Process for the preparation of urea
View Patent ↗The invention relates to a process for the preparation of urea from ammonia and carbon dioxide, which preparation takes places wholy or partly with the application of a synthesis reactor, a condenser, a scrubber and a stripper, wherein an outlet of the stripper, through which a gas stream is discharged during operation, is functionally connected to the inlet of the condenser and to the inlet of the reactor and wherein an outlet of the condenser is functionally connected to an inlet of the scrubber and wherein the obtained reaction mixture is stripped in the stripper in countercurrent with one of the starting materials, wherein the gas stream coming from the top of the submerged condenser is subjected to an extra washing step before this gas stream is supplied to the high-pressure scrubber. The submerged condenser operating as such may be for example a submerged condenser of horizontal or vertical design of a falling-film high-pressure carbamate condenser transformed into a submerged condenser. The invention further relates to a process for improving and/or optimizing a urea plant as well as to a urea plant as such.
1. Process for the preparation of urea from ammonia and carbon dioxide, which preparation takes places wholly or partly with the application of a synthesis reactor, a condenser, a scrubber and a stripper, wherein an outlet of the stripper, through which a gas stream is discharged during operation, is functionally connected to the inlet of the condenser and to the inlet of the reactor and wherein an outlet of the condenser is functionally connected to an inlet of the scrubber and wherein the obtained reaction mixture is stripped in the stripper in countercurrent with one of the starting materials, characterized in that the gas stream coming from the top of the submerged condenser is subjected to an extra washing step before it is supplied to the scrubber.
2. Process according to claim 1 , wherein, the submerged condenser operating as such is a submerged condenser or a falling-film condenser transformed into a submerged condenser.
3. Process according to claim 1 , wherein the wash fluid used in the extra washing step is fresh ammonia.
4. Process according to claim 1 , wherein the wash fluid used in the extra washing step is the carbamate solution flowing from the high-pressure scrubber to the condenser.
5. Process according to claim 1 , wherein the gas stream is subjected to an extra washing step with both fresh ammonia and the carbamate solution.
6. Process according to claim 5 , wherein the gas stream is washed first with the carbamate solution and then with fresh ammonia.
7. Process for improving and/or optimising a urea plant, which plant essentially comprises a synthesis reactor, a condenser, a scrubber and a stripper, wherein an outlet of the stripper, through which a gas mixture is discharged during operation, is functionally connected to an inlet of the condenser and with the inlet of the reactor, and wherein an outlet of the condenser is functionally connected to an inlet of the scrubber and wherein the obtained reaction mixture is stripped in the stripper in countercurrent with one of the starting materials, characterized in that the gas stream coming from the top of the submerged condenser is subjected to an extra washing step before this gas stream is supplied to the scrubber.
8. Process according to claim 7 , wherein the submerged condenser operating as such is a submerged condenser, of horizontal or vertical design, or a falling-film high-pressure carbamate condenser transformed into a submerged condenser.
9. Urea plant comprising a high-pressure section essentially consisting of a synthesis reactor, a submerged condenser operating as such, a first scrubber and a stripper, wherein an outlet of the condenser is functionally connected to an inlet of the first scrubber, characterized in that a second scrubber is positioned between the said outlet of the condenser and the said inlet of the first scrubber, wherein an extra washing step of the gas stream coming from the condenser is performed.
10. Urea plant according to claim 9 , wherein the submerged condenser operating as such is a submerged condenser, of horizontal or vertical design, or a falling-film high-pressure carbamate condenser transformed into a submerged condenser.