Method for manufacturing multilayer ceramic capacitor

1. A method of manufacturing a multilayer ceramic capacitor, comprising:

the first step of introducing a raw material powder mainly composed of barium titanate particles and a dispersion medium into a mixing container, and stirring them with balls serving as a mixing medium, to obtain a slurry containing a raw material powder mixture;

the second step of drying said slurry, to obtain said raw material powder mixture;

the third step of forming said raw material powder mixture and a binder into a green sheet;

the fourth step of alternately layering said green sheet and an internal electrode, to obtain a laminated body; and

the fifth step of sintering said laminated body,

wherein said mixing medium has a diameter that is equal to or less than 400 times the mean particle size of the barium titanate particles before the first step.

2. The method of manufacturing a multilayer ceramic capacitor in accordance with claim 1 , wherein the mean particle size of said barium titanate particles of the raw material powder is 0.1 to 1 μm, and the diameter of said mixing medium is 200 μm or less.

3. The method of manufacturing a multilayer ceramic capacitor in accordance with claim 1 , wherein the amount of said dispersion medium is 1 to 3 times the volume of the raw material powder.

4. The method of manufacturing a multilayer ceramic capacitor in accordance with claim 1 , wherein the surface of the raw material powder is coated with the dispersion medium before being brought into contact with the mixing medium in the first step.

5. The method of manufacturing a multilayer ceramic capacitor in accordance with claim 1 , wherein the temperature of the dispersion medium is 50° C. or less in the first step.

6. The method of manufacturing a multilayer ceramic capacitor in accordance with claim 1 , wherein the amount of said mixing medium occupies 60 to 74% of the internal volume of the mixing container in the first step.

7. The method of manufacturing a multilayer ceramic capacitor in accordance with claim 1 , wherein the drying temperature is 120° C. or less in the second step.

8. The method of manufacturing a multilayer ceramic capacitor in accordance with claim 1 , wherein the second step further comprises the step of dehydrating the slurry before said drying.

9. The method of manufacturing a multilayer ceramic capacitor in accordance with claim 1 , further comprising between the second step and the third step the steps of:

calcining said mixture;

stirring the calcined mixture, with a dispersion medium and a grinding medium having a diameter that is equal to or less than 400 times the mean particle size of said barium titanate particles of the raw material powder, to obtain a slurry containing a calcined powder; and

drying said slurry, to obtain the calcined powder.

10. The method of manufacturing a multilayer ceramic capacitor in accordance with claim 9 , wherein said grinding medium has a diameter that is equal to or larger than the diameter of the mixing medium used in the first step.

11. The method of manufacturing a multilayer ceramic capacitor in accordance with claim 9 , wherein the specific surface area of said calcined powder is 0.5 to 1 time the specific surface area of said barium titanate particles of the raw material powder.

12. The method of manufacturing a multilayer ceramic capacitor in accordance with claim 1 , wherein the third step comprises the steps of:

stirring said raw material powder mixture, an organic binder and a solvent thereof, with a third mixing medium having a diameter that is equal to or less than 400 times the mean particle size of said barium titanate particles of the raw material powder, to obtain a slurry; and

forming a green sheet from said slurry.