IP Library Granted Patent US 7,026,425
Granted Patent B2
US 7,026,425 · App. 10/485,668 · Granted Apr 11, 2006

Moisture crosslinking elastomer composition

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 7,026,425
App. No.
10/485,668
Granted
Apr 11, 2006
Kind
B2
Abstract

The invention relates to moisture cross-linking compositions containing (A) 100 parts per weight of a silane-terminated polydiorganosiloxane-urea/urethane copolymer of general formula (1), and (B) between 0.1 and 20 parts per weight of silane of general formula (3): Ω-(CH 2 ) e —Si(R 2 ) 3-f (CH 3 ) f , in which R, X, A, Y, D, B, W, n, a, b, c, d, Ω, R 2 , e and f are defined as per claim 1.

Claims (36)

1. A moisture-crosslinkable composition comprising

(A) 100 parts by weight of at least one silane-terminated polydiorganosiloxane-urea/urethane copolymer of the general formula 1

 in which

R is a monovalent C 1-20 hydrocarbon radical optionally substituted by fluoro or chloro,

X is a C 1-20 alkylene radical in which nonadjacent methylene units are optionally replaced by —O—,

A is an oxygen atom or an amino group —NR′—,

R′ is hydrogen or a C 1-10 alkyl radical,

Y is a C 1-20 hydrocarbon radical optionally substituted by fluoro or chloro,

D is a C 1-700 alkylene radical in which nonadjacent methylene units are optionally replaced by —O—, —COO—, —OCO—, or —OCOO— groups, said alkylene radical optionally substituted by fluoro, chloro, C 1 –C 6 alkyl or C 1 –C 6 alkyl ester,

B is a radical of the formula 2

-Z-Si(R 1 ) m (R″) 3-m   (2)

Z is a methylene radical,

R 1 is a monovalent C 1-12 hydrocarbon radical optionally substituted by fluoro or chloro,

R″ is a moisture-reactive radical selected from the group consisting of C 1 –C 4 alkoxy, C 1 –C 20 acyl, C 1 –C 6 alkylaminooxy, C 1 –C 6 alkyloximo, and mixtures thereof,

W is a radical B or hydrogen,

m is 0, 1 or 2,

n is an integer from 1 to 300,

a is an integer which is at least 1,

b is 0 or an integer from 1 to 30,

c is an integer from 1 to 30, and

d is 0 or 1, with the proviso that the composition of the units is chosen such that the copolymer possesses a melting point in the range of 30° C. to 200° C., and

(B) from 0.1 to 20 parts by weight of at least one silane of the formula 3

Ω-(CH 2 ) e —Si(R 2 ) 3-f (CH 3 ) f   (3)

where

Ω is a moiety selected from the group consisting of —NHR 3 , —NR 3 —(CH 2 ) g —NHR 3 , acryloyl, methacryloyl, OCN, —SH, glycidyloxy, and chloro,

R 3 is hydrogen or an optionally halogen-substituted C 1-18 hydrocarbon radical,

R 2 independently are methoxy or ethoxy group,

e is 1 or 3,

f is 0 or 1, and

g is from 1 to 10.

2. The moisture-crosslinkable composition of claim 1 , wherein polydiorganosiloxane blocks in copolymer (A) have a molecular weight Mw of from 500 to 30,000.

3. The moisture-crosslinkable composition of claim 1 , wherein R are methyl, phenyl, or some R are methyl and some R are phenyl.

4. The moisture-crosslinkable composition of claim 1 , wherein A is an amino group.

5. The moisture-crosslinkable composition of claim 1 , wherein R″ is a methoxy or ethoxy radical, or wherein some R″ are methoxy and some R″ are ethoxy.

6. The moisture-crosslinkable composition of claim 1 , wherein at least one Ω is a moiety selected from the group consisting of —NHR 3 , —NR 3 —(CH 2 ) g —NHR 3 , and glycidyloxy.

7. A one-component hotmelt adhesive which is moisture-crosslinking by way of silane end groups, comprising at least one moisture-crosslinkable composition of claim 1 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 21, 2007
From: CONSORTIUM FUR ELEKTROCHEMISCHE INDUSTRIES GMBH
To: WACKER CHEMIE AG
Reel/Frame 019725/0609 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 3, 2004
From: SCHINDLER, WOLFRAM; SCHAFER, OLIVER; CHATZINERANTZIS, MARTINA; PACHALY, BERND
To: CONSORTIUM FUR ELEKTROCHEMISCHE INDUSTRIE GMBH
Reel/Frame 015696/0376 →