Method and reactor for carrying out chemical reactions in pseudo-isothermal conditions
View Patent ↗A method for controlling the pseudo-isothermicity of a chemical reaction in a respective reaction zone. ( 9 ) in which the use of heat exchangers ( 6 ) is foreseen having an operating heat exchange fluid flowing through them and in which heat exchange critical areas ( 9 a ) are identified, the method being distinguished by the fact that it reduces and controls, in the critical areas ( 9 a ) of the reaction zone, the value of the heat exchange coefficient between the operating fluid and the zone ( 9 ), through thermal insulation of the portions ( 6 a, 6 b ) of such exchangers extending in such areas ( 9 a ).
1. A method for controlling the pseudo-isothermicity of a chemical reaction in a respective reaction zone in which heat exchangers are used, the heat exchangers having an operating heat exchange fluid flowing through them and in which critical areas are identified, the method comprising the step of:
reducing and controlling, in the critical areas of the reaction zone, the value of a heat exchange coefficient between the operating fluid and the reaction zone, through thermal insulation of the portions of the heat exchangers extending in the critical areas,
wherein the thermal insulation of the portions of the exchangers is carried out through the application on the portions of at least one layer of thermally insulating material; and
wherein a plurality of layers of insulating material of different thickness or a single layer of insulating material of variable thickness is applied on the portions of the exchangers.
2. The method according to claim 1 , wherein the at least one layer of insulating material is applied to the outside and/or to the inside of the exchangers at the portions.
3. The method according to claim 1 , wherein the at least one layer of insulating material has a thickness between 50 and 800 μm.
4. The method according to claim 3 , wherein the at least one layer of insulating material has a thickness between 100 and 500 μm.
5. The method according to claim 1 , wherein the at least one layer of insulating material comprises a ceramic material based upon oxides of zirconium, of yttrium, of aluminum, of cerium, of magnesium or mixtures thereof.
6. The method according to claim 5 , wherein the at least one layer of insulating material is applied on the portions of the heat exchangers through plasma.