Heat-shrinkable polyester film
View Patent ↗A heat-shrinkable polyester film comprising a polyester base film and a coat layer formed on one or both sides of the polyester base film, said coat layer comprising a copolymerised polyester having carboxyl group terminals and Tg in the range of 70 to 80;É, exhibits superior properties suitable for labeling or shrink-wrapping containers.
1. A heat-shrinkable polyester film comprising a polyester base film and a coat layer formed on one or both sides of the polyester base film, wherein said coat layer comprises a copolymerized polyester having carboxyl group terminals and T g in the range of 70 to 80° C., and is formed in an amount ranging from 0.01 to 0.1 g/m 2 on the base film surface.
2. The heat-shrinkable polyester film of claim 1 , wherein said copolymerized polyester is copolymerized using a dicarboxylic acid selected from the group consisting of terephthalic acid, an ester thereof, isophthalic acid, an ester thereof, 2,6-naphthalenedicarboxylic acid, an ester thereof, sebacic acid, adipic acid, sodium 5-sulfoisophthalate, trimellitic acid, oxalic acid, maleic acid, succinic acid, glutaric acid, pimelic acid, azelaic acid, pyromellitic acid and a mixture thereof; and a diol component selected from the group consisting of ethylene glycol, 1,3-propanediol, diethylene glycol, hexanediol, 2,2-(4-oxyphenol)propanediol derivatives, xylene glycol, triethylene glycol, poly-tetramethylene glycol, 2,2′-oxybis(ethanol), 2,2-dimethyl(-1,3-propane)diol and a mixture thereof.
3. The heat-shrinkable polyester film of claim 1 , wherein said polyester base film further comprises an inorganic lubricant in an amount of 0.1 to 0.5% by weight based on the copolymerized polyester.
4. The heat-shrinkable polyester film of claim 3 , wherein said inorganic lubricant is selected from the group consisting of silica, alumina, titania, calcium carbonate, barium sulfate and a mixture thereof.
5. The heat-shrinkable polyester film of claim 1 , wherein said polyester base film comprises a trimethylene terephthalate repeating unit.
6. The heat-shrinkable polyester film of claim 5 , wherein said polyester base film further comprises ethylene terephthalate and 2,2-dimethyl (-1,3-propylene)terephthalate repeating units.
7. The heat-shrinkable polyester film of claim 6 , wherein the content of said trimethylene terephthalate repeating unit is in the range of 5 to 25% by mole, the content of said ethylene terephthalate repeating unit is in the range of 45 to 90% by mole, and the content of said 2,2-dimethyl(-1,3-propane)terephthalate repeating unit is in the range of 5 to 30% by mole.
8. The heat-shrinkable polyester film of claim 6 , wherein the polyester base film is prepared by blending a polytrimethylene terephthalate, a polyethylene terephthalate and a 2,2-dimethyl(-1,3-propane)diol-copolymerized polyester.
9. The heat-shrinkable polyester film of claim 8 , wherein the intrinsic viscosities of the polytrimethylene terephthalate and the polyethylene terephthalate are in the ranges of 0.7 to 0.95 and 0.5 to 0.65, respectively.
10. The heat-shrinkable polyester film of claim 8 , wherein the 2,2-dimethyl(-1,3-propane)diol-copolymerized polyester is prepared by copolymerizing terephthalic acid or dimethyl terephthalate with a mixture of ethylene glycol and 2,2-dimethyl(-1,3-propane)diol.
11. The heat-shrinkable polyester film of claim 10 , wherein the intrinsic viscosity of the 2,2-dimethyl(-1,3-propane)diol-copolymerized polyester is in the range of 0.5 to 0.7.
12. The heat-shrinkable polyester film of claim 10 , wherein said 2,2-dimethyl(-1,3-propane)diol-copolymerized polyester comprises 75 to 85% by mole of said ethylene terephthalate repeating unit and 15 to 25% by mole of said 2,2-dimethyl(-1,3-propylene)terephthalate repeating unit.
13. The heat-shrinkable polyester film of claim 5 , wherein said trimethylene terephthalate repeating unit is prepared by polymerizing terephthalic acid or dimethyl terephthalate with propanediol.
14. The heat-shrinkable polyester film of claim 13 , wherein said dicarboxylic acid component further comprises dimethyl isophthalate and dimethyl-2,6-naphthalenedicarboxylate, and said diol component further comprises 2,2-dimethyl(-1,3-propane)diol and ethylene glycol.
15. The heat-shrinkable polyester film of claim 14 , wherein said dicarboxylic acid component comprises 70 to 100% by mole of dimethyl terephthalate, 0 to 20% by mole of dimethyl isophthalate and 0 to 10% by mole of dimethyl-2,6-naphthalenedicarboxylate.
16. The heat-shrinkable polyester film of claim 14 , wherein said diol component comprises 5 to 20% by mole of propanediol, 5 to 20% by mole of 2,2-dimethyl(-1,3-propane)diol and 60 to 90% by mole of ethylene glycol.