Nickel electrode material, and production method therefor, and nickel electrode and alkaline battery
View Patent ↗For accomplishing the subjects, the invention provides a nickel electrode material for use in a nickel electrode, wherein the positive-electrode material constituting the electrode material comprises: positive active material particles which comprise as the main component either a nickel hydroxide or a solid solution in a nickel hydroxide of one or more other elements and in which part of the nickel hydroxide has been oxidized; and a coating layer formed on the surface of the positive active material particles and comprising as the main component a high-order cobalt compound in which the cobalt has an oxidation number larger than 2, the average oxidation number of the nickel in the positive active material particles and the cobalt in the coating layer being from 2.04 to 2.40, and the positive-electrode material having a tap density of 2.0 g/cm 3 or higher. The invention further provides a process for producing the electrode material, a nickel electrode employing the electrode material, and an alkaline storage battery having the nickel electrode.
1. A nickel electrode material for use in a nickel electrode, comprising:
a positive-electrode material comprising:
positive active material particles which comprise as the main component at least one member selected from a group consisting of a nickel hydroxide, and a solid solution in a nickel hydroxide of one or more other elements and in which part of the nickel hydroxide has been oxidized; and
a coating layer formed on a surface of the positive active material particles and comprising as a main component a high-order cobalt compound in which cobalt has an oxidation number greater than 2,
wherein an average oxidation number of nickel in the positive active material particles and the cobalt in the coating layer is from 2.04 to 2.40,
wherein the positive-electrode material has a tap density of 2.0 g/cm 3 or greater, and
wherein the high-order cobalt compound is capable of being electrochemically oxidized and reduced, has an electric double-layer capacity, and has a peak for a (003) plane with a half width of 0.7 degrees or greater in an X-ray diffraction pattern.
2. The nickel electrode material of claim 1 , wherein the proportion of the coating layer in the positive-electrode material is from 3 to 10% by weight.
3. The nickel electrode material of claim 1 , wherein the nickel hydroxide in the positive active material particles is one in which, in an X-ray diffraction pattern, the peak intensity ratio between a (100) plane and (001) plane, (100)/(001), and the peak intensity ratio between a (101) plane and (001) plane, (101)/(001), each are 0.5 or greater and the half width of the peak for the (101) plane is greater than 0.8 degrees and not greater than 1.2 degrees.
4. The nickel electrode material of claim 1 , wherein the high-order cobalt compound has a specific surface area of 4 m 2 /g or greater in terms of BET area.
5. The nickel electrode material of claim 1 , wherein the positive-electrode material comprises:
positive active material particles comprising a solid solution in a nickel hydroxide of both cobalt and zinc; and
a coating layer formed on the surface of the active material particles and comprising as the main component a high-order cobalt compound in which the cobalt has an oxidation number greater than 2,
wherein the average oxidation number of the nickel in the positive active material particles and the cobalt in the coating layer is from 2.04 to 2.40, and
wherein the amounts of the cobalt and zinc in said solid solution in the positive active material are from 0.5 to 4% by weight and from 1 to 5% by weight, respectively, in terms of the proportion of the metal, and the proportion of all cobalt in the positive-electrode material, including the cobalt in solution in the positive active material and the cobalt in the coating layer, is from 3 to 10% by weight in terms of the proportion of the metal.
6. The nickel electrode material of claim 1 , wherein the positive active material particles comprise a compound containing one or more rare earth elements, and
wherein the compound containing one or more rare earth elements comprises an oxide or hydroxide including at least one of Yb, Er, Lu, Tm, and Y.
7. The nickel electrode material of claim 6 , wherein the positive-electrode material has, disposed on the surface thereof, said compound containing one or more rare earth elements.
8. A nickel electrode comprising:
a porous substrate impregnated with the nickel electrode material of claim 1 .
9. An alkaline storage battery having a nickel electrode, said nickel electrode comprising:
a positive-electrode material comprising:
positive active material particles which comprise as the main component at least one member selected from a group consisting of a nickel hydroxide, and a solid solution in a nickel hydroxide of one or more other elements and in which part of the nickel hydroxide has been oxidized; and
a coating layer formed on a surface of the positive active material particles and comprising as a main component a high-order cobalt compound in which cobalt has an oxidation number greater than 2,
wherein an average oxidation number of nickel in the positive active material particles and the cobalt in the coating layer is from 2.04 to 2.40,
wherein the positive-electrode material has a tap density of 2.0 g/cm 3 or greater, and
wherein the high-order cobalt compound is capable of being electrochemically oxidized and reduced, has an electric double-layer capacity, and has a peak for a (003) plane with a half width of 0.7 degrees or greater in an X-ray diffraction pattern.
10. A nickel electrode comprising:
a porous substrate impregnated with the nickel electrode material of claim 2 .
11. A nickel electrode comprising:
a porous substrate impregnated with the nickel electrode material of claim 3 .
12. A nickel electrode comprising:
a porous substrate impregnated with the nickel electrode material of claim 4 .
13. A nickel electrode comprising:
a porous substrate impregnated with the nickel electrode material of claim 5 .
14. A nickel electrode comprising:
a porous substrate impregnated with the nickel electrode material of claim 6 .
15. A nickel electrode comprising:
a porous substrate impregnated with the nickel electrode material of claim 7 .
16. The alkaline storage battery of claim 9 , wherein the proportion of the coating layer in the positive-electrode material is from 3 to 10% by weight.
17. The alkaline storage battery of claim 9 , wherein the nickel hydroxide in the positive active material particles comprises one in which, in an X-ray diffraction pattern, the peak intensity ratio between a (100) plane and (001) plane, (100)/(001), and the peak intensity ratio between a (101) plane and (001) plane, (101)/(001), each are 0.5 or greater and the half width of the peak for the (101) plane is greater than 0.8 degrees and not greater than 1.2 degrees.
18. The alkaline storage battery of claim 9 , wherein the high-order cobalt compound comprises a specific surface area of 4 m 2 /g or greater in terms of BET area.
19. The alkaline storage battery of claim 9 , wherein the positive-electrode material comprises:
positive active material particles comprising a solid solution in a nickel hydroxide of both cobalt and zinc; and
a coating layer formed on the surface of the active material particles and comprising as the main component a high-order cobalt compound in which the cobalt has an oxidation number greater than 2,
wherein the average oxidation number of the nickel in the positive active material particles and the cobalt in the coating layer is from 2.04 to 2.40, and
wherein the amounts of the cobalt and zinc contained in solid solution in the positive active material are from 0.5 to 4% by weight and from 1 to 5% by weight, respectively, in terms of the proportion of the metal, and the proportion of all cobalt in the positive-electrode material, including the cobalt contained in solution in the positive active material and the cobalt contained in the coating layer, is from 3 to 10% by weight in terms of the proportion of the metal.
20. The alkaline storage battery of claim 9 , wherein the positive active material particles comprise a compound containing one or more rare earth elements, and
wherein the compound containing one or more rare earth elements comprises an oxide or hydroxide including at least one of Yb, Er, Lu, Tm, and Y.
21. The alkaline storage battery of claim 20 , wherein the positive-electrode material has, disposed on the surface thereof, said compound containing one or more rare earth elements.
22. The nickel electrode material of claim 6 , wherein a proportion of the compound containing one or more rare earth elements in the nickel electrode material is in a range from 0.1% to 20% by weight.
23. The nickel electrode material of claim 1 , wherein the nickel hydroxide in the positive active material particles is one in which, in an X-ray diffraction pattern, the peak intensity ratio between a (100) plane and (001) plane, (100)/(001), and the peak intensity ratio between a (101) plane and (001) plane, (101)/(001), each are 0.5 or greater and the half width of the peak for the (101) plane is greater than 0.9 degrees and not greater than 1.2 degrees.