Process and device for manufacturing an aromatic alkylene polymer
View Patent ↗The present invention relates to a process and a device for the continuous manufacture of a polymer of an aromatic alkylene monomer e.g. styrene comprising a bulk polymerisation of the monomer and a devolatilization of the resulting polymer in at least two successive steps so as to separate the polymer from the unreacted monomer and the oligomers formed during the polymerisation. The process comprises conveying a first gas stream resulting from the first step of the devolatilization into a first zone Z 1 for direct condensation and fractionation, removing a gas stream G 1 comprising essentially the monomer from the top of Z 1 , and removing a liquid stream L 1 rich in oligomers from the bottom of Z 1 , a portion of L 1 being taken, cooled and then returned into Z 1 . It also comprises conveying a second gas stream resulting from the second step of the devolatilization into a second zone Z 2 for direct condensation and fractionation, this zone being also fed with the other portion of L 1 , removing a gas stream G 2 comprising the monomer from the top of Z 2 , and removing a liquid stream L 3 comprising essentially the oligomers from the bottom of Z 2 . The process and the device are particularly suitable for continuously manufacturing a styrene polymer, a styrene copolymer having a high impact strength modified by grafting onto a rubber, an expandable polystyrene or an expanded polystyrene. The invention is useful for improving the separation of the unreacted monomer from the oligomers and the quality of the polymer when the unreacted monomer thus separated is recycled e.g. to the polymerisation.
1. In a process for the continuous manufacture of an aromatic alkylene polymer in which an aromatic alkylene monomer is bulk polymerized to form a mass of polymer which is then subjected to a devolatilization process in at least two successive steps to separate polymer from unreacted monomer and oligomers formed at least partially during the polymerization, the improvement comprising:
separating a first gas stream from the polymer in a first step of the devolatilization process, conveying the separated first gas stream to a first zone Z 1 for direct condensation and fractionation, removing a gas stream G 1 comprising essentially monomer from a top zone of Z 1 , while removing a liquid stream L 1 rich in oligomers from a bottom of zone Z 1 , cooling a portion of the liquid stream L 1 and then returning the cooled portion to zone Z 1 so as to partially condense by direct contact the first gas stream in zone Z 1 , and
separating a second gas stream from the polymer in a second step of the devolatilization process, conveying the separated second gas stream to a second zone Z 2 for direct condensation and fractionation, feeding another portion of the liquid stream L 1 from zone Z 1 to zone Z 2 so as to partially condense by direct contact the second gas stream in zone Z 2 , and removing a gas stream G 2 comprising monomer from a top of zone Z 2 , while removing a liquid stream L 3 comprising oligomers from a bottom of zone Z 2 .
2. The process of claim 1 , wherein at least a portion of the gas stream G 1 removed from the top of zone Z 1 is recovered and is then recycled directly or indirectly into the polymerization of the aromatic alkylene monomer.
3. The process of claim 2 , wherein the recovered portion of the gas stream G 1 is condensed and optionally cooled and is recycled in the form of a liquid stream.
4. The process of claim 1 or 2 , wherein at least another portion of the gas stream G 1 removed from the top of zone Z 1 is recovered and returned, after condensation and optionally cooling, in the form of a liquid stream into zone Z 1 .
5. The process of claim 4 , wherein the recovered another portion of the gas stream G 1 is returned into a top part of zone Z 1 .
6. The process of claim 5 , wherein the recovered another portion of the gas stream G 1 is returned into the top of zone Z 1 .
7. The process of claim 1 or 2 , wherein a point of return of the cooled portion of the liquid stream L 1 is at a point in zone Z 1 such that it delimits in zone Z 1 a top part for fractionation of the oligomers, and a bottom part for direct condensation.
8. The process of claim 1 or 2 , wherein a point of return of the cooled portion of the liquid stream L 1 is located in a central part of zone Z 1 .
9. The process of claim 1 , wherein the first gas stream separated in the first step of the devolatilization process is conveyed into a part of zone Z 1 which is below a point of return of the cooled portion of the liquid stream L 1 into zone Z 1 .
10. The process of claim 9 , wherein the cooled portion of the liquid stream L 1 is returned to a bottom part of zone Z 1 .
11. The process of claim 10 , wherein the cooled portion of the liquid stream L 1 is returned to the bottom of zone Z 1 .
12. The process of claim 1 , wherein the another portion of the liquid stream L 1 is fed to zone Z 2 at a point in zone Z 2 which is above a point at which the second gas stream separated in the second step of the devolatilization process is conveyed into zone Z 2 .
13. The process of claim 1 , wherein the second gas stream separated in the second step of the devolatilization process is conveyed into a bottom part of zone Z 2 .
14. The process of claim 13 , wherein the second gas stream is conveyed into the bottom of zone Z 2 .
15. The process of claim 1 , wherein a point at which zone Z 2 is fed with the another portion of the liquid stream L 1 is at a point in zone Z 2 such that it delimits in zone Z 2 a top part for fractionation of the oligomers, and a bottom part for direct condensation.
16. The process of claim 1 , wherein the gas stream G 2 removed from the top of zone Z 2 is condensed and optionally cooled so as to form a liquid stream L 2 .
17. The process of claim 16 , wherein the liquid stream L 2 is at least partly conveyed directly or indirectly into zone Z 1 .
18. The process of claim 17 , wherein said part of the liquid stream L 2 is conveyed into a top part of zone Z 1 .
19. The process of claim 18 , wherein said part of the liquid stream L 2 is conveyed into a top of zone Z 1 .
20. The process of claim 16 or 17 , wherein a portion of the liquid stream L 2 is returned into zone Z 2 .
21. The process of claim 20 , wherein said portion of the liquid stream L 2 is returned into a top part of zone Z 2 .
22. The process of claim 21 , wherein said portion of the liquid stream L 2 is returned to the top of zone Z 2 .
23. The process of claim 1 , wherein the gas stream G 2 removed from the top of Z 2 is condensed and optionally cooled so as to form a liquid stream L 2 and is then fractionated by phase separation or by decantation, so as to isolate a purified liquid stream essentially containing the monomer.
24. The process of claim 1 , including adding a stripping agent for facilitating the devolatilization to the mass of polymer between the two successive steps of the devolatilization process.
25. The process of claim 24 , wherein the stripping agent is water or carbon dioxide.
26. The process of claim 1 , including adding superheated steam to the mass of polymer during the second step of the devolatilization process, or to the second gas stream separated in the second step of the devolatilization process, before or after it has been introduced into zone Z 2 .