Glass fibre with at least two glass layers
View Patent ↗The glass fiber for an optical amplifier has a matrix glass core, a first glass cladding, and a second glass cladding. The matrix glass core has a composition, in mol %, of Bi 2 O 3 , 30-60; SiO 2 , 0.5-40; B 2 O 3 , 0.5-40; Al 2 O 3 , 0-30; Ga 2 O 3 , 0-20; Ge 2 O 3 , 0-25 ; La 2 O 3 , 0-15; Nb 2 O 5 , 0-10; SnO 2 , 0-30; alkali metal oxides, 0-40; and Er 2 O 3 , 0.05-8. The glass claddings have the same composition as the core, except that a transition metal compound is included as an absorbent. The refraction index of the matrix glass is > about 1.85, the refraction index of the first glass cladding is less than that of the core, and the refraction index of the second glass cladding is higher than that of the first.
1. A glass fiber, comprising a core and at least two glass claddings surrounding said core, in which said core comprises a matrix glass, the matrix glass contains at least one heavy metal oxide and at least one rare earth compound, the matrix glass has a refractive index of greater than about 1.85, a refractive index change Δn from a first of the at least two glass claddings to the core is in a range from 0.001 to 0.08, the refractive index of the first glass cladding is lower than that of the core, the first glass cladding contains said at least one rare earth compound, and an outermost cladding of the at least two glass claddings contains from 5 to 5000 ppm of at least one absorbent component;
in which said at least one absorbent component is at least one transition metal compound;
in which the at least one heavy metal oxide is at least one oxide of Bi, Te, Se, Sb, Pb, Cd, Ga andlor As, or a mixture thereof; and
in which said matrix glass contains an amount of each of said at least one rare earth compound equal to 0.05 to 5 mol %, but the first glass cladding contains only up to one half of said amount of each of said at least one rare earth compound in said matrix glass.
2. The glass fiber as claimed in claim 1 ,in which the core comprises at least Bi 2 O 3 and/or TeO 2 and/or Sb 2 O 3 .
3. The glass fiber as claimed in claim 1 , wherein the at least one rare earth compound contains at least one element selected from the group consisting of Ge, La, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, or a mixture thereof.
4. The glass fiber as claimed in claim 1 , in which the refractive index n m2 of a second of the at least two glass claddings is higher than the refractive index n m1 of the first cladding.
5. The glass fiber as claimed in claim 1 , in which the refractive index n m2 of a second of the at least two glass claddings is lower than the refractive index n m1 of the first cladding.
6. The glass fiber as claimed in claim 1 , in which the core is surrounded by two or three glass claddings.
7. The glass fiber as claimed in claim 1 , in which the core has a diameter of from 1 to 15 μm.
8. The glass fiber as claimed in claim 1 , in which the first cladding has a thickness d m1 in a range from 5 to 100 μm.
9. The glass fiber as claimed in claim 4 , in which the second cladding and/or a further cladding has a thickness (d m2 ) in a range from 10 to 300 μm.
10. The glass fiber as claimed in claim 1 , having a total thickness of 125 μm.
11. An optical amplifier comprising at least one glass fiber as claimed in claim 1 .
12. A laser component comprising a glass fiber as claimed in claim 1 .
13. The glass fiber as defined in claim 1 , in which said at least one rare earth compound is Er 2 O 3 .
14. The glass fiber as defined in claim 1 , in which said at least one absorbent compound contain Co +2 ions.
15. The glass fiber as defined in claim 1 , wherein said matrix glass consists of, in mol % on an oxide basis, Bi 2 O 3 , 30-60; SiO 2 , 0.5 -40; B 2 O 3 , 0.5-40; Al 2 O 3 , 0-30; Ga 2 O 3 , 0-20; GeO 2 , 0-25; La 2 O 3 , 0-15; Nb 2 O 5 , 0-10; SnO 2 , 0-30; M 1 2 O, 0-40; and said at least one rare earth compound, 0.05-8, wherein M 1 is Li, Na, K, Rb, and/or Cs.