Binder for glass fibers, glass fibers for olefin resin reinforcement, and process for producing olefin resin composition for fiber-reinforced molding
View Patent ↗This invention provides a sizing composition for glass fibers useful in reinforcing an olefin resin, which comprises at least a) an acid-modified olefin resin which has been neutralized with an amine and b) an amino-containing silane coupling agent. The sizing composition makes it possible to firmly adhere an olefin resin as a matrix resin and the glass fibers with each other and hence, to provide a molding having excellent strength without occurrence of fuzzing on the resin pellets or the molding. This invention also provides glass fibers for olefin resin reinforcement and a production process of an olefin resin composition for fiber-reinforced moldings.
1. A sizing composition comprising:
a) an acid-modified olefin resin having a number average molecular weight of 10,000–50,000 which has been neutralized with ethylenediamine, and
b) γ-aminopropyltriethoxysilane.
2. The sizing composition as claimed in claim 1 , wherein said acid-modified olefin resin is obtained by
chlorosulfonating an olefin resin to obtain one or more chlorosulfone groups, and then converting said one or more chlorosulfone groups into one or more sulfone groups; or
sulfonating an olefin resin; or
copolymerizing a polymerizable, unsaturated carboxylic acid compound or a derivative thereof with an olefin resin; or
graft-polymerizing an addition-polymerizable, unsaturated carboxylic acid compound or a derivative thereof with an olefin resin.
3. The sizing composition as claimed in claim 1 , wherein said acid-modified olefin resin is a sulfonated polyethylene, a sulfonated polypropylene, or mixtures thereof.
4. The sizing composition as claimed in claim 2 , wherein said acid-modified olefin resin is obtained by
said copolymerizing or said graft-polymerizing; wherein
said unsaturated carboxylic acid compound is at least one selected from the group consisting of maleic acid, fumaric acid, itaconic acid, acrylic acid, and methacrylic acid; and
said derivative is an anhydride, ester, amide, imide, metal salt, or mixtures thereof of said unsaturated carboxylic acid.
5. The sizing composition as claimed in claim 4 , wherein said unsaturated carboxylic acid compound is selected from the group consisting of glycidyl acrylate, glycidyl methacrylate, and maleic anhydride.
6. The sizing composition as claimed in claim 1 , wherein said acid-modified olefin resin is neutralized with an alkali metal hydroxide in addition to said ethylenediamine.
7. The sizing composition as claimed in claim 1 , wherein said sizing composition further comprises a surfactant.
8. The sizing composition as claimed in claim 1 , wherein said silane coupling agent is present in an amount of 10–30 wt. % acid-modified olefin resin based on total weight of component a) and b).
9. The sizing composition as claimed in claim 8 , wherein said sizing composition comprises 70–90 wt. % of said acid-modified olefin resin based on total weight of component a) and b).
10. The sizing composition as claimed in claim 1 , further comprising a lubricant.
11. The sizing composition as claimed in claim 1 , further comprising an anti-static agent.
12. The sizing composition as claimed in claim 1 , wherein said sizing composition is in the form of an aqueous dispersion or aqueous solution having a solids concentration of 0.01 to 0.5 wt %.
13. The sizing composition as claimed in claim 1 , wherein said acid-modified olefin resin has a number average molecular weight of 10,000–15,000.
14. The sizing composition as claimed in claim 1 , wherein said acid-modified olefin resin has a number average molecular weight of 10,000–25,000.
15. The sizing composition as claimed in claim 1 , wherein said acid-modified olefin resin has a number average molecular weight of 15,000–25,000.
16. The sizing composition as claimed in claim 1 , wherein said acid-modified olefin resin has a number average molecular weight of 15,000–50,000.
17. The sizing composition as claimed in claim 1 , wherein said acid-modified olefin resin has a number average molecular weight of 25,000–50,000.
18. A process for producing an olefin resin composition, said method comprising:
impregnating a continuous glass fiber strand, which has been treated with a sizing composition according to claim 1 , with a melt of an olefin resin fed to a crosshead from an extruder while pulling said continuous glass fiber strand through said crosshead.
19. A process for producing an olefin resin composition, said method comprising:
kneading chopped strands, which have been formed by chopping a glass fiber strand treated with a sizing composition according to claim 1 , with an olefin resin into a mass,
extruding said mass into wires, and then
chopping said wires.
20. The process according to claim 18 , wherein said olefin resin is polypropylene.
21. The process according to claim 19 , wherein said olefin resin is polypropylene.
22. Glass fibers comprising a sizing composition according to claim 1 , applied in an amount of from 0.1 to 2.0 wt. % in terms of solids based on a whole weight of said glass fibers and said sizing composition.