Composite thin film holding substrate, transparent conductive film holding substrate, and panel light emitting body
View Patent ↗There is provided a composite thin film-holding substrate in which a composite thin film ( 4 ) comprising a filler ( 2 ) having a refractive index lower than that of a substrate ( 1 ) and a binder ( 3 ) having a refractive index higher than that of the filler ( 2 ) is formed on a surface of the substrate ( 1 ). Light is efficiently scattered when passing through the composite thin film ( 3 ) which comprises the filler ( 2 ) and the binder ( 3 ) having different refractive indexes from each other. In addition, the refractive index of a composite thin film ( 4 ) comprising a filler ( 2 ) having a low refractive index is low. As a result, the discharge efficiency of light which passes through the composite thin film ( 4 ) from the substrate ( 1 ) to the external is improved.
1. A composite thin film-holding substrate which comprises a substrate and a composite thin film disposed on a surface of the substrate, wherein
the composite thin film comprises a filler and a binder, and wherein
a refractive index of the filler (Nf) is lower than a refractive index of the binder (Nb) and lower than a refractive index of the substrate (Ns).
2. The composite thin film holding-substrate according to claim 1 , wherein the filler is selected from aerogel fine particles, silica fine and hollow particles, and polymer fine and hollow particles, and the binder is selected from organic polymers and metal oxides.
3. The composite thin film-holding substrate according to claim 2 , wherein the refractive index of the composite thin film is not higher than 1.4.
4. The composite thin film-holding substrate according to claim 3 , wherein the refractive index of the filler is not higher than 1.3.
5. A transparent and electrically conductive film-holding substrate comprising a transparent and electrically conductive film, wherein the transparent and electrically conductive film is formed on the composite thin film of the composite thin film-holding substrate according to claim 1 .
6. The transparent conductive film-holding substrate according to claim 5 , wherein the transparent and electrically conductive film is formed on a smoothening backing layer which is formed on the composite thin film.
7. A surface light emitting device, wherein a light emitting layer and a metal electrode are stacked in this order on the transparent and electrically conductive film of the transparent conductive film-holding substrate according to claim 5 , and the transparent and electrically conductive film, the light emitting layer and the metal electrode form an electroluminescent element.
8. A composite thin film-holding substrate which comprises a substrate and a composite thin film disposed on a surface of the substrate, wherein
the composite thin film comprises a filler and a binder, and wherein
a refractive index of the binder (Nb) is lower than a refractive index of the filler (Nf) and lower than a refractive index of the substrate (Ns).
9. The composite thin film-holding substrate according to claim 8 , wherein the binder comprises a silica porous material, and the filler is selected from organic polymer fine particles, metal compound fine particles, and silica fine and hollow particles.
10. The composite thin film-holding substrate according to claim 9 , wherein the refractive index of the composite thin film is not higher than 1.4.
11. The composite thin film-holding substrate according to claim 10 , wherein the refractive index of the binder is not higher than 1.5.
12. The composite thin film-holding substrate according to claim 9 , wherein the composite thin film is formed by applying, to the substrate, a coating material composition which comprises silica fine and hollow particles and SILICONE RESIN-M, and drying the resulting applied film.
13. The composite thin film-holding substrate according to claim 12 , wherein an average particle diameter of the fine and hollow silica particles is from 5 nm to 2 μm.
14. A transparent and electrically conductive film-holding substrate comprising a transparent and electrically conductive film, wherein the transparent and electrically conductive film is formed on the composite thin film of the composite thin film-holding substrate according to claim 8 .
15. The transparent conductive film holding substrate according to claim 14 , wherein the transparent and electrically conductive film is formed on a smoothening backing layer which is formed on the composite thin film.
16. A surface light emitting device, wherein a light emitting layer and a metal electrode are stacked in this order on the transparent and electrically conductive film of the transparent and electrically conductive film-holding substrate according to claim 14 , and the transparent and electrically conductive film, the light emitting layer and the metal electrode form an electroluminescent element.
17. A transparent and electrically conductive film-holding substrate comprising:
a composite thin film-holding substrate which comprises a substrate and a composite thin film disposed on a surface of the substrate,
the composite thin film comprises a filler and a binder,
both of a refractive index of the filler (Nf) and a refractive index of the binder (Nb) are higher than a refractive index of the substrate (Ns), and
a transparent and electrically conductive film formed on the composite thin film.
18. The transparent conductive film holding substrate according to claim 17 , wherein the transparent and electrically conductive film is formed on a smoothening backing layer which is formed on the composite thin film.
19. A surface light emitting device, wherein a light emitting layer and a metal electrode are stacked in this order on the transparent and electrically conductive film of the transparent and electrically conductive film-holding substrate according to claim 17 , and the transparent and electrically conductive film, the light emitting layer and the metal electrode form an electroluminescent element.
20. The transparent and electrically conductive film-holding substrate according to claim 17 , wherein the filler is selected from organic polymer fine particles and metal oxide fine particles, and the binder is selected from organic polymers and metal oxides.
21. The transparent and electrically conductive film-holding substrate according to claim 20 , wherein the refractive index of the binder is not higher than 1.8.
22. A surface light emitting device comprising a thin film of a fluorescent material, wherein the thin film of the fluorescent material is formed on a composite thin film of a composite thin film-holding substrate, the composite thin film-holding substrate comprising a substrate and a composite thin film disposed on a surface of the substrate, wherein the composite thin film comprises a filler and a binder, the filler is selected from the group consisting of fine aerogel fine particles, silica fine and hollow particles, and polymer fine and hollow particles, and the binder is selected from the group consisting of organic polymers and metal oxides, and wherein a refractive index of the filler (Nf) is lower than a refractive index of the binder (Nb) lower than a refractive index of the substrate (Ns), and the thin film of the fluorescent material comprises an organic or inorganic fluorescent material which is excited by an ultraviolet ray or electron ray to emit light.