Polymer film comprising a propylene random copolymer
View Patent ↗The present invention relates in a first embodiment to a polymer film comprising a propylene random copolymer with a total comonomer content of 4.5 to 12 mol % wherein the sealing initiation temperature SIT of the film is T m −30° C. or less, preferably T m −33° C. or less, in a second embodiment to a polymer film comprising a propylene random copolymer with a total comonomer content of 4.5 to 12 mol % wherein the film is having a relative reduction of the static friction value (inside-inside) from one to four days of 35% or more, preferably 40% or more, in a third embodiment to a polymer film comprising a propylene random copolymer with a total comonomer content of 4.5 to 12 mol % wherein the distribution of the comonomer in the random copolymer determined according to TREF method is multimodal, preferably bimodal, in a fourth embodiment to a polymer film comprising a propylene random copolymer with a total comonomer content of 4.5 to 12 mol %, wherein the copolymer is having an elution interval of 50° C. or more, and in a fifth embodiment to a polymer film comprising a copolymer with a total comonomer content of 4.5 to 12 mol % wherein the random copolymer is a unimodal polymer and the elution interval is determined by the equation Y≦ 4.5· m+ 16 wherein Y is the elution interval in ° C. and m is the percentage of ethylene in the copolymer in wt. %.
1. A polymer film comprising a propylene random copolymer which was produced according to a process comprising polymerisation of propylene with a comonomer, said comonomer being ethylene or an α-olefin comprising at least four carbon atoms, in the presence of a catalyst in a multistage process comprising polymerisation of propylene with a comonomer in a first reaction zone including at least one slurry reactor to give a first polymerisation product, transferring said first product to a second reaction zone including at least one gas phase reactor and polymerisation of propylene with a comonomer in said gas phase reactor in the presence of said first polymerisation product, wherein the temperature in the gas phase reactor is at least 10° higher than that in the slurry reactor, wherein the polymer has a multimodal comonomer distribution, wherein the content of xylene solubles in the polymer film is from 4 to 15 wt %, and wherein the film has a relative reduction of the static friction value (inside-inside) from one to four days of 35% or more, 40% or more.
2. A polymer film according to claim 1 , wherein the copolymer has an elution interval determined according to the TREF method using 1,2,4-trichlorobcnzene as an eluent of 50° C. or more.
3. A polymer film according to claim 1 , wherein the comonomer in the propylene random copolymer is ethylene.
4. A polymer film according to claim 1 , wherein the content of xylene solubles in the polymer film is from 6 to 10 wt %.
5. A polymer film comprising a propylene random copolymer which was produced according to a process comprising polymerisation of propylene with a comonomer, said comonomer being ethylene or an α-olefin comprising at least four carbon atoms, in the presence of a catalyst in a multistage process comprising polymerisation of propylene with a comonomer in a first reaction zone including at least one slurry reactor to give a first polymerisation product, transferring said first product to a second reaction zone including at least one gas phase reactor and polymerisation of propylene with a comonorner in said gas phase reactor in the presence of said first polymerisation product wherein the temperature in the gas phase reactor is at least 10° C. higher than that in the slurry reactor, wherein the shear thinning index (SHI) of the polymer after visbreaking is between 3 and 5, and wherein the film has a relative reduction of the static friction value (inside-inside) from one to four days of 35% or more, or 40% or more.
6. A polymer film comprising a propylene random copolymer which was produced according to a process comprising polymerisation of propylene with a comonomer, said comonomer being ethylene or an α-olefin comprising at least four carbon atoms, in the presence of a catalyst in a multistage process comprising polymerisation of propylene with a comonomer in a first reaction zone including at least one slurry reactor to give a first polymerisation product, transferring said first product to a second reaction zone including at least one gas phase reactor and polymerisation of propylene with a comonomer in said gas phase reactor in the presence of said first polymerisation product wherein the temperature in the gas phase reactor is at least 10° C. higher than that in the slurry reactor, wherein the molar mass distribution (Mw/Mn) is between 4 and 6, and wherein the film has a relative reduction of the static friction value (inside-inside) from one to four days of 35% or more, or 40% or more.