Electric separator, method for producing the same and the use thereof
View Patent ↗A separator based on a sheetlike flexible substrate having a multiplicity of openings and having a coating on and in the substrate, the material of the substrate being selected from woven or non-woven electrically nonconductive fibers of glass or ceramic or a combination thereof and the coating being a porous electrically insulating ceramic coating, characterized by a thickness of less than 100 μm; a process for producing the separator; and a battery comprising the separator.
1. A separator comprising
a flexible substrate in sheet form
having a multiplicity of openings and
having a coating on and in said substrate,
the material of said substrate being woven electrically nonconductive fibers of glass and said coating being a porous electrically insulating ceramic coating, wherein the substrate is a woven glass fiber fabric comprising woven fibers or filaments which has been produced from 2 to 20 tex yarns and has from 5 to 30 weft threads/cm and from 5 to 30 warp threads/cm, and the separator has a thickness of less than 100 μm.
2. The separator of claim 1 , wherein the separator has a thickness of less than 50 μm.
3. The separator of claim 1 , wherein said fibers or filaments are at least one glass selected from the group consisting of E-, R- and S-glass.
4. The separator of claim 3 , wherein said filaments are coated with SiO 2 , ZrO 2 , Al 2 O 3 or mixtures thereof.
5. The separator of claim 3 , wherein said woven glass fiber fabric was produced from 5.5 or 11 tex yarns.
6. The separator of claim 1 , wherein said coating on and in said substrate comprises an oxide, nitride or carbide of the metals Al, Zr, Si, Sn, Ce, Mg, Hf, B and/or Y.
7. The separator of claim 1 , wherein the separator has a breaking strength of 5 N/cm to 500 N/cm.
8. The separator of claim 1 , wherein the separator is bendable around a radius down to 100 mm without damage.
9. A battery, which comprises the separator as claimed in claim 1 .
10. A process for producing a separator as claimed in claim 1 , the process comprising
providing a flexible substrate in sheet form having a multiplicity of openings with a coating on and in said substrate,
the material of said substrate being a woven fabric comprising woven glass fibers which has been produced from threads having a linear density of not more than 20 tex and has from 5 to 30 weft threads/cm and from 5 to 30 warp threads/cm and
said coating being a porous electrically insulating ceramic coating.
11. The process of claim 10 , wherein said coating is provided by applying to said substrate a suspension comprising at least one inorganic component comprising a compound of at least one metal, one semimetal or one mixed metal with at least one element of the 3 rd to 7 th main group and a sol and heating one or more times to solidify said suspension comprising at least one inorganic component on or in or else on and in the support.
12. The process of claim 11 , wherein said suspension is brought onto and into said substrate by printing on, pressing on, pressing in, rolling on, knifecoating on, spreadcoating on, dipping, spraying or pouring on.
13. The process of claim 10 , wherein said suspension, which comprises at least one inorganic component and at least one sol, at least one semimetal oxide sol or at least one mixed metal oxide sol or a mixture thereof, is prepared by suspending at least one inorganic component in at least one of these sols.
14. The process of claim 13 , wherein said sols are obtained by hydrolyzing at least one metal compound, at least one semimetal compound or at least one mixed metal compound using water, water vapor, ice, alcohol or an acid or a combination thereof.
15. The process of claim 14 , wherein said metal compound hydrolyzed is at least one metal alkoxide compound or at least one semimetal alkoxide compound selected from the alkoxide compounds of the elements Zr, Al, Si, Sn, Ce and Y or at least one metal nitrate, metal carbonate or metal halide selected from the metal salts of the elements Zr, Al, Si, Sn, Ce and Y.
16. The process of claim 13 , wherein the mass fraction of said suspended component is 0.1 to 500 times that of the sol used.
17. The process of claim 10 , wherein said inorganic component suspended is at least one oxide selected from the oxides of the elements Sc, Y, Zr, V, Cr, Nb, Mo, W, Mn, Fe, Ce, Co, B, Al, In, Ti, Si, Ge, Sn, Pb and Bi.
18. The process of claim 10 , wherein said suspension on and in said substrate is solidified by heating to 50to 1000° C.
19. The process of claim 18 , wherein said heating is carried out at 50 to 100° C. for 10 min to 5 hours.
20. The process of claim 19 , wherein said heating is carried out at 100 to 800° C. for 1 second to 10 minutes.