Polyester false-twist yarn and method of manufacturing the yarn
View Patent ↗A polyester false-twist textured yarn, useful as a yarn for woven or knitted fabrics having excellent water-absorbing and quick drying properties, satisfies all of the requirements (1) to (3) shown below: (1) the cross-sectional profiles of a plurality of individual filaments, from which the false-twist textured multifilament yarn is constituted, each have 3 to 6 concavities, and the average number of the concavities having a ratio (H/W) of a largest depth (H) to a largest width (W) of the individual concavities of 0.3 or more is in the range of from 50 to 80% of the total number of the concavities; (2) the average of the cross-sectional profile flatness factors is in the range of from 1.5 to 3.5; and (3) the standard deviation of the cross-sectional profile flatness factors is in the range of from 0.3 to 1.0.
1. A polyester false-twist textured yarn comprising a false-twist textured yarn, of a multifilament yarn, comprising a polyester resin,
wherein cross-sectional profiles of a plurality of individual filaments, from which the false-twist textured multifilament yarn is constituted, satisfy all of the requirements (1) to (3) shown below:
(1) the cross-sectional profiles of the plurality of individual filaments each have 3 to 6 convexities and 3 to 6 concavities formed between the convexities, and the average number of the concavities having a ratio (H/W) of a largest depth (H) of the individual concavities to a largest opening width of the individual concavities of 0.3 or more is in the range of from 50 to 80% of the total number of the concavities;
(2) an average flatness factor of the cross-sectional profiles of the plurality of individual filaments represented by ratios (L 1 /L 2 ) of largest lengths (L 1 ) of the cross-sectional profiles of the plurality of individual filaments to largest widths (L 2 ) at right angles to the direction of the largest lengths (L 1 ) is in the range from 1.5 to 3.5; and
(3) a standard deviation of the flatness factors of the plurality of individual filaments is in the range of from 0.3 to 1.0.
2. The polyester false-twist textured yarn as claimed in claim 1 , wherein the polyester resin comprises, as a principal component, a polyester comprising, as principal repeating units, repeating ethylene terephthalate units.
3. The polyester false-twist textured yarn as claimed in claim 1 , wherein the polyester resin contains a fine pore-forming agent (1) synthesized by mixing, during the preparation procedure of the polyester resin, (a) a metal-containing phosphorus compound represented by the general formula (1):
wherein R 1 and R 2 , which may be the same as each other or different from each other, represent a mono-valent organic group, M 1 represents an alkali metal atom or an alkaline earth metal atom, and ma represents 1 when M 1 represents an alkali metal atom, or 1/2 when M 2 represents an alkaline earth metal atom,
and (b) an alkaline earth metal compound into the preparation system of the polyester resin.
4. The polyester false-twist textured yarn as claimed in claim 1 , wherein the polyester resin contains a fine pore-forming agent (2) comprising at least one member selected from metal salts of aromatic sulfonic acids represented by the general formula (2):
wherein R 3 represents a hydrogen atom or ester-forming organic group, M 2 and M 3 respectively and independently from each other represent a metal atom, mb and mc respectively represent a reciprocal of the valance number of M 2 or M 3 corresponding to mb or mc, and n represents an integer of 1 or 2.
5. A process for producing the polyester false-twist textured yarn comprising a melt spinning procedure in which a polyester resin is melted, the polyester resin melt is extruded through a plurality of spinning orifices into filamentary streams, the polyester resin filamentary streams are cooled and solidified; and the resultant undrawn polyester multifilament yarn is taken up, wherein the form of the spinning orifices and the melt-spinning conditions are controlled so that the form and dimensions of the cross-sectional profiles of a plurality of individual filaments from which the undrawn polyester multi-filament yarn is constituted, satisfy both of requirements (4) and (5) shown below:
(4) in each of the cross-sectional profiles of the plurality of undrawn individual filaments, 3 to 6 concavities are formed and the average of the ratios (Ha/Wa) of the largest depth as (Ha) to the largest opening widths (Wa) of the individual concavities of the cross-sectional profiles are in the range of from 0.3 to 0.5; and
(5) the average of cross-sectional profile flatness factors represented by the ratios (L 1 a /L 2 a ) of the largest lengths (L 1 a ) of the cross-sectional profiles of the plurality of undrawn individual filaments to the largest widths (L 2 a ) at right angles to the directions of the largest lengths is in the range of from 1.0 to 1.5,
and a simultaneous drawing and false-twist texturing procedure in which the undrawn polyester multifilament yarn is simultaneously drawn and false-twist textured, to prepare a drawn false-twist textured yarn,
wherein the simultaneous drawing and false-twist texturing procedure is carried out under conditions satisfying both of the requirements (6) and (7) as shown below:
(6) the temperature of a first heater for the false-twisting procedure is adjusted in the range of from 30° C. to 100° C. below the melting temperature of the polyester resin; and
(7) the false twist number per meter is adjusted in the range of from 25,000/D 1/2 to 35,000/D 1/2 ,
wherein D represents a thickness in dtex of the yarn obtained by the simultaneous drawing and false-twist texturing procedure, to thereby produce the polyester false-twist textured yarn as claimed in claim 1 .
6. The process for producing a polyester false-twist textured yarn as claimed in claim 5 , wherein the polyester comprises, as a principal component, a polyester comprising, as principal repeating units, repeating ethylene terephthalate units.
7. The process for producing a polyester false-twist textured yarn as claimed in claim 6 wherein, in the melt-spinning procedure, the taking up speed of the undrawn multifilament yarn is 2,500 to 4,000 m/min, and in the drawing and false-twist texturing procedure, the temperature of the first heater for the false-twist texturing is in the range of from 150 to 200° C.
8. The process for producing the polyester false-twist textured yarn as claimed in claim 5 , wherein
the polyester resin contains a fine pore-forming agent (1) synthesized by mixing, during the preparation procedure of the polyester resin, a metal-containing phosphorus compound represented by the general formula (1):
wherein R 1 and R 2 , which may be the same as or different from each other, represent a mono-valent organic group, M 1 represents an alkali metal atom or an alkaline earth metal atom, and ma represents 1 when M 1 represents an alkali metal atom, or 1/2 when M 2 represents an alkaline earth metal atom,
and an alkaline earth metal compound into the preparation system of the polyester resin.
9. The process for producing a polyester false-twist textured yarn as claimed in claim 7 , wherein the polyester resin contains a fine pore-forming agent ( 2 ) comprising at least one member selected from metal salts of aromatic sulfonic acids represented by the general formula (2):
wherein R 3 represents a hydrogen atom or ester-forming organic group, M 2 and M 3 respectively and independently from each other represent a metal atom, mb and mc respectively represent a reciprocal of the valance number of M 2 or M 3 corresponding to mb or mc, and n represents an integer of 1 or 2.