Multifunctional viscosity index improver and dispersant
View Patent ↗A process is disclosed that comprises solution grafting a hydrocarbon polymer prepared from at least C 2 to C 28 polymerizable hydrocarbon, said polymer having a number average molecular weight in the range of from about 5,000 to about 500,000, with an ethylenically unsaturated C 3 to C 10 carboxylic acid material, using a free radical initiator, in the presence of an aromatic ester oil of the formula (I) wherein R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are independently selected from the group consisting of hydrogen, —COOR 7 , —COOR 8 , —COOR 9 , —COOR 10 , —COOR 11 , and —COOR 12 , provided that no more than 5 of R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are hydrogen, and R 7 , R 8 , R 9 , R 10 , R 11 , and R 12 are independently selected from the group consisting of alkyl and alkylesters
1. A process comprising:
(A) dissolving a hydrocarbon polymer in one or more solvents selected from the group consisting of aromatic ester oils of the formula
wherein R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are independently selected from the group consisting of hydrogen, —COOR 7 , —COOR 8 , —COOR 9 , —COOR 10 , —COOR 11 , and —COOR 12 , provided that no more than 5 of R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are hydrogen, and R 7 , R 8 , R 9 , R 10 , R 11 , and R 12 are independently selected from the group consisting of alkyl and alkylesters to form a solution of said hydrocarbon polymer in said solvent(s); and
(B) adding an ethylenically unsaturated C 3 to C 10 carboxylic acid material and a free radical initiator to said solution over about 0.1 to about 12 hours at a temperature of from about 25° C. to about 250° C., whereby said ethylenically unsaturated C 3 to C 10 carboxylic acid material is grafted onto said hydrocarbon polymer;
wherein said hydrocarbon polymer has previously been prepared from at least one C 2 to C 28 polymerizable hydrocarbon and has a number average molecular weight in the range of from about 5,000 to about 500,000.
2. The process of claim 1 , wherein the hydrocarbon polymer is a copolymer of ethylene with a C 3 to C 28 alpha olefin.
3. The process of claim 2 wherein the copolymer comprises from about 15 to about 90 weight percent ethylene and, correspondingly, from about 85 to about 10 weight percent of the alpha olefin.
4. The process of claim 2 wherein the C 3 to C 28 alpha olefin is propylene.
5. The process of claim 3 wherein the C 3 to C 28 alpha olefin is propylene.
6. The process of claim 1 wherein about 5 to 95 % of the copolymer is dissolved in 95 to 5 wt. % of the aromatic ester to form the solution, the amount of the unsaturated material is about 0.05 to 10 wt. % based upon the weight of the solution, and the amount of the initiator is about 0.005 to 10 wt. % based on the weight of the solution.
7. The process of claim 6 further comprising, after the grafting step, the steps of adding about 40 to 500 wt. %, based upon the weight of the solution, of mineral or synthetic lubricating oil and then adding an amine sufficient to neutralize the acid and heating at 100° C. to 250° C. for 0.5 to 10 hours.
8. The process of claim 7 , wherein the unsaturated material is maleic anhydride and the amine is N-(4-anilinophenyl)-3-aminobutanamide.
9. The process of claim 6 , wherein the unsaturated material is a nitrogen-containing ethylenically unsaturated monomer.
10. The process of claim 9 , wherein the nitrogen-containing monomer is selected from the group consisting of vinyl pyridines, vinyl pyrrolidones, vinyl imidazoles, and amine group-containing acrylates and methacrylates.