Binder resin solution composition, coatings, inks, adhesives and primers
View Patent ↗The present invention provides a binder resin solution composition, and a coating, ink, and adhesive containing the composition as an active ingredient, the binder resin solution composition having a solid content of 10 to 50 wt. % and comprising (a) a chlorinated polyolefin prepared by chlorinating an isotactic polypropylene polymer having a molecular weight distribution of no more than 3 and a melting point measured by a differential scanning calorimeter of 110 to 140° C. to a chlorine content of 10 to 40 wt. % and, (b) an organic solvent.
1. A binder resin solution composition having a solid content of 10 to 50 wt. % comprising (a) a chlorinated polyolefin prepared by chlorinating to a chlorine content of 10 to 40 wt. % an isotactic polypropylene polymer having a molecular weight distribution of no more than 3 and a melting point measured by a differential scanning calorimeter of 110 to 140° C. and (b) an organic solvent.
2. A binder resin solution composition having a solid content of 10 to 50 wt. % comprising (a) a carboxyl-containing chlorinated polyolefin prepared by chlorinating to a chlorine content of 10 to 40 wt. % an isotactic polypropylene polymer having a molecular weight distribution of no more than 3 and a melting point measured by a differential scanning calorimeter of 110 to 140° C. to produce a chlorinated polyolefin and graft-polymerizing with the chlorinated polyolefin 1 to 10 wt. % of at least one unsaturated carboxylic acid monomer selected from the group consisting of carboxylic acids and carboxylic acid anhydrides, and (b) an organic solvent.
3. A binder resin solution composition having a solid content of 10 to 50 wt. % comprising (a) a carboxyl-containing chlorinated polyolefin prepared by graft-polymerizing 1 to 10 wt. % of at least one unsaturated carboxylic acid monomer selected from the group consisting of carboxylic acids and carboxylic acid anhydrides with an isotactic polypropylene polymer having a molecular weight distribution of no more than 3 and a melting point measured by a differential scanning calorimeter of 110 to 140° C. to produce a carboxyl-containing polyolefin and chlorinating the carboxyl-containing polyolefin to a chlorine content of 10 to 40 wt. %, and (b) an organic solvent.
4. The binder resin solution composition according to claim 1 , wherein the isotactic polypropylene polymer is an isotactic propylene-α-olefin random copolymer.
5. The binder resin solution composition according to claim 2 , wherein the isotactic polypropylene polymer is an isotactic propylene-α-olefin random copolymer.
6. The binder resin solution composition according to claim 3 , wherein the isotactic polypropylene polymer is an isotactic propylene-α-olefin random copolymer.
7. The binder resin solution composition according to claim 1 , wherein the isotactic polypropylene polymer is an isotactic propylene-ethylene random copolymer.
8. The binder resin solution composition according to claim 2 , wherein the isotactic polypropylene polymer is an isotactic propylene-ethylene random copolymer.
9. The binder resin solution composition according to claim 3 , wherein the isotactic polypropylene polymer is an isotactic propylene-ethylene random copolymer.
10. The binder resin solution composition according to claim 1 , wherein the isotactic polypropylene polymer is an isotactic polypropylene.
11. The binder resin solution composition according to claim 2 , wherein the isotactic polypropylene polymer is an isotactic polypropylene.
12. The binder resin solution composition according to claim 3 , wherein the isotactic polypropylene polymer is an isotactic polypropylene.
13. The binder resin solution composition according to claim 1 , wherein the isotactic polypropylene polymer is produced in the presence of a metallocene catalyst.
14. The binder resin solution composition according to claim 2 , wherein the isotactic polypropylene polymer is produced in the presence of a metallocene catalyst.
15. The binder resin solution composition according to claim 3 , wherein the isotactic polypropylene polymer is produced in the presence of a metallocene catalyst.
16. A coating for a polyolefin film, sheet or molded article, the coating comprising as an active ingredient the binder resin solution composition according to claim 1 .
17. A coating for a polyolefin film, sheet or molded article, the coating comprising as an active ingredient the binder resin solution composition according to claim 2 .
18. A coating for a polyolefin film, sheet or molded article, the coating comprising as an active ingredient the binder resin solution composition according to claim 3 .
19. An ink for a polyolefin film, sheet or molded article, the ink comprising as an active ingredient the binder resin solution composition according to claim 1 .
20. An ink for a polyolefin film, sheet or molded article, the ink comprising as an active ingredient the binder resin solution composition according to claim 2 .
21. An ink for a polyolefin film, sheet or molded article, the ink comprising as an active ingredient the binder resin solution composition according to claim 3 .
22. An adhesive for a polyolefin film, sheet or molded article, the adhesive comprising as an active ingredient the binder resin solution composition according to claim 1 .
23. An adhesive for a polyolefin film, sheet or molded article, the adhesive comprising as an active ingredient the binder resin solution composition according to claim 2 .
24. An adhesive for a polyolefin film, sheet or molded article, the adhesive comprising as an active ingredient the binder resin solution composition according to claim 3 .
25. A primer for coating a polyolefin resin, the primer comprising as an active ingredient the binder resin solution composition according to claim 2 .
26. A primer for coating a polyolefin resin, the primer comprising as an active ingredient the binder resin solution composition according to claim 3 .