Coating derived from polyesters crosslinked with melamine formaldehyde
View Patent ↗A coating composition is based on a polyester mixed with an alkyl-etherified melamine formaldehyde. The coating composition is partially cured in a first stage to provide a thermoformable partially cured, tack-free, non-blocking, coating layer, followed by application to generally a contoured substrate and thermoforming to conform thereto. The contoured partially cured coating layer is then heat cured to form a cured coating. A hydroxyl-terminated polyoxetane containing repeat units derived from oxetane monomers having one or two pendent —CH 2 —O—(CH 2 ) n —Rf groups, wherein Rf is partially or fully fluorinated, can be esterified with polyester-forming reactants to form a fluorinated polyoxetane-modified polyester.
1. A method of providing an article with a thermoformed coating, said method comprising:
a) forming a composite by applying to a substrate a composition, said composition comprising a polyester, an alkyl-etherified melamine formaldehyde compound and, based on the combined weight of the polyester and alkyl-etherified melamine formaldehyde compound, from about 1 to about 15% of a thermally activatable catalyst;
b) heating said composite to a temperature of from about 49° to about 77° C. for about 2 to about 60 seconds so as to partially cure said composition and provide a laminate;
c) thermoforming said laminate to said article; and
d) heating said laminate to a temperature of at least 83° C. for at least 30 seconds so as to cure said laminate, thereby providing said thermoformed coating.
2. The method of claim 1 wherein said substrate is a poly(vinyl chloride) sheet.
3. The method of claim 1 wherein said laminate is heated to a temperature of from 88° to 149° C. in step (d).
4. The method of claim 1 wherein said article is a furniture piece component.
5. The method of claim 1 wherein said polyester is modified with a fluorinated polyoxetane.
6. The method of claim 5 wherein the modified polyester is provided by one of
(i) reacting a hydroxyl-terminated fluorinated polyoxetane with a dicarboxylic acid or anhydride to form an acid terminal group and allowing said acid terminal group to react with ester-forming monomers so as to provide said modified polyester, said ester-forming monomers comprising one or more diols, dicarboxylic acids, and mixtures thereof, and
(ii) reacting a hydroxyl-terminated fluorinated polyoxetane with a preformed polyester,
wherein said hydroxyl-terminated fluorinated polyoxetane comprises repeat units derived from oxetanes comprising at least one pendent ether group of the formula —CH 2 O(CH 2 ) n Rf in which n is an integer of from 1 to 5 and Rf is a C 1 -C 20 alkyl group in which at least some of the H atoms have been replaced by F atoms.
7. The method of claim 6 wherein said hydroxyl-terminated fluorinated polyoxetane additionally comprises repeat units derived from a non-fluorinated C 2 -C 4 cyclic ether.
8. The method of claim 6 wherein said hydroxyl-terminated fluorinated polyoxetane has a number average molecular weight of from about 500 to about 5000.
9. The method of claim 1 wherein said melamine formaldehyde is etherified with at least three alkyl groups, at least one of said alkyl groups optionally being different from the others.
10. A method of providing an article with a thermoformed coating, said method comprising:
a) coating a substrate with a composition comprising a thermally activatable catalyst, one or more polyester compounds and a melamine formaldehyde that comprises at least two different C 1 -C 6 alkoxy groups;
b) heating the coated substrate to a temperature of from about 49° to about 77° C. so as to activate said catalyst component, thereby partially curing said composition and providing a laminate;
c) thermoforming said laminate to said article; and
d) heating said laminate to a temperature of at least 83° C. for at least 30 seconds so as to cure said laminate, thereby providing said thermoformed coating.
11. The method of claim 10 wherein said substrate is a poly(vinyl chloride) sheet.
12. The method of claim 10 wherein the laminate is heated to a temperature of from 88° to 149° C. in step (d).
13. The method of claim 10 wherein said article is a furniture piece component.
14. The method of claim 10 wherein said polyester is modified with a fluorinated polyoxetane.
15. The method of claim 14 wherein the modified polyester is provided by one of
(i) reacting a hydroxyl-terminated fluorinated polyoxetane with a dicarboxylic acid or anhydride to form an acid terminal group and allowing said acid terminal group to react with ester-forming monomers so as to provide said modified polyester, said ester-forming monomers comprising one or more diols, dicarboxylic acids, and mixtures thereof, and
(ii) reacting a hydroxyl-terminated fluorinated polyoxetane with a preformed polyester,
wherein said hydroxyl-terminated fluorinated polyoxetane comprises repeat units derived from oxetanes comprising at least one pendent ether group of the formula —CH 2 O(CH 2 ) n Rf in which n is an integer of from 1 to 5 and Rf is a C 1 -C 20 alkyl group in which at least some of the H atoms have been replaced by F atoms.
16. The method of claim 15 wherein said hydroxyl-terminated fluorinated polyoxetane additionally comprises repeat units derived from a non-fluorinated C 2 -C 4 cyclic ether.
17. The method of claim 15 wherein said hydroxyl-terminated fluorinated polyoxetane has a number average molecular weight of from about 500 to about 5000.
18. The method of claim 10 wherein said melamine formaldehyde comprises at least three alkoxy groups.
19. The method of claim 1 wherein said thermally activatable catalyst component comprises one or more of para-toluene sulfonic acid, methyl sulfonic acid, boric acid, phosphoric acid, sulfate acid, hypochlorides, oxalic acid and ammonium salts thereof, sodium or barium ethyl sulfates, and sulfonic acids.
20. The method of claim 10 wherein said thermally activatable catalyst component comprises one or more of para-toluene sulfonic acid, methyl sulfonic acid, boric acid, phosphoric acid, sulfate acid, hypochlorides, oxalic acid and ammonium salts thereof, sodium or barium ethyl sulfates, and sulfonic acids.