Cooking of cellulose pulp in a cooking liquor containing pre-evaporated black liquor
View Patent ↗The method is for cooking of cellulose pulp in which the raw material, preferably in the form of chips, undergoes a successive elevation of temperature towards the cooking temperature while the chips are first impregnated with an impregnation liquor followed by cooking in a cooking liquor that is preferably alkali. Through the addition of pre-evaporated black liquor, either as early as the impregnation stage or during the subsequent cooking stage, an improved delignification process is achieved in which the pulp obtains improved properties, primarily with respect to strength/viscosity for a given degree of delignification, and also with respect to yield. The method can be used both for continuous cooking and for batch cooking of cellulose pulp.
1. A method for the production of cellulose pulp, comprising:
adding an impregnation liquor to an impregnation stage;
treating wood chips in the impregnation stage with the impregnation liquor at an impregnation temperature;
cooking the wood chips in a cooking stage by using a cooking liquor having a cooking temperature of 150±20° C., the cooking temperature being higher than the impregnation temperature;
withdrawing black liquor from the impregnation stage, the withdrawn black liquor being at the impregnation temperature and having a first concentration of dry matter (TS);
subjecting the withdrawn black liquor to a pressure reduction in a pressure-reduction vessel to form a pressure-reduced black liquor having a second concentration of dry matter (TS), the second concentration being higher than the first concentration;
conveying the pressure-reduced black liquor to an evaporation stage;
in the evaporation stage, forming a partially evaporated black liquor, the partially evaporated black liquor having a third concentration of dry matter (TS), the third concentration having a dry matter (TS) concentration that is at least 10% higher than a dry matter (TS) concentration of the second concentration of the pressure-reduced black liquor;
adding the partially evaporated black liquor to the cooking liquor at a start of or during a delignification stage; and
cooking the wood chips in the cooking stage to produce cellulose pulp.
2. The method according to claim 1 , wherein the partially evaporated black liquor has a concentration of dry matter (TS) in the partially evaporated black liquor that exceeds 30%.
3. The method according to claim 2 , wherein the partially evaporated black liquor has a concentration of dry matter (TS) in the partially evaporated black liquor that exceeds 50%.
4. The method according to claim 1 , wherein the partially evaporated black liquor is mixed with another treatment liquor before the partially evaporated black liquor is added to the wood chips prior to the wood chips being cooked in a delignification stage.
5. The method according to claim 1 wherein the method further comprises reducing a pressure of the withdrawn black liquor in at least one pressure-reduction tank down to a pressure that does not exceed an excess pressure of 0.5 bar and evaporating the pressure-reduced black liquor in at least one primary evaporation step in which the evaporated black liquor is heated during a removal of volatile substances from the evaporated black liquor to increase a content of dry material.
6. The method according to claim 5 , wherein the method further comprises making the primary evaporation step part of a recovery plant for black liquor.
7. The method according to claim 5 , wherein the primary evaporation stage is constituted by a dedicated evaporation stage that only evaporates an amount of black liquor that is to be returned to the impregnation or cooking stage.
8. The method according to claim 1 wherein the partially evaporated black liquor is added to the cooking liquor so that the partially evaporated black liquor is present during at least part of an initial delignification stage of a cooking stage.
9. The method according to claim 1 wherein the partially evaporated black liquor is present during more than 50% of a retention time of the wood chips in a bulk delignification stage.
10. The method according to claim 1 wherein the third concentration has a concentration of dry matter (TS) in the partially evaporated black liquor that is in a range of 27-30%.
11. The method according to claim 1 wherein the partially evaporated black liquor is mixed with cooking liquor before being added to the start of or during the delignification stage of the digester.
12. The method according to claim 1 wherein the method further comprises treating wood chips in several stages including impregnation and cooking stages at successively increasing temperatures.