. The process of claim 13 wherein in formula (I), k has a value of 5.
18. The process of claim 13 wherein in formula (I), n has a value of 2.
19. The process of claim 13 wherein in formula (I), R is a linear alkyl group containing 9 carbon atoms, k has a value of 5, n has a value of 2 and C is a —O—CH 2 —CH(CH 3 )—O— group.
20. The process of claim 13 wherein in formula (I), R is a linear alkyl group containing 11 carbon atoms, k has a value of 5, n has a value of 2 and C is a —O—CH 2 —CH(CH 3 )—O— group.
21. The process of claim 13 wherein the additive has a cold cloud point below 12° C.
22. The process of claim 13 where the additive is present in the composition in an amount of from about 0.1 to 30% by weight, based on the weight of the composition.